ChemicalBook >> CAS DataBase List >>3,4-Diaminofurazan

3,4-Diaminofurazan

CAS No.
17220-38-1
Chemical Name:
3,4-Diaminofurazan
Synonyms
AKOS BB-9341;Furazandiamine;furan-3,4-diamine;3,4-DIAMINOFURAZAN;VITAS-BB TBB000397;4,5-Diaminofurazan;3,4-Furazandiamine;TIMTEC-BB SBB000032;FURAZAN-3,4-DIAMINE;3,4-DIAMINOFURAZANE
CBNumber:
CB1341139
Molecular Formula:
C2H4N4O
Molecular Weight:
100.08
MDL Number:
MFCD00138084
MOL File:
17220-38-1.mol
MSDS File:
SDS
Last updated:2025-08-29 17:52:28

3,4-Diaminofurazan Properties

Melting point 178-183 °C
Boiling point 304.0±45.0 °C(Predicted)
Density 1.582±0.06 g/cm3(Predicted)
storage temp. 2-8°C
pka 1.31±0.47(Predicted)
form Crystalline Powder
color White to slightly beige
InChI InChI=1S/C2H4N4O/c3-1-2(4)6-7-5-1/h(H2,3,5)(H2,4,6)
InChIKey JHJVSUCUNFXIHN-UHFFFAOYSA-N
SMILES O1N=C(N)C(N)=N1
CAS DataBase Reference 17220-38-1(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  24/25-26-36/37
WGK Germany  3
HazardClass  IRRITANT
HS Code  29349990
NFPA 704
0
2 0

3,4-Diaminofurazan price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 749524 3,4-Diaminofurazan 97% 17220-38-1 1g $42.94 2025-07-31 Buy
TCI Chemical D4030 3,4-Diaminofurazan >98.0%(GC) 17220-38-1 1g $98 2025-07-31 Buy
TCI Chemical D4030 3,4-Diaminofurazan >98.0%(GC) 17220-38-1 5g $351 2025-07-31 Buy
TRC D416440 3,4-Diaminofurazan 17220-38-1 5g $195 2021-12-16 Buy
AK Scientific 8855AA 3,4-Diaminofurazan 17220-38-1 10g $241 2021-12-16 Buy
Product number Packaging Price Buy
749524 1g $42.94 Buy
D4030 1g $98 Buy
D4030 5g $351 Buy
D416440 5g $195 Buy
8855AA 10g $241 Buy

3,4-Diaminofurazan Chemical Properties,Uses,Production

Description

3,4-Diaminofurazan (DAF) is a simple furanocyclic compound. Since DAF molecule has two highly reactive neighbouring amino groups, it is considered to be the basic structure for the preparation of other complex energetic compounds by oxidation, acylation and azide reactions. Energetic compounds based on DAF include: aminonitrofurazan (ANF), 3,4-dinitrofurazan (DNF), 4,4-diamino-3,3-diazofurazan (DAAF) and 4,4-diamino-3,3-diazofurazan (DAAzF).

Chemical Properties

white to slightly beige crystalline powder

Uses

3,4-Diaminofurazan is a building block used to prepare magnesium and zinc alkynylated salicylaldehyde-diamine Schiff base complexes. 3,4-Diaminofurazan is also used to prepare aryl(hydroxy)oxadiazolopyrazines via oxidation of acetophenones followed by heterocyclization with antibacterial-activities.

Synthesis

DIAMINOGLYOXIME

2580-79-2

3,4-Diaminofurazan

17220-38-1

The general procedure for the synthesis of 3,4-diaminofurazan from diaminoglyoxime is as follows: Example 1: Synthesis of 3,4-diaminofurazan. In a 500 mL round-bottomed flask equipped with a mechanical stirrer and a thermometer, ethylene glycol (150 mL) was heated to 120 °C. To this hot solution, diaminoglyoxime (50 g, 0.42 mol) and potassium hydroxide (24 g, 0.42 mol) were added sequentially. The reaction mixture was warmed to 170 °C and maintained at this temperature for 1 hour. Upon completion of the reaction, the clarified reaction solution was cooled to room temperature and subsequently slowly poured into a mixture consisting of ice (500 g) and water (100 mL). The mixture was stirred vigorously for 5 minutes until 3,4-diaminofurazan precipitated as solid crystals. The precipitate was collected by filtration, washed with cold water (20 mL) and subsequently dried in air overnight to give 22 g of an off-white solid product (52% yield) with a melting point of 179-181 °C (literature value: Gunasekaran, A. et al., 179-180 °C). The 1H NMR (DMSO-d6) data of the product were as follows: δ 5.81 (s) ppm.

structure and hydrogen bonding

The unit cell parameter for monoclinic crystals of 3,4-Diaminofurazan at 20℃: a = 3.6035(3), b = 11.141(2), c = 10.329(1)Å, β = 94.80(1) , V = 413.2(1)Å3, Z = 4, dcalc = 1.61 g/cm 3, space group C2/c[1]
3,4-Diaminofurazan.

References

[1] A. S. Batsanov, Yu. T. Struchkov. “Crystal structure of 3,4-diaminofurazan and 3-amino-4-nitrofurazan.” Journal of Structural Chemistry 26 1 (1985): 52–56.

2580-79-2
17220-38-1
Synthesis of 3,4-Diaminofurazan from DIAMINOGLYOXIME

3,4-Diaminofurazan Preparation Products And Raw materials

Global( 234)Suppliers
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Wuhan Jingkang en Biomedical Technology Co., Ltd
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Accela ChemBio Inc.
+1-858-6993322 info@accelachem.com United States 21193 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58

View Lastest Price from 3,4-Diaminofurazan manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3,4-Diaminofurazan pictures 2025-08-29 3,4-Diaminofurazan
17220-38-1
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mujin Biotechnology Co.,Ltd
3,4-Diaminofurazan pictures 2025-06-24 3,4-Diaminofurazan
17220-38-1
US $10.00 / KG 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
3,4-Diaminofurazan pictures 2025-06-19 3,4-Diaminofurazan
17220-38-1
US $1.60-6.60 / kg 1kg 99% 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
  • 3,4-Diaminofurazan pictures
  • 3,4-Diaminofurazan
    17220-38-1
  • US $1.60-6.60 / kg
  • 99%
  • ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

3,4-Diaminofurazan Spectrum

FURAZAN-3,4-DIAMINE Furazandiamine 3,4-Diamino-1,2,5-oxadiazole 3,4-DIAMINOFURAZAN 3,4-DIAMINOFURAZANE 4-AMINO-1,2,5-OXADIAZOL-3-YLAMINE AKOS BB-9341 TIMTEC-BB SBB000032 VITAS-BB TBB000397 3,4-DIAMINOFURAZAN/FURAZANDIAMINE 3,4-DIAMINOFURAZAN 99% 3,4-Diaminofurazan,97% 1,2,5-oxadiazole-3,4-diamine(SALTDATA: FREE) 3,4-DiaMinofurazan, 97% 1GR (4-aminofurazan-3-yl)amine 4,5-Diaminofurazan furan-3,4-diamine 3,4-Diaminofurazan> 3,4-Furazandiamine 3,4-Diaminofurazone 17220-38-1 C2H4N4O Amines API