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(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE

CAS No.
24388-23-6
Chemical Name:
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
Synonyms
4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane;Pinacol phenylboronate;Phenylboronic acid pinacol ester 97%;2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole;(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;M7121;Phenylpinacolborane;(Pinacolboryl)benzene;Pinaryl phenylboronic acid;PHENYL-BORONIC ACID PINACOL ESTER
CBNumber:
CB0459079
Molecular Formula:
C12H17BO2
Molecular Weight:
204.07
MDL Number:
MFCD00966985
MOL File:
24388-23-6.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 22:41:17
Product description Number Pack Size Price
Phenylboronic acid pinacol ester 97% 647098 5g $94.9
Phenylboronic acid pinacol ester 97% 647098 10g $115
2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >98.0%(GC) P1855 5g $46
2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >98.0%(GC) P1855 25g $135
Benzeneboronic acid, pinacol ester ≥95% OR11007 1g $21
More product size

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Properties

Melting point 27-31 °C(lit.)
Boiling point 130°C/20mmHg(lit.)
Density 0.99±0.1 g/cm3(Predicted)
Flash point 225 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form powder to lump
color White to Almost white
InChI 1S/C12H17BO2/c1-11(2)12(3,4)15-13(14-11)10-8-6-5-7-9-10/h5-9H,1-4H3
InChIKey KKLCYBZPQDOFQK-UHFFFAOYSA-N
SMILES CC1(C)OB(OC1(C)C)c2ccccc2
CAS DataBase Reference 24388-23-6(CAS DataBase Reference)
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,Xi
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29319090
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE price More Price(56)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 647098 Phenylboronic acid pinacol ester 97% 24388-23-6 5g $94.9 2026-04-30 Buy
Sigma-Aldrich 647098 Phenylboronic acid pinacol ester 97% 24388-23-6 10g $115 2026-04-30 Buy
TCI Chemical P1855 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >98.0%(GC) 24388-23-6 5g $46 2026-04-30 Buy
TCI Chemical P1855 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >98.0%(GC) 24388-23-6 25g $135 2026-04-30 Buy
Apolloscientific OR11007 Benzeneboronic acid, pinacol ester ≥95% 24388-23-6 1g $21 2026-06-04 Buy
Product number Packaging Price Buy
647098 5g $94.9 Buy
647098 10g $115 Buy
P1855 5g $46 Buy
P1855 25g $135 Buy
OR11007 1g $21 Buy

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Chemical Properties,Uses,Production

Chemical Properties

White to light yellow crystal

Uses

suzuki reaction

Uses

Phenylboronic acid pinacol ester can be used:

  • To prepare sulfinamide derivatives by reacting with diethylaminosulfur trifluoride (DAST) and potassium phenyltrifluoroborate.
  • As a substrate in the study of Suzuki–Miyaura coupling of various aryl iodides over SiliaCatPd(0).

Synthesis Reference(s)

The Journal of Organic Chemistry, 60, p. 7508, 1995 DOI: 10.1021/jo00128a024

General Description

Phenylboronic acid, pinacol ester, also known as boronate ester, is generally used in metal-catalyzed C-C bond formation reactions like Suzuki–Miyaurareaction.

Global( 241)Suppliers
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View Lastest Price from (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE pictures 2025-04-04 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
24388-23-6
1KG 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE pictures 2021-08-12 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
24388-23-6
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE pictures 2021-07-13 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE
24388-23-6
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd

(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Spectrum

Phenylpinacolborane 1,3,2-Dioxaborolane,4,4,5,5-tetraMethyl-2-phenyl- (Pinacolboryl)benzene Phenylboronic acid pinacol ester 97% cyclic tetramethylethylene ester benzeneboronic acid PHENYL-BORONIC ACID PINACOL ESTER Benzeneboronic acid, pinacol ester (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)- 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene Phenylboronic Acid Pinacol Ester 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane> M7121 (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborola 24388-23-6 (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Phenylboronic acid pinacol ester, 97%, (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane Pinacol phenylboronate Pinaryl phenylboronic acid 24388-23-6 C12H17BNO2 Aryl Boronic Acids and Derivatives Boronate Esters Organometallic Reagents