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2,3-Difluorobenzyl bromide

2,3-Difluorobenzyl bromide structure

CAS No.: 113211-94-2

Chemical Name:: 2,3-Difluorobenzyl bromide

Synonyms: CAS:113211-94-2;TIMTEC-BB SBB006681;2,3-DIFLUOROBENZYL BROMIDE;2,3-Difluorophenyl bromide;α-bromo-2,3-difluorotoluene;à-bromo-2,3-difluorotoluene;2,3-Difluorobenzylbromide98%;2,3-DifluorobenzylBromide>2,3-Difluorobenzyl bromide 98%;ALPHA-BROMO-2,3-DIFLUOROTOLUENE

CBNumber:: CB1285064

Molecular Formula:: C7H5BrF2

Molecular Weight:: 207.02

MDL Number:: MFCD00042488

MOL File:: 113211-94-2.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-04-24 14:58:24

Product description	Number	Pack Size	Price
2,3-Difluorobenzyl bromide 98%	265314	5g	$93.2
2,3-Difluorobenzyl Bromide >98.0%(GC)	D4320	1g	$29
2,3-Difluorobenzyl Bromide >98.0%(GC)	D4320	5g	$114
2,3-Difluorobenzyl bromide	D450868	10g	$95
2,3-Difluorobenzyl bromide	D450868	5g	$60
More product size

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2,3-Difluorobenzyl bromide Properties

Boiling point	190.5±25.0 °C(Predicted)
Density	1.628 g/mL at 25 °C(lit.)
refractive index	n20/D 1.528(lit.)
Flash point	194 °F
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	clear liquid
Specific Gravity	1.628
color	Colorless to Light yellow
Sensitive	Lachrymatory
BRN	7089244
InChI	1S/C7H5BrF2/c8-4-5-2-1-3-6(9)7(5)10/h1-3H,4H2
InChIKey	FTBSGSZZESQDBM-UHFFFAOYSA-N
SMILES	Fc1cccc(CBr)c1F
CAS DataBase Reference	113211-94-2(CAS DataBase Reference)
NIST Chemistry Reference	2,3-Difluorobenzyl bromide(113211-94-2)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H314

Precautionary statements

P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405

PPE

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Codes

C,Xi

Risk Statements

34-36/37/38

Safety Statements

26-36/37/39-45-25-36/37

RIDADR

UN 3265 8/PG 2

WGK Germany

10-19-21

Hazard Note

Corrosive/Lachrymatory

HazardClass

PackingGroup

III

HS Code

29049090

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Skin Corr. 1B

Limited Quantities

5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)

Excepted Quantities

Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

NFPA 704

	2
3		0

2,3-Difluorobenzyl bromide price More Price(39)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	265314	2,3-Difluorobenzyl bromide 98%	113211-94-2	5g	$93.2	2026-04-30	Buy
TCI Chemical	D4320	2,3-Difluorobenzyl Bromide >98.0%(GC)	113211-94-2	1g	$29	2026-04-30	Buy
TCI Chemical	D4320	2,3-Difluorobenzyl Bromide >98.0%(GC)	113211-94-2	5g	$114	2026-04-30	Buy
TRC	D450868	2,3-Difluorobenzyl bromide	113211-94-2	10g	$95	2021-12-16	Buy
TRC	D450868	2,3-Difluorobenzyl bromide	113211-94-2	5g	$60	2021-12-16	Buy

Product number	Packaging	Price	Buy
265314	5g	$93.2	Buy
D4320	1g	$29	Buy
D4320	5g	$114	Buy
D450868	10g	$95	Buy
D450868	5g	$60	Buy

2,3-Difluorobenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

2,3-Difluorobenzyl bromide was used in the synthesis of chemokine antagonists.

Synthesis

75853-18-8

113211-94-2

Step 2 (MW-S2): phosphorus tribromide (6.7 mL, 69.44 mmol) was added dropwise to a solution of diethyl ether (250 mL) of 2,3-difluorobenzyl alcohol (20 g, 138.88 mmol) at -10 °C. The reaction mixture was stirred at -10 °C for 1 hour. Upon completion of the reaction, the reaction was quenched with saturated sodium bicarbonate solution. The organic layer was separated and the aqueous layer was extracted with diethyl ether (2 x 100 mL). The combined organic layers were washed sequentially with water (100 mL), brine (100 mL), dried with anhydrous sodium sulfate, filtered and concentrated in vacuum to give 20 g of 2,3-difluorobenzyl bromide (MW-52) as a light brown liquid, which can be used in the next reaction without further purification.

