ChemicalBook >> CAS DataBase List >>6-BROMO-2,2'-BIPYRIDINE

6-BROMO-2,2'-BIPYRIDINE

CAS No.
10495-73-5
Chemical Name:
6-BROMO-2,2'-BIPYRIDINE
Synonyms
6-Bromo-2,2'-bipyridyl;6-bromo-2,2'-bipyridine;6-BROMO-2,2'-BIPYRIDINE;6-Bromo-[2,2']bipyridinyl;2,2'-Bipyridine, 6-bromo-;6-Bromo-2,2'-bipyridyl >6-broMo-2,2'-bipyridine 97%;2-BROMO-6-(2-PYRIDYL)PYRIDINE;2-bromo-6-(pyridin-2-yl) pyridine;6-BROMO-2,2'-BIPYRIDINE ISO 9001:2015 REACH
CBNumber:
CB0214564
Molecular Formula:
C10H7BrN2
Molecular Weight:
235.08
MDL Number:
MFCD01318953
MOL File:
10495-73-5.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-06-04 16:00:12
Product description Number Pack Size Price
6-Bromo-2,2′-bipyridine 97% 690066 1g $233
6-Bromo-2,2'-bipyridyl >97.0%(GC) B4114 1g $147
6-Bromo-2,2'-bipyridyl >97.0%(GC) B4114 5g $584
6-Bromo-2,2'-bipyridyl Asreported 267147 500mg $317
6-Bromo-2,2'-bipyridyl Asreported 267147 1g $440
More product size

6-BROMO-2,2'-BIPYRIDINE Properties

Melting point 72.0 to 76.0 °C
Boiling point 133°C/2.2mmHg(lit.)
Density 1.493±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform, Methanol
pka 3.70±0.22(Predicted)
form powder to crystal
color White to Almost white
BRN 130238
InChI InChI=1S/C10H7BrN2/c11-10-6-3-5-9(13-10)8-4-1-2-7-12-8/h1-7H
InChIKey NCRIDSGPLISUEU-UHFFFAOYSA-N
SMILES C1(C2=NC=CC=C2)=NC(Br)=CC=C1
CAS DataBase Reference 10495-73-5
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
Signal word  Danger
Hazard statements  H301-H315-H318-H335
Precautionary statements  P280-P301+P310+P330-P302+P352-P305+P351+P338+P310
target organs Respiratory system
PPE Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-22
Safety Statements  26-36/37/39
RIDADR  UN 2811
WGK Germany  3
HazardClass  6.1
HS Code  2933399990
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Limited Quantities 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
1 0

6-BROMO-2,2'-BIPYRIDINE price More Price(53)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 690066 6-Bromo-2,2′-bipyridine 97% 10495-73-5 1g $233 2026-04-30 Buy
TCI Chemical B4114 6-Bromo-2,2'-bipyridyl >97.0%(GC) 10495-73-5 1g $147 2026-04-30 Buy
TCI Chemical B4114 6-Bromo-2,2'-bipyridyl >97.0%(GC) 10495-73-5 5g $584 2026-04-30 Buy
Usbiological 267147 6-Bromo-2,2'-bipyridyl Asreported 10495-73-5 500mg $317 2026-06-03 Buy
Usbiological 267147 6-Bromo-2,2'-bipyridyl Asreported 10495-73-5 1g $440 2026-06-03 Buy
Product number Packaging Price Buy
690066 1g $233 Buy
B4114 1g $147 Buy
B4114 5g $584 Buy
267147 500mg $317 Buy
267147 1g $440 Buy

6-BROMO-2,2'-BIPYRIDINE Chemical Properties,Uses,Production

Uses

6-Bromo-2,2’-bipyridine is a reagent used in the synthesis of electron transporting layers for OLEDs.

Synthesis

2,6-Dibromopyridine

626-05-1

2-(TRIBUTYLSTANNYL)PYRIDINE

17997-47-6

6-BROMO-2,2'-BIPYRIDINE

10495-73-5

General procedure for the synthesis of 6-bromo-2,2'-bipyridine from 2,6-dibromopyridine and 2-tributylmethylstannylpyridine: 1.5 g (6.33 mmol) of 2,6-dibromopyridine, 3.48 g (9.48 mmol) of 2-tributylmethylstannylpyridine and 0.15 g (0.06 mmol) of tetrakis(triphenylphosphine)palladium (Pd(PPh3)4) were were dissolved in 15 mL of toluene in a two-necked round bottom flask. The reaction mixture was stirred at 80°C for about 24 hours. Upon completion of the reaction, the solvent was removed by evaporation under reduced pressure. The resulting residue was dissolved in dichloromethane and subsequently extracted with 6M hydrochloric acid solution. The aqueous layer was separated and collected, the pH was adjusted by adding ammonia to the aqueous layer and extracted with dichloromethane. The organic layer was separated and dried with anhydrous magnesium sulfate (MgSO4) followed by evaporation under reduced pressure to remove the solvent. Purification by column chromatography (eluent: hexane/ethyl acetate=5:1, v/v) afforded 0.9 g of 6-bromo-2,2'-bipyridine as a white solid (yield: 61%).

References

[1] Organic Letters, 2008, vol. 10, # 6, p. 1091 - 1094
[2] Chemical Communications, 2007, # 42, p. 4401 - 4403
[3] Organometallics, 2017, vol. 36, # 9, p. 1727 - 1735
[4] Patent: KR2015/142709, 2015, A. Location in patent: Paragraph 0473-0475
[5] Inorganic Chemistry, 2013, vol. 52, # 9, p. 5570 - 5580

6-BROMO-2,2'-BIPYRIDINE Preparation Products And Raw materials

Global( 176)Suppliers
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Shanghai UCHEM Inc.
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career henan chemical co
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CD Chemical Group Limited
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Henan Alfa Chemical Co., Ltd
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HANGZHOU LEAP CHEM CO., LTD.
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Changzhou AniKare Pharmatech Co., Ltd.
+86-0519-8359-8696 sales@anikare.com China 9993 58

View Lastest Price from 6-BROMO-2,2'-BIPYRIDINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
6-Bromo-2,2’-bipyridine pictures 2026-08-20 6-Bromo-2,2’-bipyridine
10495-73-5
$193.00-710.00 1g 0.98 10kg Shanghai UCHEM Inc.
6-BROMO-2,2'-BIPYRIDINE  pictures 2026-08-20 6-BROMO-2,2'-BIPYRIDINE
10495-73-5
$1.10 1g 99.00% 100 Tons Min Dideu Industries Group Limited
6-BROMO-2,2'-BIPYRIDINE pictures 2020-01-01 6-BROMO-2,2'-BIPYRIDINE
10495-73-5
$1.00 1KG 99% 200kg Career Henan Chemical Co

6-BROMO-2,2'-BIPYRIDINE Spectrum

6-Bromo-[2,2']bipyridinyl 2-BROMO-6-(2-PYRIDYL)PYRIDINE 6-broMo-2,2'-bipyridine 97% 2-bromo-6-(pyridin-2-yl) pyridine 6-Bromo-2,2'-bipyridyl > 2,2'-Bipyridine, 6-bromo- 6-BROMO-2,2'-BIPYRIDINE ISO 9001:2015 REACH 6-bromo-2,2'-bipyridine 6-Bromo-2,2'-bipyridyl 6-BROMO-2,2'-BIPYRIDINE 10495-73-5 104935-73-5 C10H7BrN2