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(+)-10-CAMPHORSULFONIMINE

(+)-10-CAMPHORSULFONIMINE structure

CAS No.: 107869-45-4

Chemical Name:: (+)-10-CAMPHORSULFONIMINE

Synonyms: (+)-10-Camphorsulfonimine;(1R)-(+)-CAMPHORSULFONYLIMINE;(+)-10-CAMPHORSULFONIMINE 97+%;(R)-(+)-10-Camphorsulfonylimine;(1R)-(+)-(10-CAMPHORSULFONYL)IMINE;(7R)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DEC-4-ENE-3,3-DIOXIDE;(7R)-(+)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DEC-4-ENE 3,3-DIOXIDE;(1R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide;(7R)-(+)-10,10-DIMETHYL-5-THIA-4-AZATRICYCLO[5.2.1.0(3,7)]DEC-3-ENE-5,5-DIOXIDE;(3aR,6S)-8,8-dimethyl-4,5,6,7-tetrahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide

CBNumber:: CB0459781

Molecular Formula:: C10H15NO2S

Molecular Weight:: 213.3

MDL Number:: MFCD00064576

MOL File:: 107869-45-4.mol

MSDS File:: SDS

Last updated:2025-07-24 18:13:42

Product description	Number	Pack Size	Price
(+)-10-Camphorsulfonimine >97.0%(N)	C1391	5g	$118
(+)-10-Camphorsulfonimine	C175138	50mg	$45
(1R)-(+)-(10-Camphorsulfonyl)imine	FC19654	2g	$130
(1R)-(+)-(10-Camphorsulfonyl)imine	FC19654	1g	$80
(+)-10-Camphorsulfonimine	J51512	25g	$180
More product size

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(+)-10-CAMPHORSULFONIMINE Properties

Melting point	229-230 °C(lit.)
Boiling point	337℃
Density	1.50
refractive index	31 ° (C=2, CHCl3)
Flash point	158℃
storage temp.	Sealed in dry,Room Temperature
solubility	Acetone, Dichloromethane, Hot Methanol
pka	-1.63±0.40(Predicted)
form	Solid
color	White Cyrstalline
InChI	InChI=1S/C10H15NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7H,3-6H2,1-2H3/t7-,10-/m0/s1
InChIKey	ZAHOEBNYVSWBBW-XVKPBYJWSA-N
SMILES	N1=C2[C@@]3(C(C)(C)[C@]([H])(C2)CC3)CS1(=O)=O
CAS DataBase Reference	107869-45-4

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P305+P351+P338

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany

HS Code

2934.99.9001

NFPA 704

	0
2		0

(+)-10-CAMPHORSULFONIMINE price More Price(23)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	C1391	(+)-10-Camphorsulfonimine >97.0%(N)	107869-45-4	5g	$118	2026-03-19	Buy
TRC	C175138	(+)-10-Camphorsulfonimine	107869-45-4	50mg	$45	2021-12-16	Buy
Biosynth Carbosynth	FC19654	(1R)-(+)-(10-Camphorsulfonyl)imine	107869-45-4	2g	$130	2021-12-16	Buy
Biosynth Carbosynth	FC19654	(1R)-(+)-(10-Camphorsulfonyl)imine	107869-45-4	1g	$80	2021-12-16	Buy
AK Scientific	J51512	(+)-10-Camphorsulfonimine	107869-45-4	25g	$180	2021-12-16	Buy

Product number	Packaging	Price	Buy
C1391	5g	$118	Buy
C175138	50mg	$45	Buy
FC19654	2g	$130	Buy
FC19654	1g	$80	Buy
J51512	25g	$180	Buy

(+)-10-CAMPHORSULFONIMINE Chemical Properties,Uses,Production

Chemical Properties

White Cyrstalline Solid

Uses

A useful synthetic intermediate. Used for asymmetric hydroxylation.

Uses

(+)-10-CAMPHORSULFONIMINE is a useful synthetic intermediate,it is used for asymmetric hydroxylation.

Synthesis

72597-34-3

107869-45-4

Example 1; Synthesis of (1R)-(+)-2,10-camphorsulfonamide (Scheme 3,3-1): Thionyl chloride (0.896 kg, 7.5 mol) was slowly added to a solution of (-)-camphorsulfonic acid (1.45 kg, 6.25 mol) in chloroform (7 L) over a period of 1 hour under refluxing conditions. The reaction mixture was refluxed for 16 h and then cooled to 4 °C using an ice bath. The cooled reaction mixture was slowly added to concentrated NH4OH (15 L) while controlling the rate of addition to keep the temperature below 15 °C. After the addition was completed, the mixture was stirred at room temperature for 4 hours. The organic layer was separated and the aqueous layer was extracted with chloroform (2 x 2 L). The combined organic extracts were washed with brine (4 L) and dried over MgSO4. After filtration, the filtrate was concentrated in vacuum and dried to give 1.2 kg (83% yield) of camphorsulfonamide. In another experiment, a comparable yield was obtained using 145 g scale of camphorsulfonamide with dichloromethane replacing chloroform for reaction and extraction. To a suspension of camphorsulfonamide (1.2 kg, 5.2 mol) in toluene (15 L) was added Amberlyst H+ resin (150 g), and the mixture was heated and refluxed for 4 hr while the resulting water was removed by azeotropic boiling using a Dean-Stark water separator. The reaction mixture was hot filtered to remove the resin. Cooling of the filtrate yielded a white solid, which was collected by filtration to give 1.02 kg (92% yield) of the target imine. To an ethanol (0.75 L) solution of the above imine (100 g, 0.47 mol) was added Raney nickel (100 g) and the mixture was hydrogenated at 40 psi for 2 hours. The catalyst was removed by filtration and the filtrate was concentrated in vacuum to give product 3-1 as a white solid.