References

[1] Journal of Medicinal Chemistry, 1988, vol. 31, # 5, p. 1005 - 1009
[2] Patent: WO2014/140279, 2014, A1. Location in patent: Page/Page column 88; 170

2,3-Difluorobenzyl bromide Preparation Products And Raw materials

Raw materials

2,3-Difluorobenzyl alcohol Phosphorus tribromide Diethyl ether

Preparation Products

(S)-2-AMINO-3-(2,3-DIFLUORO-PHENYL)-PROPIONIC ACID

2,3-Difluorobenzyl bromide Suppliers

Global( 265)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8738	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20124	58
Hefei Lbao Physical & Chemical Science Co.,Ltd	+15184799099	lbaochemicals@gmail.com	China	671	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29640	60
Hi-Tech Chemistry Corp	0519-86626038	yuhh@hitechem.com	CHINA	810	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21590	55
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1445	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29819	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10404	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Henan Fengda Chemical Co., Ltd	58
Hefei Lbao Physical & Chemical Science Co.,Ltd	58
Capot Chemical Co.,Ltd.	60
Hi-Tech Chemistry Corp	58
Henan Tianfu Chemical Co.,Ltd.	55
Fluoropharm Co., Ltd.	60
career henan chemical co	58
Shenzhen Nexconn Pharmatechs Ltd	58
Jinan Carbotang Biotech Co.,Ltd.	58

View Lastest Price from 2,3-Difluorobenzyl bromide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-04-29	2,3-Difluorobenzyl bromide 113211-94-2	US $0.00 / kg	1kg	98%	Customise	Hefei Lbao Physical & Chemical Science Co.,Ltd
2026-03-20	2,3-Difluorobenzyl bromide 113211-94-2	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Chuanghai Biotechnology Co., Ltd
2025-09-25	2,3-Difluorobenzyl bromide 113211-94-2	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd

2,3-Difluorobenzyl bromide
113211-94-2
US $0.00 / kg
98%
Hefei Lbao Physical & Chemical Science Co.,Ltd

2,3-Difluorobenzyl bromide
113211-94-2
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

2,3-Difluorobenzyl bromide
113211-94-2
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

2,3-Difluorobenzyl bromide Spectrum

2,3-Difluorobenzyl bromide(113211-94-2)FT-IR 2,3-Difluorobenzyl bromide(113211-94-2)IR 2,3-Difluorobenzyl bromide(113211-94-2)Raman

113211-94-2(2,3-Difluorobenzyl bromide)Related Search:

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2,3,6-TRIFLUOROBENZYL BROMIDE Bromine 2,3,5-TRIFLUOROBENZYL BROMIDE

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TIMTEC-BB SBB006681 ALPHA-BROMO-2,3-DIFLUOROTOLUENE 1-(BROMOMETHYL)-2,3-DIFLUORO-BENZENE 2,3-DIFLUOROBENZYL BROMIDE Benzene, 1-(bromomethyl)-2,3-difluoro- à-bromo-2,3-difluorotoluene α-bromo-2,3-difluorotoluene 2,3-Difluorobenzyl bromide 98% 2,3-Difluorobenzylbromide98% 2,3-Difluorophenyl bromide α-Bromo-2,3-difluorotoluene ,98% alpha-Bromo-2,3-difluorotoluene,98% 2,3-DifluorobenzylBromide> 2,3-Difluorobenzyl bromide ISO 9001：2015 REACH CAS:113211-94-2 1-(Bromomethyl)-2,3-difluoro benzene 2,3-Difluorobenzyl bromide 113211-94-2 F2C6H3CH2Br C7H5BrF2 BENZYL HALIDE Building Blocks Halogenated Hydrocarbons Organic Building Blocks Aryl C7 Miscellaneous Benzenes Fluoro-contained benzyl bromide series Aromatic compound