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ChemicalBook >> CAS DataBase List >>3-BROMO-4-HYDROXYBENZALDEHYDE

3-BROMO-4-HYDROXYBENZALDEHYDE

3-BROMO-4-HYDROXYBENZALDEHYDE Structure
3-BROMO-4-HYDROXYBENZALDEHYDE structure
CAS No.
2973-78-6
Chemical Name:
3-BROMO-4-HYDROXYBENZALDEHYDE
Synonyms
2-Bromo-4-formylphenol;AKOS B029029;ASISCHEM N48923;3-BROMO-4-HYROXYBENZALDEHYDE;4-Hydroxy-3-bromobenzaldehyde;3-BROMO-4-HYDROXYBENZALDEHYDE;3-bromo-4-hydroxy benzeldehyde;3-Bromo-4-hydroxybenza I dehyde;Benzaldehyde, 3-bromo-4-hydroxy-;3-Bromo-4-hydroxybenzaldehyde >
CBNumber:
CB0755290
Molecular Formula:
C7H5BrO2
Molecular Weight:
201.02
MDL Number:
MFCD00017348
MOL File:
2973-78-6.mol
MSDS File:
SDS
Last updated:2025-07-24 18:13:45
Product description Number Pack Size Price
3-Bromo-4-hydroxybenzaldehyde 97% 516775 5g $45.6
3-Bromo-4-hydroxybenzaldehyde >98.0%(T) B2350 5g $59
3-Bromo-4-hydroxybenzaldehyde B415380 25g $170
3-Bromo-4-hydroxybenzaldehyde B415380 5g $45
3-Bromo-4-hydroxybenzaldehyde J91451 5g $14
More product size
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3-BROMO-4-HYDROXYBENZALDEHYDE Properties

Melting point 130-135 °C (lit.)
Boiling point 261.3±20.0 °C(Predicted)
Density 1.737±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly, Heated)
form Solid
pka 6.24±0.18(Predicted)
color White to Pale Yellow
Water Solubility Soluble in water 1.33 g/L.
Sensitive Air Sensitive
BRN 2205318
InChI InChI=1S/C7H5BrO2/c8-6-3-5(4-9)1-2-7(6)10/h1-4,10H
InChIKey UOTMHAOCAJROQF-UHFFFAOYSA-N
SMILES C(=O)C1=CC=C(O)C(Br)=C1
CAS DataBase Reference 2973-78-6(CAS DataBase Reference)
NIST Chemistry Reference Benzaldehyde, 3-bromo-4-hydroxy-(2973-78-6)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29130000
NFPA 704
1
2 0

3-BROMO-4-HYDROXYBENZALDEHYDE price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 516775 3-Bromo-4-hydroxybenzaldehyde 97% 2973-78-6 5g $45.6 2025-07-31 Buy
TCI Chemical B2350 3-Bromo-4-hydroxybenzaldehyde >98.0%(T) 2973-78-6 5g $59 2025-07-31 Buy
TRC B415380 3-Bromo-4-hydroxybenzaldehyde 2973-78-6 25g $170 2021-12-16 Buy
TRC B415380 3-Bromo-4-hydroxybenzaldehyde 2973-78-6 5g $45 2021-12-16 Buy
AK Scientific J91451 3-Bromo-4-hydroxybenzaldehyde 2973-78-6 5g $14 2021-12-16 Buy
Product number Packaging Price Buy
516775 5g $45.6 Buy
B2350 5g $59 Buy
B415380 25g $170 Buy
B415380 5g $45 Buy
J91451 5g $14 Buy

3-BROMO-4-HYDROXYBENZALDEHYDE Chemical Properties,Uses,Production

Uses

3-Bromo-4-hydroxybenzaldehyde is an intermediate in organic syntheses, it is used to produce other chemicals like 5-Brom-4-hydroxy-b-nitrostyrol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 3305, 1979 DOI: 10.1021/jo01333a006

Synthesis

2-Bromo-4-methylphenol

6627-55-0

3-BROMO-4-HYDROXYBENZALDEHYDE

2973-78-6

General procedure for the synthesis of 3-bromo-4-hydroxybenzaldehyde from 2-bromo-4-methylphenol: A mixture of the substrate 2-bromo-4-methylphenol (1 mmol), cobalt salt (n1 mol%), and NaOH (n2 eq.) in ethylene glycol (5 mL) was stirred with oxygen (1 atm) and bubbled for 8 hr at 80 °C. Upon completion of the reaction, hydrochloric acid (10 mL, 2%) and methyl tert-butyl ether (MTBE, 10 mL) were added sequentially to the reaction mixture. The organic layer was separated and the aqueous phase was further extracted with MTBE (10 mL x 2). All organic phases were combined and concentrated by drying with anhydrous sodium sulfate to give the residue. The residue was purified by silica gel column chromatography (eluent: petroleum ether/ethyl acetate, 10/1) to afford the target product 3-bromo-4-hydroxybenzaldehyde.

