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3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid structure

CAS No.: 500011-86-9

Chemical Name:: 3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid

Synonyms: 3-broMo-1-(3-chloro-2-pyridinyl)-1H-Pyrazole-5-carboxylic acid;3-Bromo-1-(3-chloropyridin-2-yl);5-Bromo-2-(3-chloro-2-pyridyl)pyrazole-3-carboxylic acid;5-Bromo-2-(3-chloro-pyridin-2-yl)-2H-pyrazole-3-carboxylic acid;cas 500011-86-9;cas 500011-86-9 95%;coragen intermediate;Chlorantraniliprole Impurity 7;Chlorantranliprole intermediate;intermediate of Chlorantranliprole

CBNumber:: CB12550168

Molecular Formula:: C9H5BrClN3O2

Molecular Weight:: 302.51

MDL Number:: MFCD08689880

MOL File:: 500011-86-9.mol

MSDS File:: SDS

Last updated:2026-05-12 09:11:21

Product description	Number	Pack Size	Price
3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid	094753	250.00mg	$439
3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid	094753	1.00g	$975
3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 96%	B50703	250mg	$12
3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 96%	B50703	1g	$16
3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 96%	B50703	5g	$18
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3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid Properties

Melting point	197-200 °C
Boiling point	477.4±45.0 °C(Predicted)
Density	1.92±0.1 g/cm3(Predicted)
vapor pressure	0Pa at 20℃
storage temp.	2-8°C
solubility	DMSO (Slightly), Methanol (Slightly)
form	Solid
pka	2.39±0.36(Predicted)
color	White to Light Brown
Water Solubility	8.84g/L at 20.3℃
InChI	InChI=1S/C9H5BrClN3O2/c10-7-4-6(9(15)16)14(13-7)8-5(11)2-1-3-12-8/h1-4H,(H,15,16)
InChIKey	FORBXGROTPOMEH-UHFFFAOYSA-N
SMILES	N1(C2=NC=CC=C2Cl)C(C(O)=O)=CC(Br)=N1
LogP	1.5 at 25℃

SAFETY

Risk and Safety Statements

TSCA	TSCA listed
HS Code	2933199090
REACH Registrations	Active

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid price More Price(46)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Matrix Scientific	094753	3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid	500011-86-9	250.00mg	$439	2026-05-18	Buy
Matrix Scientific	094753	3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid	500011-86-9	1.00g	$975	2026-05-18	Buy
Synthonix	B50703	3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 96%	500011-86-9	250mg	$12	2026-05-06	Buy
Synthonix	B50703	3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 96%	500011-86-9	1g	$16	2026-05-06	Buy
Synthonix	B50703	3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 96%	500011-86-9	5g	$18	2026-05-06	Buy

Product number	Packaging	Price	Buy
094753	250.00mg	$439	Buy
094753	1.00g	$975	Buy
B50703	250mg	$12	Buy
B50703	1g	$16	Buy
B50703	5g	$18	Buy

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid Chemical Properties,Uses,Production

Uses

3-Bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxylic acid is a useful building block and has been used in the synthesis of the pesticide Cyclaniliprole.

Flammability and Explosibility

Not classified

Synthesis

Pyridine, 2-(3-broMo-1H-pyrazol-1-yl)-3-chloro-

500011-85-8

124-38-9

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid

500011-86-9

At -78 °C, 2-(3-bromo-1H-pyrazol-1-yl)-3-chloropyridine (3.04 g, 11.8 mmol) was dissolved in anhydrous THF (25 mL), keeping the reaction temperature below -71 °C. LDA solution (6 mL, 2M) was added slowly and dropwise. The reaction mixture was stirred at -78 °C for 15 min and then bubbled with carbon dioxide gas for 10 min. Subsequently, the reaction system was slowly warmed to -57°C and continued to -20°C. Upon completion of the reaction, the reaction was quenched with water. The reaction mixture was concentrated and dissolved in water (100 mL) and ether (80 mL), and an aqueous NaOH solution (1N, 2 mL) was added. The aqueous phase was washed with ether and acidified with aqueous HCl (2N). The precipitated solid was filtered, washed with water and dried to give 3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxylic acid (2 g, 59% yield) as a brown solid.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 22, p. 6274 - 6279
[2] Patent: CN105669643, 2016, A. Location in patent: Paragraph 0072; 0075; 0076
[3] Patent: WO2006/68669, 2006, A1. Location in patent: Page/Page column 19; 25
[4] Patent: WO2003/106427, 2003, A2. Location in patent: Page 18-19
[5] Patent: WO2004/67528, 2004, A1. Location in patent: Page 27

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid synthesis

Synthesis of 3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid from ETHYL 3-BROMO-1-(3-CHLOROPYRIDIN-2-YL)-1H-PYRAZOLE-5-CARBOXYLATE

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid Preparation Products And Raw materials

