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Graphite Fluoride

Graphite Fluoride Structure
Graphite Fluoride structure
CAS No.
51311-17-2
Chemical Name:
Graphite Fluoride
Synonyms
XF096;XFM66;CEFBON;Fluorinatedcarbo;Fluorinatedcarbon;GRAPHITE FLUORIDE;Graphene fluoride;Carbonmonofluoride98%;GRAPHITE, FLUORINATED;fluorinated fullerene
CBNumber:
CB1223264
Molecular Formula:
CF
Lewis structure
cf lewis structure
Molecular Weight:
31.0091032
MDL Number:
MFCD00135559
MOL File:
51311-17-2.mol
MSDS File:
SDS
Last updated:2026-06-16 08:57:17
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Graphite Fluoride Properties

Melting point 500°C
form powder
InChI InChI=1S/CF/c1-2
InChIKey ISOSXCFSIDVNNC-UHFFFAOYSA-N
SMILES [C]F
CAS DataBase Reference 51311-17-2
EPA Substance Registry System Carbon fluoride (51311-17-2)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
RTECS  TQ1283000
TSCA  TSCA listed
HS Code  28129000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
1 0

Graphite Fluoride price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 372455 Graphite, fluorinated, polymer extent of labeling: >61 wt. % F 51311-17-2 5g $144 2026-04-30 Buy
aablocks AA01FG4D Carbon fluoride 99% 51311-17-2 1g $31 2026-05-30 Buy
aablocks AA01FG4D Carbon fluoride 99% 51311-17-2 5g $68 2026-05-30 Buy
aablocks AA01FG4D Carbon fluoride 99% 51311-17-2 25g $214 2026-05-30 Buy
aablocks AA01FG4D Carbon fluoride >61wt.%F，6/2000Noinsulation，Ps：10μm~20μm;RG 51311-17-2 100g $774 2026-05-30 Buy
Product number Packaging Price Buy
372455 5g $144 Buy
AA01FG4D 1g $31 Buy
AA01FG4D 5g $68 Buy
AA01FG4D 25g $214 Buy
AA01FG4D 100g $774 Buy

Graphite Fluoride Chemical Properties, Uses, Production

Chemical Properties

Grey powder. Structure: Flat C layers as in graphite, with F atoms bonded above and below the C layers. The composition lies within the range C3.6F to C4F. The color of the preparation is velvety black, sometimes somewhat bluish, d (under xylene) 2.05-2.09. Resistivity 2-4 ohm cm. at 750 kg/cm2. Stable to acids, bases and the common organic reagents. Slowly decomposes when heated for a long period above 100°C. Deflagrates when rapidly heated over a flame, forming sootlike flakes.

Uses

Graphite Fluoride is used in cathodic materials, lubricants, image recording, pressure-sensitive copying and carbon filament incandescent lamps.

Definition

ChEBI: Fluoromethane is a member of the class of fluoromethanes that is methane in which a single hydrogen is substituted by a fluorine atom. It has a role as a refrigerant. It is a member of fluoromethanes, a fluorohydrocarbon and a member of methyl halides.

Preparation

Prepared by fluorination of graphite at room temperature in the presence of HF. A stream of F3 at 4-5 liters/hr. is passed through a copper wash flask held at 0°C and filled with anhydrous HF, and then through an attached Cu tube (about 2 cm. in diameter). A Cu boat containing a thin layer of about 1 g. of graphite is placed in the tube. The end of the tube is closed with a screw-on cap having a narrow opening. The reaction is finished after one or two hours, as shown by the constant weight of the product. To remove excess HF, the preparation is washed with dilute base, water and alcohol and dried to room temperature over soda-lime. The yield is quantitative.

Battery Materials

Zhenyu Xiao and colleagues[1] innovatively introduced graphite fluoride (GF) interfacial layer to achieve a specific capacity of 400 mA h g−1 (500 °C, 50 mA cm−2) in NiF2|GF|electrolyte|La system, which is a 2.4-fold increase compared with that of the GF-free system (167 mA h g−1). Experiments confirm that the GF layer selectively allows F− migration and blocks the diffusion of metal cations, effectively suppressing side reactions.

