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2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone

CAS No.
119313-12-1
Chemical Name:
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
Synonyms
369;Irgacure 369;Photoinitiator369;UV-369;IHT-PI 910;Photoinitiator 910;N,N-Dimethyl-α-ethyl-α-benzyl-β-oxo-4-(4-morpholinyl)benzeneethanamine;IC-369;APi-369;YF-PI 369
CBNumber:
CB0412472
Molecular Formula:
C23H30N2O2
Molecular Weight:
366.5
MDL Number:
MFCD00191775
MOL File:
119313-12-1.mol
MSDS File:
SDS
Last updated:2025-08-13 11:09:07
Product description Number Pack Size Price
2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone 97% 405647 25g $80.1
2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone 97% 405647 100g $227.05
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone >98.0%(HPLC)(T) B3914 25g $49
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone >98.0%(HPLC)(T) B3914 100g $156
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone FB63048 50g $200
More product size

2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone Properties

Melting point 116-119 °C (lit.)
Boiling point 528.8±50.0 °C(Predicted)
Density 1.094±0.06 g/cm3(Predicted)
vapor pressure 0-0.01Pa at 25-95℃
Flash point >230 °F
storage temp. Sealed in dry,Room Temperature
solubility 3240 in mg/100g standard fat at 20 ℃
pka 7.04±0.50(Predicted)
form powder to crystal
color Light orange to Yellow to Green
Water Solubility 5.9mg/L at 20℃
InChIKey UHFFVFAKEGKNAQ-UHFFFAOYSA-N
LogP 2.91 at 25℃
CAS DataBase Reference 119313-12-1(CAS DataBase Reference)
FDA UNII 413O6RKS6B
EPA Substance Registry System 1-Butanone, 2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)- (119313-12-1)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS08,GHS09
Signal word  Danger
Hazard statements  H360D-H410
Precautionary statements  P201-P202-P273-P280-P308+P313-P391
Hazard Codes  N
Risk Statements  50/53
Safety Statements  60-61
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  EL7755000
HazardClass  9
PackingGroup  III
HS Code  29349990

2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 405647 2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone 97% 119313-12-1 25g $80.1 2025-07-31 Buy
Sigma-Aldrich 405647 2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone 97% 119313-12-1 100g $227.05 2025-07-31 Buy
TCI Chemical B3914 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone >98.0%(HPLC)(T) 119313-12-1 25g $49 2025-07-31 Buy
TCI Chemical B3914 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone >98.0%(HPLC)(T) 119313-12-1 100g $156 2025-07-31 Buy
Biosynth Carbosynth FB63048 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone 119313-12-1 50g $200 2021-12-16 Buy
Product number Packaging Price Buy
405647 25g $80.1 Buy
405647 100g $227.05 Buy
B3914 25g $49 Buy
B3914 100g $156 Buy
FB63048 50g $200 Buy

2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone Chemical Properties,Uses,Production

Chemical Properties

Light yellow solid

Uses

DBMP can be used as a dopant to dope silicone elastomer for the formation of 3D biocompatible scaffolds. It can also be used in two photon polymerization for the micro-fabrication of 3D hydrogels for potential biomedical and tissue engineering applications.

Uses

UV solidify ink and coating

General Description

2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone (DBMP) is a photoinitiator that acts at near UV and visible range. It can be incorporated into the polymeric matrix, which upon UV irradiation forms radicals by radical chain polymerization.

Synthesis

Morpholine

110-91-8

1-Butanone, 2-(dimethylamino)-1-(4-fluorophenyl)-2-(phenylmethyl)-

119312-61-7

2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone

119313-12-1

General procedure for the synthesis of 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone from 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone and morpholine: 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone was dissolved in ethylene dichloride and transferred to a four-necked flask. Morpholine (139.6 g, 1.6 mol) and 1 L of dichloroethane were added and the reaction was heated to reflux state. The reaction progress was monitored by TLC or high performance liquid chromatography (HPLC). After completion of the reaction, the reaction was cooled to room temperature, the reaction mixture was washed by adding 200 ml of water and stirred for 30 min. After standing and layering, the organic phase was separated. The solvent was recovered by distillation under reduced pressure to obtain the crude product. The crude product was recrystallized from 440 ml of ethanol to give 117.2 g of a light yellow solid product with a melting point of 115-116 °C, an overall yield of 80% and a purity of 99.3%.

References

[1] Patent: CN105384707, 2016, A. Location in patent: Paragraph 0003; 0034

110-91-8
119312-61-7
119313-12-1
Synthesis of 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone from Morpholine and 1-Butanone, 2-(dimethylamino)-1-(4-fluorophenyl)-2-(phenylmethyl)-
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Hu Bei Jiutian Bio-medical Technology CO.,Ltd
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View Lastest Price from 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Photoinitiator 369                                                 pictures 2025-10-17 Photoinitiator 369
119313-12-1
US $0.00 / KG/CTN 20KG 99%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone pictures 2025-10-16 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
119313-12-1
US $5.00 / kg 1kg >99% 200mt/year Jinan Finer Chemical Co., Ltd
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone pictures 2025-10-15 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone
119313-12-1
US $0.00-0.00 / KG 1KG 99% 20tons Wuhan Fortuna Chemical Co.,Ltd
IHT-PI 910 1-(4-Morpholinophenyl)-2-(dimethylamino)-2-benzyl-1-butanone IC-369 Irgacure 369 N,N-Dimethyl-α-ethyl-α-benzyl-β-oxo-4-(4-morpholinyl)benzeneethanamine α-(Dimethylamino)-α-benzyl-4'-morpholinobutyrophenone 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone ,97% 2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-1-butanone 2-Benzyl-2diMethylaMino-1-(4-Morpholinphenyl)butanone Photoinitiator369 369 OMNIRAD 369(former IRGACURE 369 OMNIRAD248 2-benzyl-2-(diMethylaMino)-1-(4-Morpholinophenyl)butan-1-one Omnirad 369 TIMTEC-BB SBB006931 2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-1-butanon 2-benzyl-2-(dimethylamino)-4'-morpholino-butyroph 2-Benzyl-2-(Dimethylamino)-1-[4-(4-Morpholinyl)phenyl]-1-Butanone 1-Butanone, 2-(dimethylamino)-1-4-(4-morpholinyl)phenyl-2-(phenylmethyl)- 2-Benzyl-2-dimethylamino-4′-morpholinobutyrophenon 2-Benzyl-2-dimethylamino-1-(4-morpholino-phenyl)-1-butanone 2-BENZYL-2-DIMETHYLAMINO-1-(4-MORPHOLINOPHENYL)-BUTANONE-1 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone, 97.5% YF-PI 369 Lancure369 -Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone UV-369 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone > 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenChemicalbookone Photo initiator Sunitor 910 Photoinitiator 910 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophen 2-Benzyl-2-dimethylamino-1-(4-morpholinophenyl)butanone UV Absorber Photoinitiator-369 lencolo 5023 Sinocure? 369 / Omnirad 369 / IRGACURE 369 APi-369 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone 2-Benzyl-2-dimethylamino-4-morpholinobutyrophenone in methanol α-Aminoketone(1112) 2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone, CAS 119313-12-1 2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone 2-benzyl-2-(dimethylamino)-4'-morpholino-butyroph 369 119313-12-1 119131-12-1 C23H30N2O2 KETONE chemical additive Acetophenone Organic Photoinitiators Polymerization Initiators