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2-Amino-4-methylbenzoic acid methyl ester

CAS No.
18595-17-0
Chemical Name:
2-Amino-4-methylbenzoic acid methyl ester
Synonyms
Methyl 4-methylanthranilate;2-Amino-4-methylbenzoic acid methyl ester;Benzoic acid, 2-amino-4-methyl-, methyl ester;2-Amino-4-methylbenzoic acid methyl ester 98%
CBNumber:
CB02244558
Molecular Formula:
C9H11NO2
Molecular Weight:
165.19
MDL Number:
MFCD09998260
MOL File:
18595-17-0.mol
MSDS File:
SDS
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
Methyl2-Amino-4-methylbenzoate M331230 100mg $75
2-Amino-4-methylbenzoicacidmethylester 98% OR321010 1g $63
Methyl 2-amino-4-methylbenzoate 98% 4758-1-07 1g $69
Methyl2-amino-4-methylbenzoate W4018 5g $251
Methyl 2-amino-4-methylbenzoate 95+% 075963 250mg $278
More product size

2-Amino-4-methylbenzoic acid methyl ester Properties

Melting point 35-36℃
Boiling point 269℃
Density 1.132
Flash point 130℃
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 2.42±0.10(Predicted)
Appearance Light yellow to brown Solid

SAFETY

Risk and Safety Statements

HS Code  2916399090

2-Amino-4-methylbenzoic acid methyl ester price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M331230 Methyl2-Amino-4-methylbenzoate 18595-17-0 100mg $75 2021-12-16 Buy
Apolloscientific OR321010 2-Amino-4-methylbenzoicacidmethylester 98% 18595-17-0 1g $63 2021-12-16 Buy
SynQuest Laboratories 4758-1-07 Methyl 2-amino-4-methylbenzoate 98% 18595-17-0 1g $69 2021-12-16 Buy
AK Scientific W4018 Methyl2-amino-4-methylbenzoate 18595-17-0 5g $251 2021-12-16 Buy
Matrix Scientific 075963 Methyl 2-amino-4-methylbenzoate 95+% 18595-17-0 250mg $278 2021-12-16 Buy
Product number Packaging Price Buy
M331230 100mg $75 Buy
OR321010 1g $63 Buy
4758-1-07 1g $69 Buy
W4018 5g $251 Buy
075963 250mg $278 Buy

2-Amino-4-methylbenzoic acid methyl ester Chemical Properties,Uses,Production

Synthesis

Methanol

67-56-1

2-Amino-4-methylbenzoic acid

2305-36-4

2-Amino-4-methylbenzoic acid methyl ester

18595-17-0

1. Concentrated sulfuric acid (1 mL) was added slowly and dropwise to a solution of 2-amino-4-methylbenzoic acid (1.0 g, 6.62 mmol) in anhydrous methanol (10 mL) at 0 °C. 2. The reaction mixture was heated to reflux for 16 hours. 3. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently concentrated under reduced pressure to remove the solvent. 4. The concentrated crude product was diluted with deionized water (25 mL) and the pH was adjusted to basic with sodium bicarbonate solution (10 mL). 5. The aqueous layer was extracted using ethyl acetate (2 x 50 mL) and the organic phase was collected. 6. The organic phases were combined and washed sequentially with deionized water (50 mL) and saturated saline (50 mL). 7. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford methyl 2-amino-4-methylbenzoate (900 mg, 82% yield) as a yellow liquid.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2014, vol. 24, # 3, p. 963 - 968
[2] Tetrahedron, 2009, vol. 65, # 2, p. 563 - 578
[3] Patent: US2011/160231, 2011, A1. Location in patent: Page/Page column 10
[4] Chemische Berichte, 1930, vol. 63, p. 1455,1462
[5] Advanced Synthesis and Catalysis, 2018, vol. 360, # 10, p. 1919 - 1925

2-Amino-4-methylbenzoic acid methyl ester Preparation Products And Raw materials

Global( 86)Suppliers
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Capot Chemical Co.,Ltd.
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Aromsyn Co., Ltd.
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View Lastest Price from 2-Amino-4-methylbenzoic acid methyl ester manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Amino-4-methylbenzoic acid methyl ester pictures 2020-01-01 2-Amino-4-methylbenzoic acid methyl ester
18595-17-0
US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co

2-Amino-4-methylbenzoic acid methyl ester Spectrum

2-Amino-4-methylbenzoic acid methyl ester Methyl 4-methylanthranilate 2-Amino-4-methylbenzoic acid methyl ester 98% Benzoic acid, 2-amino-4-methyl-, methyl ester 18595-17-0