References

[1] Xiao, Z., Wang, X., Xiang, Y., Zhu, J., Yang, W., Zhou, L., & Fu, L. (2025). Graphite fluoride interface blocking for higher capacity fluoride ion thermal batteries. Journal of Materials Chemistry A, 35, 29528–29537. https://doi.org/10.1039/D5TA04298D

Graphite Fluoride Preparation Products And Raw materials

Raw materials

Preparation Products

Graphite Fluoride Suppliers

Global Suppliers ( 110)
Supplier Tel Email Country ProdList Advantage
HuBei ZhuoXi Fluorochemical Co., Ltd., 0712-3586991 13801737011;13361903612 xxg@hbzxchem.com China 9 58
Shanghai Furui Fine Chemicals Co., Ltd. 021-36041048 13361903612 13361903612@189.cn China 12 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Tianjin heowns Biochemical Technology Co., Ltd. 400 638 7771 sales@heowns.com China 14412 57
Thermo Fisher Scientific 800-810-5118 cnchemical@thermofisher.com China 17752 75
Shanghai Macklin Biochemical Co.,Ltd. 15221275939 15221275939 shenlinxing@macklin.cn China 15775 55
Chizhou Kailong Import and Export Trade Co., Ltd. xg01_gj@163.com China 9413 50
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Hangzhou Dingyan Chem Co., LTD 0571-87157530-8002 15267169049 sales@dingyanchem.com China 2611 58
Supplier Advantage
HuBei ZhuoXi Fluorochemical Co., Ltd., 58
Shanghai Furui Fine Chemicals Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Tianjin heowns Biochemical Technology Co., Ltd. 57
Thermo Fisher Scientific 75
Shanghai Macklin Biochemical Co.,Ltd. 55
Chizhou Kailong Import and Export Trade Co., Ltd. 50
Sigma-Aldrich 80
Hangzhou Dingyan Chem Co., LTD 58

View Latest Price from Graphite Fluoride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Graphite Fluoride pictures 2026-09-02 Graphite Fluoride
51311-17-2
 $1.30-32.00 1kg 99% Henan Fengda Chemical Co., Ltd
Graphite Fluoride pictures 2026-08-19 Graphite Fluoride
51311-17-2
 1KG 98% 1000 KG Shaanxi Dideu New Materials Co. Ltd
Graphite Fluoride pictures 2026-07-22 Graphite Fluoride
51311-17-2
 1KG 99% 2tons Fujian Sanming Fengyuan New Material Technology Co., Ltd

Graphite Fluoride Spectrum

Graphite Fluoride(51311-17-2)IR

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CEFBON GRAPHITE, FLUORINATED GRAPHITE, FLUORINATED, POLYMER GRAPHITE FLUORIDE Fluorinatedcarbon GRAPHITE FLUORINATED, 3.35A PARTICLE SIZE -100 MESH 99% GRAPHITE FLUORINATED, 3.35A PARTICLE SIZE -100 MESH 99.9% GRAPHITE FLUORINATED, 3.35A PARTICLE SIZE -100 MESH 99.99% Carbonmonofluoride98% Graphite, fluorinated, polyMer extent of labeling: >61 wt. % F Graphite, fluorinatedCarbon monofluoride Fluorinatedcarbo Graphite, fluorinated, (CFx)n, x~1.1 Activated Carbon Fluoride fluorinated fullerene fluorinated graph-ite fiber Graphene fluoride Graphite Fluoride (Carbon Monofluoride) Nanopowder Fluorographite Powder GraphiteFluoridepowder Graphite Fluoride (Carbon Monofluoride) XF096 XFM66 51311-17-2 CFxnx11 CF CFxnx04 CFxnx05 CFxnx08 CFxnx07 CFxnx025 CFxnx033 CFxnx09 CFxnx12 CFxnx1 Fluorocarbons Hydrophobic Polymers Polymer Science Hydrophobic Polymers Materials Science Polymer Science Polymers