References

[1] Tetrahedron Letters, 2014, vol. 55, # 8, p. 1406 - 1411
[2] Green Chemistry, 2014, vol. 16, # 5, p. 2807 - 2814
[3] Green Chemistry, 2014, vol. 16, # 3, p. 1248 - 1254
[4] Research on Chemical Intermediates, 2015, vol. 41, # 6, p. 3855 - 3863
[5] Journal of Molecular Catalysis A: Chemical, 2016, vol. 420, p. 45 - 49

3-BROMO-4-HYDROXYBENZALDEHYDE Preparation Products And Raw materials

Raw materials

2-Bromo-4-methylphenol 3-Bromo-4-(methoxymethoxy)benzaldehyde 2-BROMO-4-HYDROXYMETHYL-PHENOL 4-Hydroxybenzaldehyde Oxygen
Ethylene glycol Sodium hydroxide

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Preparation Products

3-BROMO-4-HYDROXYCINNAMIC ACID 3-Formyl-4-hydroxybenzonitrile 3-Bromo-4-difluoromethoxybenzaldehyde 3-BroMo-4-(2-Methoxyethoxy)benzaldehyde 3-BroMo-4-[2-(diMethylaMino)ethoxy]benzaldehyde
3-Bromo-4-(methoxymethoxy)benzaldehyde

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3-BROMO-4-HYDROXYBENZALDEHYDE Suppliers

Global( 255)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd 		+8615350571055 Sibel@chuanghaibio.com China 8772 58
Sichuan Zhuoyu Yantang Technology Co., Ltd. 		+8613288715578 sales@sichuanzyyt.com China 12246 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20175 58
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD 		+86-15350851019; +8615350851019 admin@86-ss.com China 999 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29734 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 13451 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29852 58
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
Supplier Advantage
Hebei Chuanghai Biotechnology Co., Ltd 		58
Sichuan Zhuoyu Yantang Technology Co., Ltd. 		58
Henan Fengda Chemical Co., Ltd 		58
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Changzhou Ansciep Chemical Co., Ltd. 		58
Alchem Pharmtech,Inc. 		58

View Lastest Price from 3-BROMO-4-HYDROXYBENZALDEHYDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-BROMO-4-HYDROXYBENZALDEHYDE pictures 2025-10-17 3-BROMO-4-HYDROXYBENZALDEHYDE
2973-78-6
 US $9.90 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
3-BROMO-4-HYDROXYBENZALDEHYDE pictures 2025-09-25 3-BROMO-4-HYDROXYBENZALDEHYDE
2973-78-6
 US $8.00-2.00 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
3-BROMO-4-HYDROXYBENZALDEHYDE pictures 2025-09-23 3-BROMO-4-HYDROXYBENZALDEHYDE
2973-78-6
 US $99.00-66.00 / kg 0.001kg 99% 5000 HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

3-BROMO-4-HYDROXYBENZALDEHYDE Spectrum

3-BROMO-4-HYDROXYBENZALDEHYDE(2973-78-6)1HNMR3-BROMO-4-HYDROXYBENZALDEHYDE(2973-78-6)IR

2973-78-6(3-BROMO-4-HYDROXYBENZALDEHYDE)Related Search:

METHYL 3,5-DIBROMO-2,4-DIHYDROXY-6-METHYLBENZOATE 3,5-Dibromo-4-hydroxybenzaldehyde 5-Bromovanillin 3,5-Dibromo-4-hydroxybenzoic acid 3-BROMO-4-HYDROXYBENZOIC ACID HYDRATE
METHYL 3,5-DIBROMO-2,4-DIMETHOXY-6-METHYLBENZOATE 3',5'-Dibromo-4'-hydroxyacetophenone 3-BROMO-4-HYDROXYBENZALDEHYDE 5-BROMO-2,4-DIHYDROXYBENZOIC ACID METHYL 3,5-DIBROMO-4-HYDROXYBENZOATE
2,3-DIBROMO-4-HYDROXY-5-METHOXYBENZALDEHYDE 3-Bromo-4-methoxybenzaldehyde Benzbromarone 3,5-Dibromosalicylaldehyde 5-Bromo-2-anisaldehyde
2-BROMO-5-HYDROXYBENZALDEHYDE 3-BROMO-2-HYDROXYBENZALDEHYDE 4-Bromo-2-hydroxybenzaldehyde

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ASISCHEM N48923 3-BROMO-4-HYROXYBENZALDEHYDE 3-BROMO-4-HYDROXYBENZALDEHYDE AKOS B029029 4-Hydroxy-3-bromobenzaldehyde 3-Bromo-4-hydroxybenzaldehyde, 98+% 3-Bromo-4-hydroxybenzaldehyde, 97+% 2-Bromo-4-formylphenol 3-Bromo-4-hydroxybenzaldehyde 97% 3-Bromo-4-hydroxybenza I dehyde 3-Bromo-4-hydroxybenzaldehyde > Benzaldehyde, 3-bromo-4-hydroxy- 3-bromo-4-hydroxy benzeldehyde 3-BROMO-4-HYDROXYBENZALDEHYDE, 2-Bromo-4-formylphenol, AKOS B029029, ASISCHEM N48923, 3-BROMO-4-HYROXYBENZALDEHYDE, 4-Hydroxy-3-bromobenzaldehyde, 3-BROMO-4-HYDROXYBENZALDEHYDE, 3-bromo-4-hydroxy benzeldehyde, 3-Bromo-4-hydroxybenza I dehyde, Benzaldehyde, high qualtiy 3-Bromo-4-Hydroxy Benzeldehyde 2973-78-6 973-78-6 2973-38-6 BrC6H3OHCHO Organic Building Blocks C7 Carbonyl Compounds Building Blocks Aldehydes Aldehydes C7 Carbonyl Compounds Phenols Aromatic Aldehydes & Derivatives (substituted) Benzaldehyde Adehydes, Acetals & Ketones Bromine Compounds