DL-2-AMINO-3-METHYL-1-BUTANOL
- CAS No.
- 16369-05-4
- Chemical Name:
- DL-2-AMINO-3-METHYL-1-BUTANOL
- Synonyms
- 2-AMINO-3-METHYL-1-BUTANOL;DL-VALINOL;rac-Valinol;DL-Valinol;DL-2-AMINO-3-METHYL-1-BUTANOL;2-AMino-3-Methyl-1-butanol 97%;2-Amino-3-methylbutan-1-ol 95+%;DL-2-Amino-3-methyl-1-butanol,95%;rac-(R*)-3-Methyl-2-amino-1-butanol;rac-(R*)-2-Amino-3-methylbutane-1-ol
- CBNumber:
- CB0327471
- Molecular Formula:
- C5H13NO
- Molecular Weight:
- 103.16
- MDL Number:
- MFCD00004730
- MOL File:
- 16369-05-4.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Amino-3-methyl-1-butanol 97% | 184837 | 1g | $30 |
| 2-Amino-3-methyl-1-butanol 97% | 184837 | 5g | $142 |
| DL-Valinol >98.0%(GC)(T) | V0100 | 1g | $46 |
| DL-Valinol >98.0%(GC)(T) | V0100 | 5g | $115 |
| 2-Amino-3-Methyl-1-Butanol Asreported | 261397 | 5g | $389 |
| More product size | |||
| Melting point | 31-32℃ |
|---|---|
| Boiling point | 75-77 °C8 mm Hg(lit.) |
| Density | 0.936 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 194 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| Water Solubility | Soluble in water |
| form | Liquid |
| pka | 12.82±0.10(Predicted) |
| color | Clear yellow |
| optical activity | 0.3825°(C=1g/100ml ETOH) |
| InChI | InChI=1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3 |
| InChIKey | NWYYWIJOWOLJNR-UHFFFAOYSA-N |
| SMILES | C(O)C(N)C(C)C |
| CAS DataBase Reference | 16369-05-4(CAS DataBase Reference) |
| FDA UNII | F4FX82ATU2 |
| UNSPSC Code | 12352100 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37 | |||||||||
| RIDADR | 2735 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 29221990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
DL-2-AMINO-3-METHYL-1-BUTANOL price More Price(43)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 184837 | 2-Amino-3-methyl-1-butanol 97% | 16369-05-4 | 1g | $30 | 2023-06-20 | Buy |
| Sigma-Aldrich | 184837 | 2-Amino-3-methyl-1-butanol 97% | 16369-05-4 | 5g | $142 | 2023-06-20 | Buy |
| TCI Chemical | V0100 | DL-Valinol >98.0%(GC)(T) | 16369-05-4 | 1g | $46 | 2026-04-30 | Buy |
| TCI Chemical | V0100 | DL-Valinol >98.0%(GC)(T) | 16369-05-4 | 5g | $115 | 2026-04-30 | Buy |
| Usbiological | 261397 | 2-Amino-3-Methyl-1-Butanol Asreported | 16369-05-4 | 5g | $389 | 2026-06-03 | Buy |
DL-2-AMINO-3-METHYL-1-BUTANOL Chemical Properties,Uses,Production
Chemical Properties
CLEAR YELLOW LIQUID
Uses
2-Amino-3-methyl-1-butanol was used in the synthesis of 1-allyl-2-pyrroleimines. It was also used as chiral nucleophile in the total synthesis of benanomicin-pradimicin antibiotics. It was used as homochiral guest compound during synthesis of crown ethers containing two chiral subunits.
Definition
ChEBI: 2-Amino-3-methyl-1-butanol is an amino alcohol.
Synthesis
13292-87-0
516-06-3
16369-05-4
Example 2: To a dry 12 liter glass reaction vessel (with equipment as described in Example 1) was added 900 grams (7.7 moles) of DL-valine and 2.5 liters of tetrahydrofuran. 1.05 liters (8.5 moles) of boron trifluoride diethyl ether compound and 0.85 liters (8.5 moles) of borane-dimethyl sulfide complex were added sequentially according to the method of Example 1, followed by refluxing. The addition process lasted for 8 hours and heating was continued for 3 hours after the addition was completed. The reaction mixture was quenched with 0.75 liters of tetrahydrofuran/water mixture and subsequently hydrolyzed with 24.6 moles of aqueous sodium hydroxide. The product was separated according to the method described in Example 1, resulting in 494 g (62% yield) of 2-amino-3-methyl-1-butanol having a boiling point of 78°-79°C (8 mm), refractive index n20D 1.4543, and a purity of 97% by gas chromatography (glc) analysis.
References
[1] Patent: US3935280, 1976, A
DL-2-AMINO-3-METHYL-1-BUTANOL Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1026@dideu.com | China | 20582 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 | sale03@alfachem.cn | China | 9796 | 58 |
| Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19908 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24597 | 58 |
View Lastest Price from DL-2-AMINO-3-METHYL-1-BUTANOL manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2021-08-12 | DL-2-AMINO-3-METHYL-1-BUTANOL
16369-05-4
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
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2021-07-02 | DL-Valinol
16369-05-4
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
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2020-03-06 | 2-Amino-3-methylbutan-1-ol
16369-05-4
|
$8.00 | 1g | ≥98% | Career Henan Chemical Co |
-

- DL-2-AMINO-3-METHYL-1-BUTANOL
16369-05-4
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- DL-Valinol
16369-05-4
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-

- 2-Amino-3-methylbutan-1-ol
16369-05-4
- $8.00
- ≥98%
- Career Henan Chemical Co
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