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DL-2-AMINO-3-METHYL-1-BUTANOL

CAS No.
16369-05-4
Chemical Name:
DL-2-AMINO-3-METHYL-1-BUTANOL
Synonyms
2-AMINO-3-METHYL-1-BUTANOL;DL-VALINOL;rac-Valinol;DL-Valinol;DL-2-AMINO-3-METHYL-1-BUTANOL;2-AMino-3-Methyl-1-butanol 97%;2-Amino-3-methylbutan-1-ol 95+%;DL-2-Amino-3-methyl-1-butanol,95%;rac-(R*)-3-Methyl-2-amino-1-butanol;rac-(R*)-2-Amino-3-methylbutane-1-ol
CBNumber:
CB0327471
Molecular Formula:
C5H13NO
Molecular Weight:
103.16
MDL Number:
MFCD00004730
MOL File:
16369-05-4.mol
MSDS File:
SDS
Last updated:2026-05-27 17:40:06
Product description Number Pack Size Price
2-Amino-3-methyl-1-butanol 97% 184837 1g $30
2-Amino-3-methyl-1-butanol 97% 184837 5g $142
DL-Valinol >98.0%(GC)(T) V0100 1g $46
DL-Valinol >98.0%(GC)(T) V0100 5g $115
2-Amino-3-Methyl-1-Butanol Asreported 261397 5g $389
More product size

DL-2-AMINO-3-METHYL-1-BUTANOL Properties

Melting point 31-32℃
Boiling point 75-77 °C8 mm Hg(lit.)
Density 0.936 g/mL at 25 °C(lit.)
refractive index n20/D 1.4543(lit.)
Flash point 194 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
Water Solubility Soluble in water
form Liquid
pka 12.82±0.10(Predicted)
color Clear yellow
optical activity 0.3825°(C=1g/100ml ETOH)
InChI InChI=1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3
InChIKey NWYYWIJOWOLJNR-UHFFFAOYSA-N
SMILES C(O)C(N)C(C)C
CAS DataBase Reference 16369-05-4(CAS DataBase Reference)
FDA UNII F4FX82ATU2
UNSPSC Code 12352100

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37
RIDADR  2735
WGK Germany  3
HS Code  29221990
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
2
3 0

DL-2-AMINO-3-METHYL-1-BUTANOL price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 184837 2-Amino-3-methyl-1-butanol 97% 16369-05-4 1g $30 2023-06-20 Buy
Sigma-Aldrich 184837 2-Amino-3-methyl-1-butanol 97% 16369-05-4 5g $142 2023-06-20 Buy
TCI Chemical V0100 DL-Valinol >98.0%(GC)(T) 16369-05-4 1g $46 2026-04-30 Buy
TCI Chemical V0100 DL-Valinol >98.0%(GC)(T) 16369-05-4 5g $115 2026-04-30 Buy
Usbiological 261397 2-Amino-3-Methyl-1-Butanol Asreported 16369-05-4 5g $389 2026-06-03 Buy
Product number Packaging Price Buy
184837 1g $30 Buy
184837 5g $142 Buy
V0100 1g $46 Buy
V0100 5g $115 Buy
261397 5g $389 Buy

DL-2-AMINO-3-METHYL-1-BUTANOL Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

2-Amino-3-methyl-1-butanol was used in the synthesis of 1-allyl-2-pyrroleimines. It was also used as chiral nucleophile in the total synthesis of benanomicin-pradimicin antibiotics. It was used as homochiral guest compound during synthesis of crown ethers containing two chiral subunits.

Definition

ChEBI: 2-Amino-3-methyl-1-butanol is an amino alcohol.

Synthesis

Borane-methyl sulfide complex

13292-87-0

DL-Valine

516-06-3

DL-2-AMINO-3-METHYL-1-BUTANOL

16369-05-4

Example 2: To a dry 12 liter glass reaction vessel (with equipment as described in Example 1) was added 900 grams (7.7 moles) of DL-valine and 2.5 liters of tetrahydrofuran. 1.05 liters (8.5 moles) of boron trifluoride diethyl ether compound and 0.85 liters (8.5 moles) of borane-dimethyl sulfide complex were added sequentially according to the method of Example 1, followed by refluxing. The addition process lasted for 8 hours and heating was continued for 3 hours after the addition was completed. The reaction mixture was quenched with 0.75 liters of tetrahydrofuran/water mixture and subsequently hydrolyzed with 24.6 moles of aqueous sodium hydroxide. The product was separated according to the method described in Example 1, resulting in 494 g (62% yield) of 2-amino-3-methyl-1-butanol having a boiling point of 78°-79°C (8 mm), refractive index n20D 1.4543, and a purity of 97% by gas chromatography (glc) analysis.

References

[1] Patent: US3935280, 1976, A

DL-2-AMINO-3-METHYL-1-BUTANOL Preparation Products And Raw materials

Global( 139)Suppliers
Supplier Tel Email Country ProdList Advantage
Accela ChemBio Inc.
+1-858-6993322 info@accelachem.com United States 21193 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49979 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29792 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 20582 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739 info@dycnchem.com China 52705 58
Henan Alfa Chemical Co., Ltd
+8615838112936 sale03@alfachem.cn China 9796 58
Nextpeptide Inc
+86-0571-81612335 +8613336028439 sales@nextpeptide.com China 19908 58
HANGZHOU LEAP CHEM CO., LTD.
+86-571-87711850 market18@leapchem.com China 24597 58

View Lastest Price from DL-2-AMINO-3-METHYL-1-BUTANOL manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
DL-2-AMINO-3-METHYL-1-BUTANOL pictures 2021-08-12 DL-2-AMINO-3-METHYL-1-BUTANOL
16369-05-4
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
DL-Valinol pictures 2021-07-02 DL-Valinol
16369-05-4
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
2-Amino-3-methylbutan-1-ol pictures 2020-03-06 2-Amino-3-methylbutan-1-ol
16369-05-4
$8.00 1g ≥98% Career Henan Chemical Co
  • DL-Valinol pictures
  • DL-Valinol
    16369-05-4
  • $10.00-15.00
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
DL-VALINOL DL-2-AMINO-3-METHYL-1-BUTANOL 2-Amino-3-methylbutan-1-ol 95+% rac-(R*)-2-Amino-3-methylbutane-1-ol rac-(R*)-3-Methyl-2-amino-1-butanol DL-2-Amino-3-methyl-1-butanol,95% [1-(Hydroxymethyl)-2-methylpropyl]amine N-(1-Hydroxy-3-methylbutan-2-yl)amine rac-Valinol 2-AMino-3-Methyl-1-butanol 97% DL-Valinol DL-2-AMINO-3-METHYL-1-BUTANOL USP/EP/BP 2-AMINO-3-METHYL-1-BUTANOL 16369-05-4 CH32CHCHNH2CH2OH Organic Building Blocks Oxygen Compounds Building Blocks Amino Alcohols