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Ethyl carbazate

CAS No.
4114-31-2
Chemical Name:
Ethyl carbazate
Synonyms
ETHYL HYDRAZINECARBOXYLATE;Ethyl carbazinate;HYDRAZINOCARBOXYLIC ACID ETHYL ESTER;AKOS 90785;ETHYL CARBAZATE;ethylecarbazate;ethylcarbazinate;Ethyl Carbazatecas;Carbethoxyhydrazine;Ethyl carbazate 97%
CBNumber:
CB0697565
Molecular Formula:
C3H8N2O2
Molecular Weight:
104.11
MDL Number:
MFCD00007595
MOL File:
4114-31-2.mol
MSDS File:
SDS
Last updated:2026-05-27 22:54:20
Product description Number Pack Size Price
Ethyl carbazate 97% E16503 25g $83.5
Ethyl Carbazate >99.0%(T) C1097 25g $86
Ethyl Carbazate >99.0%(T) C1097 500g $1032
Ethyl Carbazate TRC-E900950-5G 5g $154
Ethyl Carbazate TRC-E900950-50G 50g $212
More product size

Ethyl carbazate Properties

Melting point 44-47 °C (lit.)
Boiling point 108-110 °C/22 mmHg (lit.)
Density 1.2719 (rough estimate)
refractive index 1.4715 (estimate)
Flash point 187 °F
storage temp. Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka 10.72±0.20(Predicted)
form Powder
color White to cream
Water Solubility Very soluble in water.
Sensitive Moisture Sensitive
BRN 878265
InChI 1S/C3H8N2O2/c1-2-7-3(6)5-4/h2,4H2,1H3,(H,5,6)
InChIKey VYSYZMNJHYOXGN-UHFFFAOYSA-N
SMILES CCOC(=O)NN
CAS DataBase Reference 4114-31-2(CAS DataBase Reference)
NIST Chemistry Reference Hydrazinecarboxylic acid, ethyl ester(4114-31-2)
EPA Substance Registry System Hydrazinecarboxylic acid, ethyl ester (4114-31-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xi,T
Risk Statements  36/37/38-25
Safety Statements  26-36-45
RIDADR  2811
WGK Germany  3
RTECS  FE2545000
TSCA  TSCA listed
HazardClass  6.1
PackingGroup  III
HS Code  29280090
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
2
3 1

Ethyl carbazate price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich E16503 Ethyl carbazate 97% 4114-31-2 25g $83.5 2026-04-30 Buy
TCI Chemical C1097 Ethyl Carbazate >99.0%(T) 4114-31-2 25g $86 2026-04-30 Buy
TCI Chemical C1097 Ethyl Carbazate >99.0%(T) 4114-31-2 500g $1032 2026-04-30 Buy
TRC TRC-E900950-5G Ethyl Carbazate 4114-31-2 5g $154 2026-06-03 Buy
TRC TRC-E900950-50G Ethyl Carbazate 4114-31-2 50g $212 2026-06-03 Buy
Product number Packaging Price Buy
E16503 25g $83.5 Buy
C1097 25g $86 Buy
C1097 500g $1032 Buy
TRC-E900950-5G 5g $154 Buy
TRC-E900950-50G 50g $212 Buy

Ethyl carbazate Chemical Properties,Uses,Production

Chemical Properties

Off-white crystals.

Uses

Synthetic intermediate.

Uses

Prepare 4-phenylurazole from ethyl carbazate and then oxidize the urazole with gaseous dinitrogen tetroxide to yield 4-phenyl-1,2,4-tri- azoline-3,5-dione la. Modification of the ethyl carbazate procedure in which analytically pure monoalkylhydrazine hydrochlorides were isolated in greater than 90% yield, starting from a ketone or aldehyde. Treatment of primary amines is with chloroamine or hydroxylamine-0-sulfonic acid and the condensation of a carbonyl compound with ethyl carbazate. The FeCl 3 -catalyzed reaction of ethyl carbazate (2 b) proceeded readily to give β-hydroxyester 3 b in better yield. A new one-pot neat synthesis of some 5-aryl-2,4-dihydro-3H-1,2,4-triazol-3-ones through cyclocondensation of ethyl carbazate with aryl nitriles catalyzed by DMAP as an efficient and basic nucleophilic catalyst is described.

Hazard

Irritant.

Purification Methods

Fractionate the carbazate using a Vigreux column (p 11) until the distillate crystallises [Allen & Bell Org Synth Coll Vol III 404 1955, Beilstein 3 IV 174].

Global( 304)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd
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Hebei Chuanghai Biotechnology Co,.LTD
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Henan Tianfu Chemical Co.,Ltd.
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Tianjin Zhongxin Chemtech Co., Ltd.
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Alchem Pharmtech,Inc.
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CONIER CHEM AND PHARMA LIMITED
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career henan chemical co
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SIMAGCHEM CORP
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View Lastest Price from Ethyl carbazate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl carbazate pictures 2026-06-12 Ethyl carbazate
4114-31-2
1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Ethyl Carbazatecas pictures 2026-05-28 Ethyl Carbazatecas
4114-31-2
$5.70 10KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
Ethyl carbazate pictures 2026-03-20 Ethyl carbazate
4114-31-2
$10.00 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
(Ethoxycarbonyl)hydrazide (Monocarbethoxy)hydrazine 1-(Carbethoxy)hydrazine 1-(Ethoxycarbonyl)hydrazine AKOS 90785 Ethoxycarbonylhydrazine~Ethyl hydrazinocarboxylate ETHOXY CARBONYLHYDRAZINE ETHOXY FORMHYDRAZINE ETHYL CARBAZATE ETHYL HYDRAZINE-1-CARBOXYLATE HYDRAZINOCARBOXYLIC ACID ETHYL ESTER HYDRAZINOFORMIC ACID ETHYL ESTER CARBAZIC ACID ETHYL ESTER CARBOETHOXY HYDRAZINE Ethyl N-aminocarbamate Ethyl carbazate ,97% Carbazinic acid ethyl Hydrazinecarboxylic acid ethyl N-Aminocarbamic acid ethyl ester ETHOXY FORMYL HYDRAZINE Ethoxycarbonylhydrazine Carbazic Acid Ethyl Ester 1-carbethoxyhydrazine Carbethoxyhydrazine ethoxycarbonylhydrazide ethylcarbazinate ethylhydrazinocarboxylate hydrazinecarboxylicacid,ethylester monocarbethoxyhydrazine N-(Carbethoxy)hydrazine N-(Ethoxycarbonyl)hydrazine Ethyl carbazate 97% Hydrazine ethyl forMate ethylecarbazate Ethyl Carbazate > Ethyl Carbazatecas 4114-31-2 Hydrazinecarboxylicacid, ethyl ester Ethyl hydrazine formate ETHYL HYDRAZINECARBOXYLATE Ethyl carbazinate 4114-31-2 H2NNHCO2C2H5 ACETATE Building Blocks Carbonyl Compounds Nitrogen Compounds Protected Amines Organic Building Blocks Hydrazides Pharmaceutical Intermediates Miscellaneous Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Protected Amines bc0001