Raw materials

Pyridine, 2-(3-broMo-1H-pyrazol-1-yl)-3-chloro- ETHYL 3-BROMO-1-(3-CHLOROPYRIDIN-2-YL)-1H-PYRAZOLE-5-CARBOXYLATE Carbon dioxide Lithium diisopropylamide Tetrahydrofuran

1H-Pyrazole-5-carboxylic acid, 3-bromo-1-(3-chloro-2-pyridinyl)-, methyl ester

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Preparation Products

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid Suppliers

Global( 188)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14301	58
Shanghai Cube Chemical Co., Ltd.	+86-02156500520 +86-18116101847	kevin.li@cubechem.com	China	43	58
Hebei Yanxi Chemical Co., Ltd.	+86-17531190177	faithe@yan-xi.com	China	5838	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-86-13131129325	sales1@chuanghaibio.com	China	5216	58
Hebei Chuanghai Biotechnology Co., Ltd	+86-17732866630	mina@chuanghaibio.com	China	18114	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29626	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14032	58
Anhui Royal Chemical Co., Ltd.	+86-025-86655873 +86-13962173137	marketing@royal-chem.com	China	201	55
NINGBO INNO PHARMCHEM CO., LTD.	13867897135	sales@nbinno.com	CHINA	920	58
Win-Win Chemical CO., Limited	0086-577-64498589	sales@win-winchemical.com	CHINA	998	58

Supplier	Advantage
Win-Win chemical CO., Limited	58
Shanghai Cube Chemical Co., Ltd.	58
Hebei Yanxi Chemical Co., Ltd.	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Anhui Royal Chemical Co., Ltd.	55
NINGBO INNO PHARMCHEM CO., LTD.	58
Win-Win Chemical CO., Limited	58

View Lastest Price from 3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-05-28	K Acid 500011-86-9	$2.00-5.00	1KG	99%	10000kg	Hebei Chuanghai Biotechnology Co,.LTD
2025-12-23	3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 500011-86-9			98%+	100KG	XINXIANG RUNYU MATERIAL CO., LTD.
2025-06-27	3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 500011-86-9		1KG	99%	500000kg	Hebei Chuanghai Biotechnology Co., Ltd

K Acid
500011-86-9
$2.00-5.00
99%
Hebei Chuanghai Biotechnology Co,.LTD

3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid
500011-86-9
98%+
XINXIANG RUNYU MATERIAL CO., LTD.

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid
500011-86-9
99%
Hebei Chuanghai Biotechnology Co., Ltd

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid Spectrum

3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid(500011-86-9)¹HNMR

500011-86-9(3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid)Related Search:

ETHYL 3-BROMO-1-(3-CHLOROPYRIDIN-2-YL)-1H-PYRAZOLE-5-CARBOXYLATE 1-(3-chloropyridin-2-yl)-3-(trifluoromethyl)-1H-pyrazole-5-carboxylic acid 3-Chloro-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxylic acid 1H-Pyrazole-5-carboxylic acid, 3-amino-1-(3-chloro-2-pyridinyl)-, methyl ester Ethyl 1-(3-chloropyridin-2-yl)-3-(hydroxymethyl)-1H-pyrazole-5-carboxylate

1-(3-chloropyridin-2-yl)-3-methoxy-1H-pyrazole-5-carboxylic acid

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3-Bromo-1-(3-chloropyridin-2-yl) 3-Bromo-1-(3-Chloro-2-Pyridinyl)-1H-Pyrazole 5-Bromo-2-(3-chloro-pyridin-2-yl)-2H-pyrazole-3-carboxylic acid 3-Bromo-1-(3-chloro-2-pyridyl)pyrazole-5-carboxylic Acid 1H-Pyrazole-5-carboxylic acid, 3-bromo-1-(3-chloro-2-pyridinyl)- 5-Bromo-2-(3-chloro-2-pyridyl)pyrazole-3-carboxylic acid 3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid ISO 9001：2015 REACH 3-bromo-1-(3-chloro-2-pyridinyl)-1H-Pyrazole-5-carboxylic ac... cas 500011-86-9 95% 3-BroMo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid 95% Intermediate of Chlorantraniliprole (Coragen) cas 500011-86-9 Coragen intermediate cas 500011-86-9 98% Coragen intermediate 5-bromo-2-(3-chloropyridin-2-yl)pyrazole-3-carboxylic acid coragen intermediate intermediate of Chlorantranliprole Chlorantranliprole intermediate cas 500011-86-9 3-Bromo-1- (3-chloro-2-pyridine) -1H-pyrazole-5-carboxylic acid 3-Bromo-1-(3-chloro-2-pyridinyl)-1H- pyrazole-5-carboxylic Acid [K Acid] 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-carboxylic acid 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylicaci Chlorantraniliprole Impurity 7 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid(Pyrazole acid) 3-broMo-1-(3-chloro-2-pyridinyl)-1H-Pyrazole-5-carboxylic acid 500011-86-9