791616-55-2
中文名称
R-3,3'-二(三苯基硅基)联萘酚膦酸酯
英文名称
(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
CAS
791616-55-2
分子式
C56H41O4PSi2
分子量
865.082
MOL 文件
791616-55-2.mol
更新日期
2025/05/16 15:51:52
791616-55-2 结构式
基本信息
中文别名
MACMILLAN TIPSY 催化剂R-3,3'-二(三苯基硅基)联萘酚磷酸酯
S-3,3'-二(三苯基硅基)联萘酚膦酸酯
R-3,3'-二(三苯基硅基)联萘酚膦酸酯
(R)-3,3'-双(三苯基硅基)联萘酚膦酸酯
(R)-3,3'-双(三苯基硅基)联萘酚磷酸酯
(R)-(–)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚磷酸酯
(R)-(-)-3,3′-双(三苯甲硅烷基)-1,1′-联萘-2,2′-二酚膦酸氢酯
(11BR)-4-羟基-2,6-双(三苯甲硅烷基)二萘并-[2,1-D:1′,2′F]-1,3,2-二恶磷环庚烷-4-氧化物
(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYLHYDROGENPHOSPHATE,MIN.98%[(R)-TIPSY]
英文别名
Carreira SALDIPAC Ligand(S)-3,3μ-Bis(triphenylsilyl)-1,1μ-binaphthyl-2,2μ-diyl hydrogenphosphate
(R)-(-)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate 96%
(R)-(-)-3,3'-BIS(TRIPHENYLSILYL)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE, 95%
(R)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl Hydrogen Phosphate,99%e.e.
2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide
(11bR)-2,6-Bis(triphenylsilyl)-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bS)-4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
MacMillan TiPSY catalyst, (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1μ,2μf]-1,3,2-dioxaphosphepin 4-oxide
所属类别
化学试剂：膦配体物理化学性质
熔点329-335 °C
比旋光度-197° (c=1, CHCl3)
密度1.32±0.1 g/cm3(Predicted)
储存条件Sealed in dry,Room Temperature
酸度系数(pKa)1.17±0.20(Predicted)
形态粉末
颜色白色至淡黄色
旋光性 (optical activity)[α]22/D -197°, c = 1 in chloroform
