Hexamethylene diacrylate
- CAS No.
- 13048-33-4
- Chemical Name:
- Hexamethylene diacrylate
- Synonyms
- HDDA;1,6-HEXANEDIOL DIACRYLATE;Hexanediol acrylate;HDODA;Hexane-1,6-diyl diacrylate;Hexamethylendiacrylat;1,6-Hexanediol diacrylate,HDODA;c716;sr238;nkesterahd
- CBNumber:
- CB1114704
- Molecular Formula:
- C12H18O4
- Molecular Weight:
- 226.27
- MDL Number:
- MFCD00008631
- MOL File:
- 13048-33-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 6°C |
|---|---|
| Boiling point | 295°C |
| Density | 1.01 g/mL at 25 °C (lit.) |
| vapor density | >1 (vs air) |
| vapor pressure | <0.01 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
| solubility | Chlroform (Slightly), DMSO (Slightly) |
| form | Liquid |
| color | Colourless |
| Specific Gravity | 1.01 |
| Odor | Mild ester-like odor |
| Viscosity | 9 cp (25C) |
| Water Solubility | Slightly miscible with water. |
| FreezingPoint | 6 |
| Sensitive | Hygroscopic |
| Stability | Light Sensitive |
| InChI | 1S/C12H18O4/c1-3-11(13)15-9-7-5-6-8-10-16-12(14)4-2/h3-4H,1-2,5-10H2 |
| InChIKey | FIHBHSQYSYVZQE-UHFFFAOYSA-N |
| SMILES | C=CC(=O)OCCCCCCOC(=O)C=C |
| LogP | 2.81 at 25℃ |
| CAS DataBase Reference | 13048-33-4(CAS DataBase Reference) |
| FDA UNII | FY751V5MMY |
| NIST Chemistry Reference | Hexamethylene diacrylate(13048-33-4) |
| EPA Substance Registry System | 1,6-Hexanediol diacrylate (13048-33-4) |
| UNSPSC Code | 12162002 |
| NACRES | NA.23 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H317-H319 | |||||||||
| Precautionary statements | P261-P264-P272-P280-P302+P352-P305+P351+P338 | |||||||||
| PPE | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/38-43 | |||||||||
| Safety Statements | 39 | |||||||||
| RIDADR | UN 3082 9/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | AT1430000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29161290 | |||||||||
| Storage Class | 10 - Combustible liquids | |||||||||
| Hazard Classifications | Aquatic Acute 1 Aquatic Chronic 2 Eye Irrit. 2 Skin Irrit. 2 Skin Sens. 1 |
|||||||||
| Hazardous Substances Data | 13048-33-4(Hazardous Substances Data) | |||||||||
| REACH Registrations | Active | |||||||||
| NFPA 704 |
|
Hexamethylene diacrylate price More Price(37)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 246816 | 1,6-Hexanediol diacrylate technical grade, 80% | 13048-33-4 | 100g | $56.1 | 2026-04-30 | Buy |
| Sigma-Aldrich | 246816 | 1,6-Hexanediol diacrylate technical grade, 80% | 13048-33-4 | 500g | $134 | 2026-04-30 | Buy |
| TCI Chemical | B2936 | 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ) >85.0%(GC) | 13048-33-4 | 25g | $27 | 2026-04-30 | Buy |
| TCI Chemical | B2936 | 1,6-Bis(acryloyloxy)hexane (stabilized with MEHQ) >85.0%(GC) | 13048-33-4 | 500g | $103 | 2026-04-30 | Buy |
| AK Scientific | V1436 | 1,6-Hexanediol diacrylate (stabilized with 100 ppm MEHQ) 95%(GC) | 13048-33-4 | 5g | $16 | 2026-06-04 | Buy |
Hexamethylene diacrylate Chemical Properties, Uses, Production
Description
Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.
Sources
- https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
- Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
- https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf
Description
Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.
Chemical Properties
Colorless transparent liquid
Uses
1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.
Uses
1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.
General Description
Clear yellow liquid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.
Fire Hazard
Hexamethylene diacrylate is probably combustible.
Flammability and Explosibility
Non flammable
Synthesis
1,6-Hexanediol diacrylate was synthesized by esterification reaction using 1,6-hexanediol and acrylic acid as the raw materials, strongly acidic cationic resin D072 as the catalyst, cyclohexane as the water-carrying agent, and hydroquinone as the polymerization blocking agent. The experimental results showed that the optimum conditions for the esterification reaction were as follows: "(acrylic acid):"(1,6-hexanediol) 2.2, catalyst dosage (mass ratio of raw material) 2.5%, polymerization blocker dosage (mass ratio of acrylic acid) 0.6%, water-carrying agent dosage (mass ratio of raw material) 70O.4, reaction time 4h, reaction temperature 80-110 . 1,6-Hexanediol diacrylate was synthesized. The product yield reached 93.88%.
Hexamethylene diacrylate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Suzhou Senfeida Chemical Material Co., Ltd. | 512-66387919 13862111431 | sales2@senfeida.com | China | 298 | 58 |
| Hubei Xingyan New Material Technology Co., Ltd | 13129948835 | 2756772312@qq.com | China | 4504 | 58 |
| Guangzhou Shanghe Chemical Technology Co., Ltd | 13352869970 13352869970 | 272907493@qq.com | China | 1122 | 58 |
| Hubei Baidu Chemical Co., Ltd | 027-59106051 13627137652 | 1438180055@qq.com | China | 8469 | 58 |
| Jinan Fuzhe New Material Co., Ltd. | 00-15169181 15169181281 | 15169181281@163.com | China | 262 | 58 |
| Guangdong Yingtai new material Co., LTD | 15217305040 | yingtai505@163.com | China | 67 | 58 |
| Shanghai Xingtuo Import and Export Trading Co., Ltd. | 021-67692172 13916437905 | 115020287@qq.com | China | 73 | 58 |
| FoShan BeiSi Chemical Co., Ltd. | 19584229548 15218144393 | 3418849028@qq.com | China | 1116 | 58 |
| IGM RESINS | 021-52080993 13917193189 | selene.wu@igmresins.com | China | 89 | 57 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
Related articles
- Synthesis of 1,6-Hexanediol Diacrylate
- 1,6-hexanediol diacrylate was synthesized by direct esterification method,while its influencing factors were investigated.
- Jan 13,2025
View Latest Price from Hexamethylene diacrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-09-15 | Hexamethylene diacrylate
13048-33-4
|
200KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
 |
2026-09-02 | Hexamethylene diacrylate
13048-33-4
|
20kg | 99.0% | 20 tons | Qingdao RENAS Polymer Material Co., Ltd. | ||
 |
2026-09-02 | Hexamethylene diacrylate
13048-33-4
|
$5.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd |
-
- Hexamethylene diacrylate
13048-33-4
- $0.00
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Hexamethylene diacrylate
13048-33-4
- $0.00
- 99.0%
- Qingdao RENAS Polymer Material Co., Ltd.
-
- Hexamethylene diacrylate
13048-33-4
- $5.00
- 99%
- Henan Fengda Chemical Co., Ltd
