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Dess-Martin periodinane

Dess-Martin periodinane Structure
Dess-Martin periodinane structure
CAS No.
87413-09-0
Chemical Name:
Dess-Martin periodinane
Synonyms
DESS-MARTIN;Dess-Martin periodane;DESS-MARTIN REAGENT;PERIODINANE;DESS-MARTINE;1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE;Dess-Martin periodinane,D M P, TAPI;3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate;1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE;Martin's reagent
CBNumber:
CB0776475
Molecular Formula:
C13H13IO8
Molecular Weight:
424.14
MDL Number:
MFCD00130127
MOL File:
87413-09-0.mol
MSDS File:
SDS
Last updated:2026-01-13 11:13:27
Product description Number Pack Size Price
Dess-Martin periodinane 97% 274623 5g $140
Dess-Martin periodinane 97% 274623 25g $668
Dess-Martin Periodinane >95.0%(T) D2045 1g $35
Dess-Martin Periodinane >95.0%(T) D2045 5g $106
Dess-Martin periodinane solution 0.3 M in methylene chloride 559873 5ml $49.7
More product size
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Dess-Martin periodinane Properties

Melting point 130-133 °C (lit.)
Boiling point 40 °C
Density 1.369 g/mL at 25 °C
Flash point >221 °F
storage temp. -20°C
solubility Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
form Liquid
color Colorless to light yellow
Sensitive Light Sensitive
Merck 14,2933
BRN 4548207
Stability Light Sensitive
InChI InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3
InChIKey NKLCNNUWBJBICK-UHFFFAOYSA-N
SMILES I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2
CAS DataBase Reference 87413-09-0(CAS DataBase Reference)
FDA UNII 336B74JK56
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS03,GHS07
Signal word  Danger
Hazard statements  H272-H315-H319-H335
Precautionary statements  P210-P220-P261-P264-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xn,O,Xi
Risk Statements  22-36/37/38-40-8-20/21/22-44
Safety Statements  26-36-36/37-24/25-23-17-45-36/37/39
RIDADR  UN 1593 6.1/PG 3
WGK Germany  3
Hazard Note  Harmful/Light sensitive
TSCA  No
HazardClass  5.1
PackingGroup  Ⅲ
HS Code  29349990
Storage Class 5.2 - Organic peroxides and self-reacting hazardous materials
Hazard Classifications Eye Irrit. 2
Self-react. C
Skin Irrit. 2
STOT SE 3
Limited Quantities 5 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
0
2 0
OX

Dess-Martin periodinane price More Price(60)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 274623 Dess-Martin periodinane 97% 87413-09-0 5g $140 2025-07-31 Buy
Sigma-Aldrich 274623 Dess-Martin periodinane 97% 87413-09-0 25g $668 2025-07-31 Buy
TCI Chemical D2045 Dess-Martin Periodinane >95.0%(T) 87413-09-0 1g $35 2025-07-31 Buy
TCI Chemical D2045 Dess-Martin Periodinane >95.0%(T) 87413-09-0 5g $106 2025-07-31 Buy
Sigma-Aldrich 559873 Dess-Martin periodinane solution 0.3 M in methylene chloride 87413-09-0 5ml $49.7 2025-07-31 Buy
Product number Packaging Price Buy
274623 5g $140 Buy
274623 25g $668 Buy
D2045 1g $35 Buy
D2045 5g $106 Buy
559873 5ml $49.7 Buy

Dess-Martin periodinane Chemical Properties,Uses,Production

Description

Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.

Chemical Properties

White Crystalline powder

Uses

Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

Uses

Oxidizing reagent.

