PROPYNYLLITHIUM
- CAS No.
- 4529-04-8
- Chemical Name:
- PROPYNYLLITHIUM
- Synonyms
- PROPYNYLLITHIUM;Einecs 224-862-4;1-PROPYNYLLITHIUM;1-Lithio-1-propyne;prop-1-ynyllithium;Propynyllithium,90+%
- CBNumber:
- CB0405632
- Molecular Formula:
- C3H3Li
- Molecular Weight:
- 46
- MDL Number:
- MFCD00015181
- MOL File:
- 4529-04-8.mol
PROPYNYLLITHIUM Chemical Properties,Uses,Production
Uses
Propynyllithium is a powerful nucleophilic source of the propynyl unit for many electrophiles.
Preparation
Propynyllithium is prepared in situ under nitrogen by reaction of propyne (condensed into cold THF) with n-Butyllithium in THF at -78 °C or Lithium Amide in ether/liquid ammonia below -50 °C, or by reaction of 1,2-dibromopropane with equiv of Lithium Diisopropylamide (double elimination of hydrogen bromide and deprotonation) at -60 °C to 0 °C in THF.
Definition
ChEBI: Prop-1-ynyllithium is an alkynyllithium compound.
storage
Propynyllithium must be prepared and transferred under inert gas (Ar or N2) to exclude oxygen and moisture.
PROPYNYLLITHIUM Preparation Products And Raw materials
Raw materials
Preparation Products
PROPYNYLLITHIUM Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9976 | 60 |
| Shanghai Yolne Chemical Co., Ltd. | 021-62960152 | 934678158@qq.com | China | 9899 | 55 |
| Shanghai WeiNie Chemical Technology Co., Ltd. | 15902145085 | 657990292@qq.com | China | 668 | 50 |
| Guangdong wengjiang Chemical Reagent Co., Ltd. | 0751-2886750 13927877953 | 3005811397@qq.com | China | 13290 | 58 |
| Qiyuan (Guangdong) Pharmaceutical Chemical Co., Ltd. | 18026564465 | 304903156@qq.com | China | 7987 | 58 |
| Huangshi Bo’Er Chemical Co., Ltd. | 0714-6401888 18671400300 | 273568016@qq.com | China | 563 | 58 |
