ChemicalBook >> CAS DataBase List >>4-CHLORO-2-METHYLBENZOIC ACID
4-CHLORO-2-METHYLBENZOIC ACID
- CAS No.
- 7499-07-2
- Chemical Name:
- 4-CHLORO-2-METHYLBENZOIC ACID
- Synonyms
- RARECHEM AL BO 0472;4-CHLORO-O-TOLUIC ACID;4-CHLORO-2-METHYLBENZOIC ACID;2-METHYL-4-CHLOROBENZOIC ACID;Benzoic acid,4-chloro-2-methyl-;4-Chloro-2-methylbenzoicacid,98%;4-Chloro-2-methylbenzoic Acid >4-Chloro-2-Methylbenzoic Acid, 97+%;2-Carboxy-5-chlorotoluene, 4-Chloro-o-toluic acid
- CBNumber:
- CB0446338
- Molecular Formula:
- C8H7ClO2
- Molecular Weight:
- 170.59
- MDL Number:
- MFCD00045852
- MOL File:
- 7499-07-2.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-05-20 15:45:07
| Product description | Number | Pack Size | Price |
| 4-Chloro-2-methylbenzoic acid 96% | 634034 | 5g | $114 |
| 4-Chloro-2-methylbenzoic acid 96% | 634034 | 1g | $45 |
| 4-Chloro-2-methylbenzoic Acid >98.0%(GC)(T) | C2508 | 5g | $70 |
| 4-Chloro-2-methylbenzoic Acid >98.0%(GC)(T) | C2508 | 25g | $258 |
| 4-Chloro-2-methylbenzoic acid ≥98%(HPLC) | 27653 | 1G | $18.53 |
| More product size | |||
| Melting point | 167-171 °C (lit.) |
|---|---|
| Boiling point | 300.3±22.0 °C(Predicted) |
| Density | 1.310±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| pka | 3.63±0.25(Predicted) |
| form | Solid |
| color | White |
| InChI | InChI=1S/C8H7ClO2/c1-5-4-6(9)2-3-7(5)8(10)11/h2-4H,1H3,(H,10,11) |
| InChIKey | XXFKOBGFMUIWDH-UHFFFAOYSA-N |
| SMILES | C(O)(=O)C1=CC=C(Cl)C=C1C |
| CAS DataBase Reference | 7499-07-2(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H318 | |||||||||
| Precautionary statements | P280-P301+P312+P330-P305+P351+P338+P310 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-41 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29163990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 |
|||||||||
| NFPA 704 |
|
4-CHLORO-2-METHYLBENZOIC ACID price More Price(41)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 634034 | 4-Chloro-2-methylbenzoic acid 96% | 7499-07-2 | 5g | $114 | 2023-06-20 | Buy |
| Sigma-Aldrich | 634034 | 4-Chloro-2-methylbenzoic acid 96% | 7499-07-2 | 1g | $45 | 2023-01-07 | Buy |
| TCI Chemical | C2508 | 4-Chloro-2-methylbenzoic Acid >98.0%(GC)(T) | 7499-07-2 | 5g | $70 | 2026-04-30 | Buy |
| TCI Chemical | C2508 | 4-Chloro-2-methylbenzoic Acid >98.0%(GC)(T) | 7499-07-2 | 25g | $258 | 2026-04-30 | Buy |
| Chem-Impex | 27653 | 4-Chloro-2-methylbenzoic acid ≥98%(HPLC) | 7499-07-2 | 1G | $18.53 | 2026-05-19 | Buy |
4-CHLORO-2-METHYLBENZOIC ACID Chemical Properties,Uses,Production
Chemical Properties
White to yellow powder or crystal
Uses
4-Chloro-2-methylbenzoic acid can be used in the synthesis of:
- 4-chloro-2-methylbenzophenone via Freidel Craft′s acylation with benzene
- 4-chloro-2-methyl-5-(methylsulfonyl)benzoic acid
- 4-chloro-2-methyl-3-nitrobenzoic acid methyl ester
General Description
4-Chloro-2-methylbenzoic acid can be synthesized from 4-chlorobenzoic acid via a multi-step reaction process.
4-CHLORO-2-METHYLBENZOIC ACID Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 232)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Speranza Chemical Co., Ltd. | +86-86-075521030354 +8618688942810 | sophieliu@speranzachem.com | China | 923 | 55 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8738 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | 52513593@qq.com | CHINA | 2972 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29794 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10000 | 58 |
View Lastest Price from 4-CHLORO-2-METHYLBENZOIC ACID manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-05-22 | 4-CHLORO-2-METHYLBENZOIC ACID
7499-07-2
|
US $0.00-0.00 / KG | 1KG | 97% | 100MT/Year | Speranza Chemical Co., Ltd. | |
![]() |
2026-03-20 | 4-CHLORO-2-METHYLBENZOIC ACID
7499-07-2
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
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2025-12-29 | 4-CHLORO-2-METHYLBENZOIC ACID
7499-07-2
|
US $0.00 / kg | 1kg | 98% | follow your request | Changzhou waston chemical technology Co.,Ltd |
-

- 4-CHLORO-2-METHYLBENZOIC ACID
7499-07-2
- US $0.00-0.00 / KG
- 97%
- Speranza Chemical Co., Ltd.
-

- 4-CHLORO-2-METHYLBENZOIC ACID
7499-07-2
- US $0.00-0.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-

- 4-CHLORO-2-METHYLBENZOIC ACID
7499-07-2
- US $0.00 / kg
- 98%
- Changzhou waston chemical technology Co.,Ltd
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C6H73
Organic Building Blocks
C8
Carboxylic Acids
Carbonyl Compounds
Building Blocks
C8
Carbonyl Compounds
Carboxylic Acids
Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
Benzene series
Benzoic acid






