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2-Amino-4-methylbenzoic acid methyl ester

2-Amino-4-methylbenzoic acid methyl ester Structure
2-Amino-4-methylbenzoic acid methyl ester structure
CAS No.
18595-17-0
Chemical Name:
2-Amino-4-methylbenzoic acid methyl ester
Synonyms
Methyl 4-methylanthranilate;2-Amino-4-methylbenzoic acid methyl ester;Benzoic acid, 2-amino-4-methyl-, methyl ester;2-Amino-4-methylbenzoic acid methyl ester 98%
CBNumber:
CB02244558
Molecular Formula:
C9H11NO2
Molecular Weight:
165.19
MDL Number:
MFCD09998260
MOL File:
18595-17-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:58:09
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2-Amino-4-methylbenzoic acid methyl ester Properties

Melting point 35-36℃
Boiling point 269℃
Density 1.132
Flash point 130℃
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 2.42±0.10(Predicted)
Appearance Light yellow to brown Solid

SAFETY

Risk and Safety Statements

HS Code  2916399090

2-Amino-4-methylbenzoic acid methyl ester price More Price(54)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
AstaTech AR2393 METHYL 2-AMINO-4-METHYLBENZOATE 95% 18595-17-0 1G $17 2026-04-30 Buy
AstaTech AR2393 METHYL 2-AMINO-4-METHYLBENZOATE 95% 18595-17-0 5G $59 2026-04-30 Buy
AstaTech AR2393 METHYL 2-AMINO-4-METHYLBENZOATE 95% 18595-17-0 25G $194 2026-04-30 Buy
Activate Scientific AS34588 Methyl 2-amino-4-methylbenzoate 98% 18595-17-0 1g $34 2026-06-04 Buy
Activate Scientific AS34588 Methyl 2-amino-4-methylbenzoate 98% 18595-17-0 5g $105 2026-06-04 Buy
Product number Packaging Price Buy
AR2393 1G $17 Buy
AR2393 5G $59 Buy
AR2393 25G $194 Buy
AS34588 1g $34 Buy
AS34588 5g $105 Buy

2-Amino-4-methylbenzoic acid methyl ester Chemical Properties, Uses, Production

Synthesis

Methanol

67-56-1

2-Amino-4-methylbenzoic acid

2305-36-4

2-Amino-4-methylbenzoic acid methyl ester

18595-17-0

1. Concentrated sulfuric acid (1 mL) was added slowly and dropwise to a solution of 2-amino-4-methylbenzoic acid (1.0 g, 6.62 mmol) in anhydrous methanol (10 mL) at 0 °C. 2. The reaction mixture was heated to reflux for 16 hours. 3. Upon completion of the reaction, the mixture was cooled to room temperature and subsequently concentrated under reduced pressure to remove the solvent. 4. The concentrated crude product was diluted with deionized water (25 mL) and the pH was adjusted to basic with sodium bicarbonate solution (10 mL). 5. The aqueous layer was extracted using ethyl acetate (2 x 50 mL) and the organic phase was collected. 6. The organic phases were combined and washed sequentially with deionized water (50 mL) and saturated saline (50 mL). 7. The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford methyl 2-amino-4-methylbenzoate (900 mg, 82% yield) as a yellow liquid.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2014, vol. 24, # 3, p. 963 - 968
[2] Tetrahedron, 2009, vol. 65, # 2, p. 563 - 578
[3] Patent: US2011/160231, 2011, A1. Location in patent: Page/Page column 10
[4] Chemische Berichte, 1930, vol. 63, p. 1455,1462
[5] Advanced Synthesis and Catalysis, 2018, vol. 360, # 10, p. 1919 - 1925

2-Amino-4-methylbenzoic acid methyl ester Preparation Products And Raw materials

Raw materials

6-Methyl-1H-indole-2,3-dione 2-Amino-4-methylbenzoic acid Sodium bicarbonate Methanol

Preparation Products

2-Amino-4-methylbenzoic acid

2-Amino-4-methylbenzoic acid methyl ester Suppliers

Global Suppliers ( 81)
Supplier Tel Email Country ProdList Advantage
Shanghai Harvest Chemical Industrial Co., Ltd. 15721252604 17321035817 sales@harvest-chem.com China 2829 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Sunway Pharmaceutical Technology Co., Ltd 13761987713 hxzheng@sunwaypharm.cn China 8663 57
Shanghai Topbiochem Technology Co., Ltd 021-58170097 info@topbiochem.com China 9509 58
Nanjing ShengSai Chemical Co., Ltd. 025-85205967 13951876367 shengsaichem@163.com China 818 58
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Quality Control Solutions Ltd. 0755-66853366 13670046396 orders@qcsrm.com China 18188 56
Xinyanhe Pharmatech Co.,Ltd 0519-85252752 15366845260 taihuaren@vip.163.com China 1032 58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 025-66028182 17714375163 yftan@aikonchem.com China 16674 50
Credit Asia Chemical Co., Ltd. +86 (21) 61124340 China 9739 58
Supplier Advantage
Shanghai Harvest Chemical Industrial Co., Ltd. 64
Shanghai Hanhong Scientific Co.,Ltd. 64
Shanghai Sunway Pharmaceutical Technology Co., Ltd 57
Shanghai Topbiochem Technology Co., Ltd 58
Nanjing ShengSai Chemical Co., Ltd. 58
Bide Pharmatech Ltd. 60
Quality Control Solutions Ltd. 56
Xinyanhe Pharmatech Co.,Ltd 58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 50
Credit Asia Chemical Co., Ltd. 58

View Latest Price from 2-Amino-4-methylbenzoic acid methyl ester manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Amino-4-methylbenzoic acid methyl ester pictures 2020-01-01 2-Amino-4-methylbenzoic acid methyl ester
18595-17-0
 $1.00 1KG 99% 200kg Career Henan Chemical Co

2-Amino-4-methylbenzoic acid methyl ester Spectrum

2-Amino-4-methylbenzoic acid methyl ester(18595-17-0)1HNMR

18595-17-0 (2-Amino-4-methylbenzoic acid methyl ester) Related Search:

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2-Amino-4-methylbenzoic acid

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2-Amino-4-methylbenzoic acid methyl ester Methyl 4-methylanthranilate 2-Amino-4-methylbenzoic acid methyl ester 98% Benzoic acid, 2-amino-4-methyl-, methyl ester 18595-17-0