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4-Chlorobenzylamine

4-Chlorobenzylamine structure

CAS No.: 104-86-9

Chemical Name:: 4-Chlorobenzylamine

Synonyms: (4-Chlorophenyl)methanamine;4-Chlorbenzylamine;RARECHEM AL BW 0027;TIMTEC-BB SBB004154;P-CHLOROBENZYLAMINE;4-CHLOROBENZYLAMINE;Chlorobenzylamine,97%;Benzylamine, p-chloro-;LABOTEST-BB LTBB000701;4-ChlorobenzylaMine 98%

CBNumber:: CB1270950

Molecular Formula:: C7H8ClN

Molecular Weight:: 141.6

MDL Number:: MFCD00008121

MOL File:: 104-86-9.mol

MSDS File:: SDS

Last updated:2026-01-13 11:14:39

Product description	Number	Pack Size	Price
4-Chlorobenzylamine 98%	C27409	5g	$45.8
4-Chlorobenzylamine 98%	C27409	25g	$76.3
4-Chlorobenzylamine >98.0%(GC)	C1090	25g	$83
4-Chlorobenzylamine	C367755	50g	$180
4-Chlorobenzylamine	FC34710	250g	$195
More product size

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4-Chlorobenzylamine Properties

Melting point	277-278 °C(Solv: N,N-dimethylformamide (68-12-2))
Boiling point	215 °C (lit.)
Density	1.164 g/mL at 25 °C (lit.)
refractive index	n20/D 1.558(lit.)
Flash point	195 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
pka	8.85±0.10(Predicted)
form	Liquid
color	Clear slightly yellow
Water Solubility	Not miscible in water.
Sensitive	Air Sensitive
BRN	507949
InChI	1S/C7H8ClN/c8-7-3-1-6(5-9)2-4-7/h1-4H,5,9H2
InChIKey	YMVFJGSXZNNUDW-UHFFFAOYSA-N
SMILES	NCc1ccc(Cl)cc1
CAS DataBase Reference	104-86-9(CAS DataBase Reference)
NIST Chemistry Reference	Benzenemethanamine, 4-chloro-(104-86-9)
EPA Substance Registry System	Benzenemethanamine, 4-chloro- (104-86-9)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H302+H312-H314

Precautionary statements

P270-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338

PPE

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Codes

Xi,C

Risk Statements

36/37/38-34-52-21/22

Safety Statements

26-36-45-36/37/39

RIDADR

2735

WGK Germany

9-23

TSCA

TSCA listed

HazardClass

PackingGroup

III

HS Code

29214990

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B

Limited Quantities

1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

NFPA 704

	2
3		0

4-Chlorobenzylamine price More Price(34)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	C27409	4-Chlorobenzylamine 98%	104-86-9	5g	$45.8	2026-03-19	Buy
Sigma-Aldrich	C27409	4-Chlorobenzylamine 98%	104-86-9	25g	$76.3	2026-03-19	Buy
TCI Chemical	C1090	4-Chlorobenzylamine >98.0%(GC)	104-86-9	25g	$83	2026-03-19	Buy
TRC	C367755	4-Chlorobenzylamine	104-86-9	50g	$180	2021-12-16	Buy
Biosynth Carbosynth	FC34710	4-Chlorobenzylamine	104-86-9	250g	$195	2021-12-16	Buy

Product number	Packaging	Price	Buy
C27409	5g	$45.8	Buy
C27409	25g	$76.3	Buy
C1090	25g	$83	Buy
C367755	50g	$180	Buy
FC34710	250g	$195	Buy

4-Chlorobenzylamine Chemical Properties,Uses,Production

Chemical Properties

clear slightly yellow liquid

Uses

4-Chlorobenzylamine is used as pharmaceutical intermediate.

