Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
- CAS No.
- 742103-27-1
- Chemical Name:
- Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP
- Synonyms
- Mo-Phos;cBRIDP[R];cBRIDP(regR);cBRIDP®cBRIDP(regR) >Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine;ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP;Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine , cBRIDP
- CBNumber:
- CB11181097
- Molecular Formula:
- C24H33P
- Molecular Weight:
- 352.49
- MDL Number:
- MFCD09753012
- MOL File:
- 742103-27-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| cBRIDP(regR) >97.0%(HPLC) | C2979 | 1g | $117 |
| cBRIDP(regR) >97.0%(HPLC) | C2979 | 200mg | $34 |
| Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP | 15-1005 | 250mg | $33 |
| Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP | 15-1005 | 1g | $98 |
| cBRIDP | FC180177 | 100mg | $183 |
| More product size | |||
| Melting point | 87-91°C |
|---|---|
| Boiling point | 427.3±45.0 °C(Predicted) |
| form | solid |
| color | white to pale yellow |
| Sensitive | air sensitive, store cold |
| InChI | 1S/C24H33P/c1-21(2,3)25(22(4,5)6)23(7)18-24(23,19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,18H2,1-7H3 |
| InChIKey | QMLPJDVGNRHGJQ-UHFFFAOYSA-N |
| SMILES | CC(C)(C)P(C(C)(C)C)C1(C)CC1(c2ccccc2)c3ccccc3 |
| CAS DataBase Reference | 742103-27-1 |
| UNSPSC Code | 12352002 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H319-H335-H302+H312+H332-H315 |
| Precautionary statements | P280-P301+P312-P362+P364 |
| WGK Germany | 3 |
| HS Code | 2931499090 |
| Storage Class | 11 - Combustible Solids |
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | C2979 | cBRIDP(regR) >97.0%(HPLC) | 742103-27-1 | 1g | $117 | 2021-12-16 | Buy |
| TCI Chemical | C2979 | cBRIDP(regR) >97.0%(HPLC) | 742103-27-1 | 200mg | $34 | 2021-12-16 | Buy |
| Strem Chemicals | 15-1005 | Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP | 742103-27-1 | 250mg | $33 | 2021-12-16 | Buy |
| Strem Chemicals | 15-1005 | Di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine cBRIDP | 742103-27-1 | 1g | $98 | 2021-12-16 | Buy |
| Biosynth | FC180177 | cBRIDP | 742103-27-1 | 100mg | $183 | 2026-06-04 | Buy |
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Chemical Properties,Uses,Production
Reactions
- Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.
- Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.
- Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction.
Uses
Ligand for greener Buchwald-Hartwig coupling in TPGS-750-M.
General Description
This product has been enhanced for catalytic efficiency.
A New Hybrid Phosphine Ligand for Palladium-CatalyzedAmination of Aryl Halides.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphinecBRIDP Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Career Henan Chemica Co | +86-0371-86658258 +86-13203830695 | laboratory@coreychem.com | China | 30203 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 +86-15355479329 | market18@leapchem.com | China | 43303 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Chemwill Asia Co.,Ltd. | 86-21-51086038 | chemwill_asia@126.com | CHINA | 23861 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| TCI AMERICA | 800-4238616 | sales@tciamerica.com | Americas | 23636 | 75 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51389 | 80 |
| Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. | 0371-65511006 18625597674 | info@kingorgchem.com;sales@kingorgchem.com | China | 804 | 55 |





