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Bromocyclohexane

CAS No.
108-85-0
Chemical Name:
Bromocyclohexane
Synonyms
CYCLOHEXYL BROMIDE;Cyclohexylbromid;Bromocylohexane;BROMOCYCLOHEXANE;bromo-cyclohexan;BroMocyclohexance;1-Bromocyclohexane;Cyelohexyl bromide;Cyclohexane,bromo-;Bromocyclohexane>
CBNumber:
CB0234782
Molecular Formula:
C6H11Br
Molecular Weight:
163.06
MDL Number:
MFCD00003819
MOL File:
108-85-0.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-10 10:27:01
Product description Number Pack Size Price
Bromocyclohexane 98% 135194 5g $25.3
Bromocyclohexane 98% 135194 1kg $195
Bromocyclohexane >98.0%(GC) B0581 25g $17
Bromocyclohexane >98.0%(GC) B0581 100g $25
Bromocyclohexane 98% 135194 100g $34.9
More product size

Bromocyclohexane Properties

Melting point -57°C
Boiling point 166-167 °C (lit.)
Density 1.324 g/mL at 25 °C (lit.)
vapor density 5.62 (vs air)
refractive index n20/D 1.495(lit.)
Flash point 145 °F
storage temp. Sealed in dry,Room Temperature
solubility Miscible with ethanol, ether, acetone, benzene and carbon tetrachloride.
form Liquid
color Clear colorless to light yellow
Specific Gravity approximate 1.33 (20℃)
Odor Unpleasant Odor
Water Solubility insoluble
Sensitive Air & Light Sensitive
Merck 14,2730
BRN 1098373
Henry's Law Constant 7.0×10-3 mol/(m3Pa) at 25℃, Hilal et al. (2008)
Dielectric constant 7.9(25℃)
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
InChI 1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2
InChIKey AQNQQHJNRPDOQV-UHFFFAOYSA-N
SMILES BrC1CCCCC1
CAS DataBase Reference 108-85-0(CAS DataBase Reference)
FDA UNII YA0UMS4RNY
NIST Chemistry Reference Cyclohexane, bromo-(108-85-0)
EPA Substance Registry System Cyclohexane, bromo- (108-85-0)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335-H227
Precautionary statements  P210-P280-P403+P235-P501-P210e-P261-P280a-P305+P351+P338-P405-P501a
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xn
Risk Statements  36/37/38-20-18-52
Safety Statements  23-24/25-37/39-26
WGK Germany  3
RTECS  GU7171700
8
TSCA  TSCA listed
HS Code  29035990
Storage Class 10 - Combustible liquids
Hazard Classifications Aquatic Chronic 2
NFPA 704
2
1 0

Bromocyclohexane price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 135194 Bromocyclohexane 98% 108-85-0 5g $25.3 2026-04-30 Buy
Sigma-Aldrich 135194 Bromocyclohexane 98% 108-85-0 1kg $195 2026-04-30 Buy
TCI Chemical B0581 Bromocyclohexane >98.0%(GC) 108-85-0 25g $17 2026-04-30 Buy
TCI Chemical B0581 Bromocyclohexane >98.0%(GC) 108-85-0 100g $25 2026-04-30 Buy
Sigma-Aldrich 135194 Bromocyclohexane 98% 108-85-0 100g $34.9 2026-04-30 Buy
Product number Packaging Price Buy
135194 5g $25.3 Buy
135194 1kg $195 Buy
B0581 25g $17 Buy
B0581 100g $25 Buy
135194 100g $34.9 Buy

Bromocyclohexane Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.

Preparation

Bromocyclohexane is synthesized by the reaction of cycloethanol and hydrobromic acid.

Synthesis Reference(s)

Canadian Journal of Chemistry, 50, p. 3109, 1972 DOI: 10.1139/v72-498
Journal of the American Chemical Society, 112, p. 8212, 1990 DOI: 10.1021/ja00178a080
The Journal of Organic Chemistry, 45, p. 1638, 1980 DOI: 10.1021/jo01297a020

General Description

Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.

Purification Methods

Shake the bromide with 60% aqueous HBr to remove the free alcohol. After removing excess HBr, the sample is dried and fractionally distilled. [IR: Roberts & Chambers J Am Chem Soc 73 5031 1951, Beilstein 5 III 48, 5 IV 67.]

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View Lastest Price from Bromocyclohexane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
CYCLOHEXYL BROMIDE pictures 2026-03-20 CYCLOHEXYL BROMIDE
108-85-0
US $1.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
Bromocyclohexane pictures 2025-09-25 Bromocyclohexane
108-85-0
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Bromocyclohexane pictures 2025-06-20 Bromocyclohexane
108-85-0
US $50.00 / kg 1kg 99.9(%) 30 tons Hebei Yanxi Chemical Co., Ltd.
  • Bromocyclohexane pictures
  • Bromocyclohexane
    108-85-0
  • US $50.00 / kg
  • 99.9(%)
  • Hebei Yanxi Chemical Co., Ltd.
BROMOCYCLOHEXANE FOR SYNTHESIS BROMOCYCLOHEXANE Cyelohexyl bromide CYCLOHEXYL BROMIDE 1-Bromocyclohexane bromo-cyclohexan Bromocylohexane Cyclohexane,bromo- BroMine generation of cyclohexane Cyclohexylbromid Hexahydrobromobenzene Bromocyclohexane,98% CYCLOHEXYL BROMIDE 99% (GC) Bromocyclohexane, 95+% Cyclohexyl bromide,99% BroMocyclohexance Bromocyclohexane,Cyclohexyl bromide Cyclohexyl broMide, 99% 250ML Cyclohexyl bromide, 99%, for synthesis Bromocyclohexane> Bromocyclohexane ISO 9001:2015 REACH CYCLOHEXYL BROMIDE For Synthesis Cyclohexyl Bromide 98% For Synthesis 108-85-0 -CH2CH24CHBr 6H11Br Halogenated Hydrocarbons Alkyl Organic Building Blocks HALOGEN Building Blocks Alkyl Building Blocks Chemical Synthesis Pharmaceutical Intermediates Halogen compounds Halogenated Hydrocarbons Organic Building Blocks