Synthesis

623-03-0

104-86-9

General procedure for the synthesis of p-chlorobenzylamine from p-chlorobenzonitrile: Ruthenium(II) complex (1 M) and 2-butanol (5 mL) were added to a 25 mL flask under argon protection and stirred for 5 min at room temperature. Subsequently, KOtBu (0.05 mM) was added and stirring was continued for 5 minutes. Next, p-chlorobenzonitrile (0.5 mM) was added and the reaction mixture was heated on a hot plate at 120°C for 30 minutes. Upon completion of the reaction, the catalyst was separated from the reaction mixture by the addition of petroleum ether, followed by filtration. The filtrate was neutralized with 1 M HCl. The ether layer was purified by short path silica gel column chromatography. Hexadecane was added to the purified filtrate as an internal standard and the yield of the product p-chlorobenzylamine was determined by gas chromatography (GC).

References

[1] Chemistry - A European Journal, 2016, vol. 22, # 14, p. 4991 - 5002
[2] Journal of the American Chemical Society, 2015, vol. 137, # 28, p. 8888 - 8891
[3] Journal of Coordination Chemistry, 2015, vol. 68, # 2, p. 321 - 334
[4] Synlett, 2001, # 10, p. 1623 - 1625
[5] Catalysis Letters, 2016, vol. 146, # 10, p. 2149 - 2156

4-Chlorobenzylamine synthesis

Synthesis of 4-Chlorobenzylamine from 4-Chlorobenzyl chloride

4-Chlorobenzylamine Preparation Products And Raw materials

Raw materials

Chloroform Hydrochloric acid Sodium hydroxide Hexamethylenetetramine 4-Chlorobenzyl chloride

4-CHLOROBENZALDEHYDE OXIME 4-Chlorobenzonitrile 2-Methyl-1-propanol Potassium tert-butoxide

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Preparation Products

Pencycuron BenzeneMethanaMine, 4-chloro-N,N-diMethyl- 4-CHLOROBENZYL ISOTHIOCYANATE Chlormidazole SR9009

AKOS BAR-2012 N-[(4-chloro-2-methylphenyl)methyl]-1-(4-chlorophenyl)-N-[(5-nitrothiophen-2-yl)methyl]methanamine N-(4-CHLOROBENZYL)-2-CYANOACETAMIDE N-(4-Chlorobenzyl)-3-MethylbenzaMide, 97% AKOS BAR-2003

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4-Chlorobenzylamine Suppliers

Global( 334)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Anhui Dexinjia Biopharm Co., Ltd	+86-531-82375818 +86-15064153060	sales01@jndxj.com	China	318	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +8618949832763	info@tnjchem.com	China	2988	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29822	58
Xiamen AmoyChem Co., Ltd	+86-86-5926051114 +8615060885618	sales@amoychem.com	China	6369	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10000	58

Supplier	Advantage
Anhui Dexinjia Biopharm Co., Ltd	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58
Xiamen AmoyChem Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Fuxin Pharmaceutical	58

View Lastest Price from 4-Chlorobenzylamine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-03-20	4-Chlorobenzylamine 104-86-9	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Chuanghai Biotechnology Co., Ltd
2026-02-27	4-Chlorobenzylamine 104-86-9	US $200.00-150.00 / kg	1kg	99%	20tons	Anhui Dexinjia Biopharm Co., Ltd
2021-08-12	4-Chlorobenzylamine 104-86-9	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

4-Chlorobenzylamine
104-86-9
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

4-Chlorobenzylamine
104-86-9
US $200.00-150.00 / kg
99%
Anhui Dexinjia Biopharm Co., Ltd

4-Chlorobenzylamine
104-86-9
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

4-Chlorobenzylamine Spectrum

4-Chlorobenzylamine(104-86-9)MS 4-Chlorobenzylamine(104-86-9)¹HNMR 4-Chlorobenzylamine(104-86-9)¹³CNMR 4-Chlorobenzylamine(104-86-9)FT-IR 4-Chlorobenzylamine(104-86-9)Raman 4-Chlorobenzylamine(104-86-9)IR

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