Di(1-adaMantyl)chlorophosphine
- CAS No.
- 157282-19-4
- Chemical Name:
- Di(1-adaMantyl)chlorophosphine
- Synonyms
- Bis(tric;Mifepristone Impurity 15;Diadamantylchlorophosphine;Di(1-adaMantyl)chlorophosphine;Bis(1-AdaMantyl)Chlorophosphine;Di(adamantan-1-yl)chlorophosphine;Di-1-adamantylchlorophosphine,97%;bis(1-goldalkaneyl)chlorophosphorus;Bis(1-adamantyl)phosphinous chloride;Diadamantan-1-ylphosphinous chloride
- CBNumber:
- CB02594929
- Molecular Formula:
- C20H30ClP
- Molecular Weight:
- 336.88
- MDL Number:
- MFCD18910707
- MOL File:
- 157282-19-4.mol
- MSDS File:
- SDS
| Melting point | 168-173°C |
|---|---|
| Boiling point | 413.3±12.0 °C(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | solid |
| color | white |
| Sensitive | moisture sensitive |
| InChI | InChI=1S/C20H30ClP/c21-22(19-7-13-1-14(8-19)3-15(2-13)9-19)20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18H,1-12H2 |
| InChIKey | BVOJCPQWSXCCKU-UHFFFAOYSA-N |
| SMILES | P(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)Cl |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
|---|---|
| Signal word | Danger |
| Hazard statements | H261-H314-H317-H351-H372-H373-H420 |
| Precautionary statements | P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P502 |
| Hazard Codes | T,N |
| Risk Statements | 14-23/24/25-34-40-48/23-59 |
| Safety Statements | 26-36/37/39-45-59 |
| RIDADR | UN 3096 4.3(8) / PGII |
| WGK Germany | 3 |
| HS Code | 2932190090 |
Di(1-adaMantyl)chlorophosphine price More Price(23)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 737267 | Di(1-adamantyl)chlorophosphine 97% | 157282-19-4 | 1g | $323 | 2026-04-30 | Buy |
| Sigma-Aldrich | 737267 | Di(1-adamantyl)chlorophosphine 97% | 157282-19-4 | 250mg | $139 | 2023-06-20 | Buy |
| Strem Chemicals | 15-1095 | Di-1-adamantylchlorophosphine, min. 97% min.97% | 157282-19-4 | 250mg | $102 | 2026-04-30 | Buy |
| Strem Chemicals | 15-1095 | Di-1-adamantylchlorophosphine, min. 97% min.97% | 157282-19-4 | 1g | $301 | 2026-04-30 | Buy |
| Biosynth | HGA28219 | Di(1-adamantyl)chlorophosphine | 157282-19-4 | 0.25g | $519.2 | 2026-06-04 | Buy |
Di(1-adaMantyl)chlorophosphine Chemical Properties, Uses, Production
Synthesis
131211-27-3
157282-19-4
General procedure for the synthesis of bis(1-adamantyl)phosphonium chloride from di-1-adamantylphosphine: a solution of Ad2PH (10.5 g, 34.7 mmol) and 1,5-diazabicyclo[5.4.0]undec-5-ene (DBU, 6.12 cm3, 40.9 mmol) in toluene (250 cm3) was cooled to -10 °C. The phosgene solution (30.0 cm3, 56.7 mmol) was added slowly through a cannula and transferred through a measuring cylinder. The reaction produced a highly viscous light yellow suspension. To reduce the viscosity and to facilitate stirring, additional toluene (100 cm3) was added through the cannula. The reaction mixture was filtered through a cannula to give a yellow filtrate. The residue was washed with toluene (2 x 100 cm3), the washings were combined with the original filtrate and the volatiles were removed under vacuum to give a light yellow solid. The solid was washed with pentane (2 x 30 cm3, the wash solution was almost colorless), dried under vacuum and separated in a glove box to give a lemon yellow powdery product in 7.84 g yield, 67%.31P NMR chemical shift: δ= 139 ppm, purity 99%, molecular weight (FW) = 336.88.
References
[1] Chemistry - A European Journal, 2003, vol. 9, # 6, p. 1416 - 1425
[2] Organometallics, 2018, vol. 37, # 19, p. 3243 - 3247
[3] Phosphorus, Sulfur and Silicon and the Related Elements, 1995, vol. 102, # 1-4, p. 211 - 216
[4] Patent: US9802185, 2017, B2. Location in patent: Page/Page column 39
[5] Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 88, # 1-4, p. 241 - 244
Di(1-adaMantyl)chlorophosphine Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| BeiJing Greenchem Technology Co.,Ltd. | 131-21959385 18804271668 | chemrocking@bjgreenchem.com | China | 272 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Sichuan Zhongbang Pharma CO.，LTD | 0830-0830-2585019 13679670161 | sales2@zhongbangst.com | China | 105 | 69 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Beijing VSciChem Technology Co., Ltd. | 13811761079 | vscichem@163.com | China | 271 | 64 |
| T&W GROUP | 021-61551611 13296011611 | contact@trustwe.com | China | 9884 | 58 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 15221275939 | shenlinxing@macklin.cn | China | 15775 | 55 |
| Shanghai Uchem Inc. | 15618758386 15618758386 | sales3@myuchem.com | China | 1994 | 55 |
View Latest Price from Di(1-adaMantyl)chlorophosphine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-06-30 | Di(1-adaMantyl)chlorophosphine
157282-19-4
|
1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2026-06-30 | Di(1-adaMantyl)chlorophosphine
157282-19-4
|
1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2025-04-04 | Di-1-adamantylchlorophosphine
157282-19-4
|
1KG | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- Di(1-adaMantyl)chlorophosphine
157282-19-4
- $0.00
- 99%
- Shaanxi Dideu New Materials Co. Ltd
-
- Di(1-adaMantyl)chlorophosphine
157282-19-4
- $0.00
- 99%
- Shaanxi Dideu New Materials Co. Ltd
-
- Di-1-adamantylchlorophosphine
157282-19-4
- 98%
- Henan Aochuang Chemical Co.,Ltd.
