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Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP

CAS No.
742103-27-1
Chemical Name:
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
Synonyms
Mo-Phos;cBRIDP[R];cBRIDP(regR);cBRIDP®cBRIDP(regR) >Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine;ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine , cBRIDP
CBNumber:
CB11181097
Molecular Formula:
C24H33P
Molecular Weight:
352.49
MDL Number:
MFCD09753012
MOL File:
742103-27-1.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:04:50
Product description Number Pack Size Price
cBRIDP(regR) >97.0%(HPLC) C2979 1g $117
cBRIDP(regR) >97.0%(HPLC) C2979 200mg $34
Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 15-1005 250mg $33
Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 15-1005 1g $98
cBRIDP FC180177 100mg $183
More product size

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Properties

Melting point 87-91°C
Boiling point 427.3±45.0 °C(Predicted)
form solid
color white to pale yellow
Sensitive air sensitive, store cold
InChI 1S/C24H33P/c1-21(2,3)25(22(4,5)6)23(7)18-24(23,19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,18H2,1-7H3
InChIKey QMLPJDVGNRHGJQ-UHFFFAOYSA-N
SMILES CC(C)(C)P(C(C)(C)C)C1(C)CC1(c2ccccc2)c3ccccc3
CAS DataBase Reference 742103-27-1
UNSPSC Code 12352002

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H319-H335-H302+H312+H332-H315
Precautionary statements  P280-P301+P312-P362+P364
WGK Germany  3
HS Code  2931499090
Storage Class 11 - Combustible Solids

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical C2979 cBRIDP(regR) >97.0%(HPLC) 742103-27-1 1g $117 2021-12-16 Buy
TCI Chemical C2979 cBRIDP(regR) >97.0%(HPLC) 742103-27-1 200mg $34 2021-12-16 Buy
Strem Chemicals 15-1005 Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 742103-27-1 250mg $33 2021-12-16 Buy
Strem Chemicals 15-1005 Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP 742103-27-1 1g $98 2021-12-16 Buy
Biosynth FC180177 cBRIDP 742103-27-1 100mg $183 2026-06-04 Buy
Product number Packaging Price Buy
C2979 1g $117 Buy
C2979 200mg $34 Buy
15-1005 250mg $33 Buy
15-1005 1g $98 Buy
FC180177 100mg $183 Buy

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties,Uses,Production

Reactions

  1. Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
  2. Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
  3. Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction. 
Reactions of 742103-27-1

Uses

Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.

General Description

This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 40)Suppliers
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Career Henan Chemica Co
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TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Beijing HwrkChemical Technology Co., Ltd 89508211 18501085097 sales.bj@hwrkchemical.com China 9407 55
TCI AMERICA 800-4238616 sales@tciamerica.com Americas 23636 75
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-65511006 18625597674 info@kingorgchem.com;sales@kingorgchem.com China 804 55
Bis-(1,1-dimethylethyl)-(1-methyl-2,2-diphenylcyclopropyl)-phosphine Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane cBRIDP(regR) Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP® Phosphine,bis(1,1-dimethylethyl)(1-methyl-2,2-diphenylcyclopropyl)- cBRIDP[R] cBRIDP(regR) > Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine , cBRIDP Mo-Phos 742103-27-1 Achiral Phosphine Aryl Phosphine organophosphine ligand