4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE
- CAS No.
- 80745-07-9
- Chemical Name:
- 4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE
- Synonyms
- MTR-CL;MTR CHLORIDE;4-METHOXY-2,3,6-TRIMETHYLBENZENE-;4-Methoxy-2,3,6-trimethylphenylaulfomyl chloride;4-METHOXY-2,3,6-TRIMETHYLPHENYLSULFONYL CHLORIDE;4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE;4-METHOXY-2,3,6-TRIMETHYLBENZENESULPHONYL CHLORIDE;Benzenesulfonyl chloride, 4-methoxy-2,3,6-trimethyl-;4-METHOXY-2,3,6-TRIMETHYLBENZENE-SULFONYL CHLORIDE 97+%;Benzenesulfonyl chloride, 4-methoxy-2,3,6-trimethyl- (9CI)
- CBNumber:
- CB0732743
- Molecular Formula:
- C10H13ClO3S
- Molecular Weight:
- 248.73
- MDL Number:
- MFCD00038846
- MOL File:
- 80745-07-9.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 4-Methoxy-2,3,6-trimethylbenzenesulfonyl chloride ≥95.0% (HPLC) | 65373 | 10G | $407 |
| 4-Methoxy-2,3,6-trimethylbenzenesulfonyl chloride 95% | 6762-5-21 | 1g | $98 |
| 4-Methoxy-2,3,6-trimethylbenzenesulfonylchloride,tech. | 2755AL | 1g | $147 |
| 4-Methoxy-2,3,6-trimethylbenzenesulfonylchloride,tech. | 2755AL | 5g | $344 |
| 4-Methoxy-2,3,6-trimethylbenzenesulfonylchloride,tech. | 2755AL | 25g | $882 |
| Melting point | 57-61 °C |
|---|---|
| Boiling point | 372.5±42.0 °C(Predicted) |
| Density | 1.250±0.06 g/cm3(Predicted) |
| storage temp. | -20°C |
| Sensitive | Moisture Sensitive |
| BRN | 4867665 |
| Major Application | peptide synthesis |
| InChI | 1S/C10H13ClO3S/c1-6-5-9(14-4)7(2)8(3)10(6)15(11,12)13/h5H,1-4H3 |
| InChIKey | DWLYVEYCCPEHLX-UHFFFAOYSA-N |
| SMILES | COc1cc(C)c(c(C)c1C)S(Cl)(=O)=O |
| CAS DataBase Reference | 80745-07-9(CAS DataBase Reference) |
| UNSPSC Code | 12352200 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3261 8/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10-21 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29093090 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Skin Corr. 1B | |||||||||
| NFPA 704 |
|
4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 65373 | 4-Methoxy-2,3,6-trimethylbenzenesulfonyl chloride ≥95.0% (HPLC) | 80745-07-9 | 10G | $407 | 2023-01-07 | Buy |
| SynQuest Laboratories | 6762-5-21 | 4-Methoxy-2,3,6-trimethylbenzenesulfonyl chloride 95% | 80745-07-9 | 1g | $98 | 2021-12-16 | Buy |
| AK Scientific | 2755AL | 4-Methoxy-2,3,6-trimethylbenzenesulfonylchloride,tech. | 80745-07-9 | 1g | $147 | 2021-12-16 | Buy |
| AK Scientific | 2755AL | 4-Methoxy-2,3,6-trimethylbenzenesulfonylchloride,tech. | 80745-07-9 | 5g | $344 | 2021-12-16 | Buy |
| AK Scientific | 2755AL | 4-Methoxy-2,3,6-trimethylbenzenesulfonylchloride,tech. | 80745-07-9 | 25g | $882 | 2021-12-16 | Buy |
4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE Chemical Properties,Uses,Production
Uses
peptide synthesis
Synthesis
20469-61-8
80745-07-9
(2) Synthesis of 4-methoxy-2,3,6-trimethylbenzenesulfonyl chloride: 4.5 g of 2,3,5-trimethylanisole was dissolved in 500 mL of dichloromethane and the reaction system was cooled to -5 °C to -10 °C. The reaction system was then cooled to -5 °C to -10 °C. The reaction system was then cooled to -5 °C to -10 °C. Subsequently, 6.0 mL of a dichloromethane solution of chlorosulfonic acid (400 mL) was added slowly and dropwise. After completion of the reaction mixture with stirring at room temperature, the reaction was quenched by pouring it into an ice-5% aqueous NaHCO3 solution. The organic phase was separated and the aqueous phase was extracted with dichloromethane. The organic layers were combined, washed with water and dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure and the residue was recrystallized by hexane and filtered to give white crystals. Yield 5.0 g (yield 67.0%), melting point 56°C-58°C. Elemental analysis (C10H13O3SCl) Calculated values: C, 48.29; H, 5.27; S, 12.89; Cl, 14.26; Measured values: C, 48.42; H, 5.21; S, 12.61; Cl, 14.25.
References
[1] Chemical & Pharmaceutical Bulletin, 1981, vol. 29, # 10, p. 2825 - 2831
[2] Tetrahedron Letters, 2007, vol. 48, # 8, p. 1337 - 1340
[3] Patent: US4368150, 1983, A
[4] Patent: US4476051, 1984, A
4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10405 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29795 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14343 | 58 |
| GL Biochem (Shanghai) Ltd. | +86-021-61263370 +86-18901917034 | CHINA | 3904 | 58 | |
| GL Biochem(Binhai) Ltd. | +86-021-61263370 +8615301650015 | wuqiuyan@glschina.com | China | 2975 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| CD Chemical Group Limited | +8615986615575 | info@codchem.com | China | 17259 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 | alfa10@alfachem.cn | China | 12920 | 58 |
View Lastest Price from 4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2021-08-12 | 4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE
80745-07-9
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2020-01-14 | 4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE
80745-07-9
|
US $7.00 / KG | 1KG | 99% | 1000kg | Career Henan Chemical Co |
-
- 4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE
80745-07-9
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 4-METHOXY-2,3,6-TRIMETHYLBENZENESULFONYL CHLORIDE
80745-07-9
- US $7.00 / KG
- 99%
- Career Henan Chemical Co
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