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4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER

4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER structure

CAS No.: 872091-83-3

Chemical Name:: 4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER

Synonyms: 3-Cyanomethyl-4-chlorobenzoic acid methyl ester;4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER;Methyl 4-chloro-3-(cyanomethyl)benzoate - [M71997];3-Cyanomethyl-4-Chorobenzoic Acid Methyl Ester (en);Benzoic acid, 4-chloro-3-(cyanomethyl)-, methyl ester

CBNumber:: CB11092669

Molecular Formula:: C10H8ClNO2

Molecular Weight:: 209.63

MDL Number:: MFCD09263465

MOL File:: 872091-83-3.mol

MSDS File:: SDS

Last updated:2026-05-27 23:03:09

Product description	Number	Pack Size	Price
Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	OR13734	1g	$21
Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	OR13734	5g	$26
Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	OR13734	25g	$123
Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	OR13734	100g	$478
Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	OR13734	500g	$2367
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4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER Properties

Density	1.266
storage temp.	Inert atmosphere,Room Temperature
Appearance	White to off-white Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302+H312+H332-H315-H319-H335
Precautionary statements	P260-P280-P301+P312
HS Code	2916399090

4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER price

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Apolloscientific	OR13734	Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	872091-83-3	1g	$21	2026-06-04	Buy
Apolloscientific	OR13734	Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	872091-83-3	5g	$26	2026-06-04	Buy
Apolloscientific	OR13734	Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	872091-83-3	25g	$123	2026-06-04	Buy
Apolloscientific	OR13734	Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	872091-83-3	100g	$478	2026-06-04	Buy
Apolloscientific	OR13734	Methyl 4-chloro-3-(cyanomethyl)benzoate 98%	872091-83-3	500g	$2367	2026-06-04	Buy

Product number	Packaging	Price	Buy
OR13734	1g	$21	Buy
OR13734	5g	$26	Buy
OR13734	25g	$123	Buy
OR13734	100g	$478	Buy
OR13734	500g	$2367	Buy

4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER Chemical Properties,Uses,Production

Synthesis

220464-68-6

7677-24-9

4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER

872091-83-3

Step 2: Synthesis of intermediate 2 A mixture of Intermediate 1 (methyl 3-(bromomethyl)-4-chlorobenzoate, 1.00 g, 3.80 mmol), trimethylcyanosilane (TMSCN, 0.56 g, 5.69 mmol), and potassium carbonate (K2CO3, 786 mg, 5.69 mmol) in acetonitrile (CH3CN, 50 mL) was heated to reflux for 16 hours. After completion of the reaction, the mixture was cooled to room temperature, filtered to remove insoluble material and the filtrate was concentrated. The resulting crude product was purified by silica gel column chromatography using a hexane solution of 5-10% ethyl acetate (EtOAc) as eluent to afford the target product methyl 3-cyanomethyl-4-chlorobenzoate (590 mg, 75% yield) as a white solid. 1H NMR (400 MHz, CDCl3) δ: 8.18 (d, 1H), 7.99 (dd, 1H), 7.52 (d, 1H), 3.94 (s, 3H), 3.88 (s, 2H).

References

[1] Patent: WO2014/144737, 2014, A1. Location in patent: Paragraph 00777

4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Methyl 3-(Bromomethyl)-4-chlorobenzoate Trimethylsilyl cyanide Sodium cyanide Acetonitrile Potassium carbonate

Preparation Products

4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER Suppliers

Global( 48)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14304	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52705	58
Changzhou Anxuan Chemical Co., Ltd	+86-0519-89882563 +86-18961279162	andy@anxuanchem.com	China	4327	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19987	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418684 +8618949823763	sales@tnjchem.com	China	25356	58
Aromsyn Co., Ltd.	+86-0571-85585865 +8613336024896	CB@aromsyn.com	China	19183	58
PT CHEM GROUP LIMITED	+86-85511178;	peter68@ptchemgroup.com	China	35425	58
Aceschem Inc.	+1-817863-6948 +1-（817）863-6948	sales@aceschem.com	United States	19632	58

Supplier	Advantage
Changzhou Ansciep Chemical Co., Ltd.	58
Fuxin Pharmaceutical	58
Win-Win chemical CO., Limited	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Changzhou Anxuan Chemical Co., Ltd	58
Labnetwork lnc.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Aromsyn Co., Ltd.	58
PT CHEM GROUP LIMITED	58
Aceschem Inc.	58

872091-83-3(4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER)Related Search:

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4-CHLORO-3-CYANOMETHYL-BENZOIC ACID METHYL ESTER 3-Cyanomethyl-4-chlorobenzoic acid methyl ester 3-Cyanomethyl-4-Chorobenzoic Acid Methyl Ester (en) Benzoic acid, 4-chloro-3-(cyanomethyl)-, methyl ester Methyl 4-chloro-3-(cyanomethyl)benzoate - [M71997] 872091-83-3