Uses

Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

reaction suitability

reagent type: oxidant

Synthesis

2-Iodobenzoic acid (50.0 g,0.20 mol) was added to cyclobutanesulfone (250 mL), and the solution was heated to 50 C. 90% of the above solution was slowly added dropwise to an aqueous solution of potassium persulfate (147.4g,0.24mol,1.2eq) at 50C (300mL) and the reaction was held for 3 hours. Subsequently, the reaction solution was heated to 95 C and the remaining 10% 2-iodobenzoic acid solution was slowly added dropwise to the reaction solution and the reaction was continued for 3 hours. Upon completion of the reaction, the reaction was cooled to 5 C and stirring was continued at this temperature for 1.5 hours. Under stirring, 1 L of water was added, filtered (the filtrate was to be recycled for set use), the filter cake was washed with water and acetone sequentially, and dried at room temperature for 16 hours to obtain 53.2 g of 2-iodobenzoic acid (yield 95.04%), white solid, with a purity of 99.7% (confirmed by NMR and HPLC). The solid was identified as 2-iodoacylbenzoic acid by HNMR.

2-Iodoacylbenzoic acid (45 g, 0.16 mol) was added to acetic anhydride (49 g, 0.48 mol) and dioxane (90 mL), followed by B(C6F5)3 (0.0016 mol) followed by B(C6F5)3 (0.0016 mol), and the reaction solution was heated to 50 C and stirred for 10 min, then the solvent was evaporated off by spin-drying under reduced pressure, and the reaction solution was added to methyl tert-butyl ether (400 mL). Filtered and dried at room temperature to obtain a white solid (61.1 g, yield: 90%). The purity of Desmartin oxidizer was 99.1% (confirmed by NMR).

Advantages

Benefits of using Dess-Martin periodinane (DMP) as an oxidizing reagent:
milder reaction conditions (room temperature, neutral pH)
shorter reaction times and higher yields
high chemoselectivity
tolerance of sensitive functional groups, and a long shelf life
simplified workups

Dess-Martin periodinane Preparation Products And Raw materials

Raw materials

2-Iodobenzoic acid p-Toluenesulfonic acid Acetic anhydride 2-Iodoxybenzoic acid Potassium bromate
Acetic acid

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Preparation Products

C-(3,4-DIHYDRO-2H-BENZO[1,4]OXAZIN-3-YL)-METHYLAMINE 3-Chloro-4-Cyanobenzaldehyde 3-(4-FLUORO-PHENYL)-1-ISOPROPYL-1H-INDOLE-2-CARBALDEHYDE (3-OXO-PROPYL)-CARBAMIC ACID TERT-BUTYL ESTER 4-FORMYL-N-CBZ-PIPERIDINE
1-[[(4-METHYLPHENYL)SULPHONYL]OXY]-1,2-BENZIODOXOL-3(1H)-ONE 1H-Indazole-1-propanoic acid

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Dess-Martin periodinane Suppliers

Global( 601)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Zhuanglai Chemical Trading Co Ltd 		+86-16264648883 niki@zlchemi.com China 7245 58
Springchem New Material Technology Co.,Limited 		+86-021-62885108 +8613917661608 info@spring-chem.com China 2068 57
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29735 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 13799 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21596 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Zjartschem 		+86-571 87238903 jocelynpan@zjarts.com CHINA 988 58
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29831 58
Supplier Advantage
Hebei Zhuanglai Chemical Trading Co Ltd 		58
Springchem New Material Technology Co.,Limited 		57
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Time Chemicals CO., Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
Zjartschem 		58
career henan chemical co 		58

Related articles

View Lastest Price from Dess-Martin periodinane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dess-Martin periodinane pictures 2026-02-24 Dess-Martin periodinane
87413-09-0
 0.99 RongNa Biotechnology Co.,Ltd
Dess-Martin periodinane pictures 2025-11-18 Dess-Martin periodinane
87413-09-0
 US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
Dess-Martin periodinane pictures 2025-05-23 Dess-Martin periodinane
87413-09-0
 US $79.00-38.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co Ltd

Dess-Martin periodinane Spectrum

Dess-Martin periodinane(87413-09-0)1HNMRDess-Martin periodinane(87413-09-0)IR1Dess-Martin periodinane(87413-09-0)IR2

