2-BROMO-4-ETHYLPHENOL
- CAS No.
- 64080-15-5
- Chemical Name:
- 2-BROMO-4-ETHYLPHENOL
- Synonyms
- 2-BROMO-4-ETHYLPHENOL;Phenol, 2-bromo-4-ethyl-
- CBNumber:
- CB0658085
- Molecular Formula:
- C8H9BrO
- Molecular Weight:
- 201.06
- MDL Number:
- MFCD01593653
- MOL File:
- Mol file
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362+P364-P403+P233-P501c |
2-BROMO-4-ETHYLPHENOL price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | B613705 | 2-bromo-4-ethylphenol | 64080-15-5 | 100mg | $60 | 2021-12-16 | Buy |
| Matrix Scientific | 024165 | 2-Bromo-4-ethylphenol | 64080-15-5 | 1g | $306 | 2021-12-16 | Buy |
| Matrix Scientific | 024165 | 2-Bromo-4-ethylphenol | 64080-15-5 | 500mg | $199 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | HCH0043544 | 2-BROMO-4-ETHYLPHENOL 95.00% | 64080-15-5 | 500MG | $795.8 | 2021-12-16 | Buy |
| AK Scientific | 7273AE | 2-Bromo-4-ethylphenol | 64080-15-5 | 5g | $348 | 2021-12-16 | Buy |
2-BROMO-4-ETHYLPHENOL Chemical Properties,Uses,Production
Synthesis
123-07-9
64080-15-5
The general procedure for the synthesis of 2-bromo-4-ethylphenol from 4-ethylphenol was as follows: bromine (11.6 mL, 0.23 mol) was slowly added dropwise to a cooled solution of 4-ethylphenol (25 g, 0.21 mol) in dichloromethane (125 mL) at 0°C. After the dropwise addition was completed, the reaction mixture was continued to be stirred for 5 min, followed by quenching the reaction with 1N NaOH solution. The reaction mixture was diluted with water and the organic and aqueous layers were separated. The organic layer was concentrated to give an orange colored oil. Purification by fast column chromatography (eluent: hexane/ethyl acetate, 0 to 5% gradient) afforded 2-bromo-4-ethylphenol (42 g, 98% yield) as a clear oil. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 1.20 (t, J = 7.6 Hz, 3H), 2.58 (q, J = 7.5 Hz, 2H), 5.36 (s, 1H), 6.93 (d, J = 8.3 Hz, 1H), 7.03 (d, J = 8.3 Hz, 1H), 7.28 (s, 1H).
References
[1] Patent: WO2004/74270, 2004, A2. Location in patent: Page 348
[2] Patent: US2005/176701, 2005, A1. Location in patent: Page/Page column 169-170
[3] Australian Journal of Chemistry, 2003, vol. 56, # 11, p. 1099 - 1106
[4] Bioorganic and Medicinal Chemistry, 2014, vol. 22, # 24, p. 6908 - 6917
[5] Chemistry - A European Journal, 2018, vol. 24, # 62, p. 16516 - 16520
2-BROMO-4-ETHYLPHENOL Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14447 | 58 |
| Shanxi Xuanran Import and Export Trade Co., Ltd. | +8617735180244 | mike_yan@xuanranglobal.com | CHINA | 4017 | 58 |
| CR Corporation Limited | +8613062833949 | fred.wen@crcorporation.cn | China | 8647 | 58 |
| Changzhou Helios Biomedical Science and Technology Co.,LTD. | +8618961213068 | gaoxue@czhelios.com | China | 512 | 58 |
| Labnetwork lnc. | +86-27-50766799 +8618062016861 | contact@labnetwork.com | China | 19987 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 | CB@aromsyn.com | China | 19183 | 58 |
| Aceschem Inc. | +1-817863-6948 +1-（817）863-6948 | sales@aceschem.com | United States | 19632 | 58 |
