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1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI)

CAS No.
131020-36-5
Chemical Name:
1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI)
Synonyms
Methyl 1-Methyl-1H-benzo[d]iMidazole-5-carboxylate;Methyl 1-MethylbenziMidazole-5-carboxylate;Methyl 1-methylbenzo[d]imidazol-5-carboxylate;1-Methyl-1H-benzimidazole-5-carboxylic acid methyl ester;1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI)
CBNumber:
CB01299144
Molecular Formula:
C10H10N2O2
Molecular Weight:
190.2
MDL Number:
MFCD04492113
MOL File:
131020-36-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:59:00
Product description Number Pack Size Price
Methyl 1-methylbenzimidazole-5-carboxylate 97% OR910533 250mg $25
Methyl 1-methylbenzimidazole-5-carboxylate 97% OR910533 1g $33
Methyl 1-methylbenzimidazole-5-carboxylate 97% OR910533 5g $160
Methyl 1-methylbenzimidazole-5-carboxylate 97% OR910533 250mg $25
Methyl 1-methylbenzimidazole-5-carboxylate 97% OR910533 1g $33
More product size

1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI) Properties

Melting point 109~111℃
storage temp. Sealed in dry,Room Temperature
Appearance Brown to black Solid

SAFETY

Risk and Safety Statements

HS Code  2933998090

1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI) price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR910533 Methyl 1-methylbenzimidazole-5-carboxylate 97% 131020-36-5 250mg $25 2026-06-04 Buy
Apolloscientific OR910533 Methyl 1-methylbenzimidazole-5-carboxylate 97% 131020-36-5 1g $33 2026-06-04 Buy
Apolloscientific OR910533 Methyl 1-methylbenzimidazole-5-carboxylate 97% 131020-36-5 5g $160 2026-06-04 Buy
Apolloscientific OR910533 Methyl 1-methylbenzimidazole-5-carboxylate 97% 131020-36-5 250mg $25 2026-06-04 Buy
Apolloscientific OR910533 Methyl 1-methylbenzimidazole-5-carboxylate 97% 131020-36-5 1g $33 2026-06-04 Buy
Product number Packaging Price Buy
OR910533 250mg $25 Buy
OR910533 1g $33 Buy
OR910533 5g $160 Buy
OR910533 250mg $25 Buy
OR910533 1g $33 Buy

1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI) Chemical Properties,Uses,Production

Uses

Methyl 1-Methyl-1H-benzo[d]imidazole-5-carboxylate is a useful reagent for preparation of hydroxytryptamine receptor antagonist.

Synthesis

Formic acid

64-18-6

Methyl 3-amino-4-(methylamino)benzenecarboxylate

66315-16-0

1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI)

131020-36-5

Methyl 3-amino-4-(methylamino)benzoate (3.3 g) was dissolved in 96 ml of formic acid, 4 ml of water was added, and the reaction mixture was stirred at 90°C for 3 hours. After completion of the reaction, the reaction solution was concentrated under reduced pressure and the residue was dissolved in ethyl acetate. The organic phase was washed sequentially with saturated sodium bicarbonate solution and dried over anhydrous sodium sulfate. The organic phase was concentrated under reduced pressure to give methyl 1-methyl-1H-benzimidazole-5-carboxylate (3.4 g, 97% yield). The structure of the product was confirmed by 1H NMR (DMSO-d6, δ ppm: 3.8 (s, 3H), 3.8 (s, 3H), 7.6 (d, 1H), 7.9 (dd, 1H), 8.2 (d, 1H), 8.3 (s, 1H)) and ESI/MS (m/z: 191 [M+H]+).

References

[1] Patent: EP1595866, 2005, A1. Location in patent: Page/Page column 26

1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI) Preparation Products And Raw materials

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1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI) Spectrum

1H-Benzimidazole-5-carboxylicacid,1-methyl-,methylester(9CI) 1-Methyl-1H-benzimidazole-5-carboxylic acid methyl ester Methyl 1-Methyl-1H-benzo[d]iMidazole-5-carboxylate Methyl 1-MethylbenziMidazole-5-carboxylate Methyl 1-methylbenzo[d]imidazol-5-carboxylate 131020-36-5 BENZIMIDAZOLE