87413-09-0(Dess-Martin periodinane)Related Search:

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Dess-Martin periodinane,D M P, TAPI dess-martin periodinate 1,1,1-Triacetoxy-1,2-benziodoxole-IV-3(1H)-one 1,1,1-Triacetoxy-1,3-dihydro-3-oxo-1,2-benziodoxole-IV 1,1,1-Triacetoxy-3H-1,2-benziodoxole-IV-3-one Martin's reagent 1,1-Dihydro-1,1,1-triacetoxy-1,2-benzoiodooxol-3(1H)-one (Dess-M Dess-Martin periodinane solution Dess-Martin periodinane,1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one Acetic acid, 1,1',1''-(3-oxo-1.lambda.5-1,2-benziodoxol-1(3H)-ylidyne) ester Dess-Martin periodinane, 15 wt.% solution in dichloromethane, AcroSeal 1,1-dihydro-1,1,1-triacetoxy-1,2-benziodoxol-3(1H)-one 1,1,1-Triacetoxy-1,2-benziodoxol-3(1H)-one(Dess-Martin periodinane) Dess-Martin periodinane, 15 wt.% solution in dichloroMethane 50ML Dess-Martin Periodinane (Technical Grade) Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, J&KSeal Dess-Martin periodinane 97% Dess-Martin periodinane solution 0.3 M in Methylene chloride Dess-Martin periodinane, 15 wt.% solution in CH2Cl2, SpcSeal Deiss Martin reagent DESS-MARTIN DESS-MARTIN PERIODINANE DESS-MARTIN REAGENT DESSS-MARTIN PERIODINANE 1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE 1,1,1-TRIS(ACETYLOXY)-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE ACETIC ACID 1,1-DIACETOXY-3-OXO-1L5-IODA-2-OXA-INDAN-1-YL ESTER TRIACETOXYPERIODINANE Dess-Martinperiodinane,97% Dess-Martin periodane 3-oxo-1l5-benzo[d][1,2]iodaoxole-1,1,1(3H)-triyl triacetate 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE(DESSMARTINE) 1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE (DESS-MARTIN PERIODINANE) DESS-MARTIN(1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3(1H)-ONE) Dess Martin Periodinane 0.3M in DCM Dess-Martin Periodinane (8-12% in Dichloromethane) (1,1-diacetyloxy-3-oxo-1λ5,2-benziodoxol-1-yl) Acetate RARECHEM AR PA 0035 Triacetoxyperiodinane (Dess-Martin periodinane) DESS-MARTIN PERIODINANE, 0.3M SOLUTION & (7,7-DIACETYLOXY-9-OXO-7$L^{5}-IODA-8-OXABICYCLO[4.3.0]NONA-1,3,5-TRIEN-7-YL) ACETATE DesmartinPeriodinane DmpDess-MartinPeriodinane Dess-Martin periodinane, 15 wt.% solution in dichloromethane 1,2-Benziodoxol-3(1H)-one, 1,1,1-tris(acetyloxy)-1,1-dihydro- 1,1,1-TRIACETOXY-1,1-DIHYDRO-1,2-BENZIODOXOL-3-(1H)-ONE(DESS-MARTINPERIODINANE) DESS-MARTINE DMP DESS-MARTIN PERIODINANE TRIACETOXYPERIODINANE Dess-Martin Periodinane Triacetoxyperiodinane Dess-martin oxidizer PERIODINANE 1,1-bis(acetyloxy)-3-oxo-3H-1λ,2-benziodaoxol-1-yl acetate Dess-Martin Periodinane (DMP) Aceticacid,1,1',1''-(3-oxo-1λ5-1,2-benziodoxol-1(3H)-ylidyne)ester Dess-Martin periodinane, 15 wt.% solution in CH2Cl2 Days Martin oxidant Dess-MartinPeriodinane>