References

[1] Tetrahedron, 1986, vol. 42, # 14, p. 4035 - 4044
[2] Chemical Communications, 1998, # 15, p. 1549 - 1550
[3] Journal of the American Chemical Society, 1988, vol. 110, p. 8477
[4] Patent: US2006/128789, 2006, A1. Location in patent: Page/Page column 7
[5] Organic Process Research and Development, 2005, vol. 9, # 2, p. 193 - 197

(+)-10-CAMPHORSULFONIMINE synthesis

Synthesis of (+)-10-CAMPHORSULFONIMINE from (2S)-Bornane-10,2-sultam

(+)-10-CAMPHORSULFONIMINE Preparation Products And Raw materials

Raw materials

(2S)-Bornane-10,2-sultam (1R)-10-CAMPHORSULFONAMIDE Toluene

Preparation Products

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

(+)-10-CAMPHORSULFONIMINE Suppliers

Global( 94)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29794	58
HANGZHOU CLAP TECHNOLOGY CO.,LTD	86-571-88216897,88216896 13588875226	sales@hzclap.com	CHINA	6312	58
Finetech Industry Limited	+86-27-8746-5837 +8619945049750	info@finetechnology-ind.com	China	9541	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +8618949823763	sales@tnjchem.com	China	25356	58
Wuhan Han Sheng New Material Technology Co.，Ltd	+8617798174412	admin01@hsnm.com.cn	China	2097	58
HANGZHOU LEAP CHEM CO., LTD.	+86-571-87711850	market18@leapchem.com	China	43333	58
Aladdin Scientific		tp@aladdinsci.com	United States	52923	58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.	+8618950047208	ellena@amitychem.com	China	43416	58

Supplier	Advantage
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
HANGZHOU CLAP TECHNOLOGY CO.,LTD	58
Finetech Industry Limited	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Wuhan Han Sheng New Material Technology Co.，Ltd	58
HANGZHOU LEAP CHEM CO., LTD.	58
Aladdin Scientific	58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.	58

View Lastest Price from (+)-10-CAMPHORSULFONIMINE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-14	(+)-10-CAMPHORSULFONIMINE 107869-45-4	US $9.80 / KG	1g	≥99%	100kg	Career Henan Chemical Co

(+)-10-CAMPHORSULFONIMINE
107869-45-4
US $9.80 / KG
≥99%
Career Henan Chemical Co

(+)-10-CAMPHORSULFONIMINE Spectrum

(+)-10-CAMPHORSULFONIMINE(107869-45-4)MS (+)-10-CAMPHORSULFONIMINE(107869-45-4)¹HNMR (+)-10-CAMPHORSULFONIMINE(107869-45-4)¹³CNMR (+)-10-CAMPHORSULFONIMINE(107869-45-4)IR1 (+)-10-CAMPHORSULFONIMINE(107869-45-4)IR2

107869-45-4((+)-10-CAMPHORSULFONIMINE)Related Search:

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(S)-(+)-(2-BUTENOYL)-2 10-CAMPHORSULTAM (R)-(-)-(2-Methylacryloyl)-2,10-camphorsultam (S)-(+)-(2-Methylacryloyl)-2,10-camphorsultam (+)-10-CAMPHORSULFONIMINE 2-Ethyl-1-hexanethiol

(1S)-(-)-(10-CAMPHORSULFONYL)IMINE,(-)-10-CAMPHORSULFONIMINE Ethanesulfonamide PROPANE-1-SULFONAMIDE 1-HEXANESULFONAMIDE 4-04-00-00045 (Beilstein Handbook Reference)

1-PENTANESULFONAMIDE CYCLOHEXYLMETHYL MERCAPTAN 1-HEPTANESULFONAMIDE

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(1R)-(+)-CAMPHORSULFONYLIMINE (1R)-(+)-(10-CAMPHORSULFONYL)IMINE (3aR,6S)-8,8-Dimethyl-4,5,6,7-tetrahydro-3H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide (1R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide (1R)-(+)-Camphorsulfonylimine, (3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide (3aR,6S)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide (7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]dec-4-ene 3,3-Dioxide (3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-Dioxide (3AR)-(+)-4,5,6,7-TETRAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE 2,2-DIOXIDE (3AR)-4,5,6,7-TETRAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE-2,2-DIOXIDE (7R)-(+)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DEC-4-ENE 3,3-DIOXIDE (7R)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DEC-4-ENE-3,3-DIOXIDE (7R)-(+)-10,10-DIMETHYL-5-THIA-4-AZATRICYCLO[5.2.1.0(3,7)]DEC-3-ENE-5,5-DIOXIDE (+)-10-CAMPHORSULFONIMINE 97+% (R)-(+)-10-Camphorsulfonylimine 3H-3a,6-Methano-2,1-benzisothiazole, 4,5,6,7-tetrahydro-8,8-dimethyl-, 2,2-dioxide, (3aR,6S)- (+)-10-Camphorsulfonimine (3aR,6S)-8,8-dimethyl-4,5,6,7-tetrahydro-3a,6-methano-2,1-benzothiazole 2,2-dioxide 107869-45-4 107869-45-5 Organic Building Blocks Sulfonimides/Sulfinimides Terpenes Bicyclic Monoterpenes Asymmetric Synthesis Chiral Building Blocks Chiral Reagents Bicyclic Monoterpenes Biochemistry Terpenes Intermediates & Fine Chemicals Pharmaceuticals