3,4-Diaminofurazan
- CAS No.
- 17220-38-1
- Chemical Name:
- 3,4-Diaminofurazan
- Synonyms
- AKOS BB-9341;Furazandiamine;furan-3,4-diamine;3,4-DIAMINOFURAZAN;VITAS-BB TBB000397;4,5-Diaminofurazan;3,4-Furazandiamine;TIMTEC-BB SBB000032;FURAZAN-3,4-DIAMINE;3,4-DIAMINOFURAZANE
- CBNumber:
- CB1341139
- Molecular Formula:
- C2H4N4O
- Molecular Weight:
- 100.08
- MDL Number:
- MFCD00138084
- MOL File:
- 17220-38-1.mol
- MSDS File:
- SDS
Melting point | 178-183 °C |
---|---|
Boiling point | 304.0±45.0 °C(Predicted) |
Density | 1.582±0.06 g/cm3(Predicted) |
storage temp. | 2-8°C |
pka | 1.31±0.47(Predicted) |
form | Crystalline Powder |
color | White to slightly beige |
InChI | InChI=1S/C2H4N4O/c3-1-2(4)6-7-5-1/h(H2,3,5)(H2,4,6) |
InChIKey | JHJVSUCUNFXIHN-UHFFFAOYSA-N |
SMILES | O1N=C(N)C(N)=N1 |
CAS DataBase Reference | 17220-38-1(CAS DataBase Reference) |
UNSPSC Code | 12352100 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi,Xn | |||||||||
Risk Statements | 36/37/38-22 | |||||||||
Safety Statements | 24/25-26-36/37 | |||||||||
WGK Germany | 3 | |||||||||
HazardClass | IRRITANT | |||||||||
HS Code | 29349990 | |||||||||
NFPA 704 |
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3,4-Diaminofurazan price More Price(30)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 749524 | 3,4-Diaminofurazan 97% | 17220-38-1 | 1g | $42.94 | 2025-07-31 | Buy |
TCI Chemical | D4030 | 3,4-Diaminofurazan >98.0%(GC) | 17220-38-1 | 1g | $98 | 2025-07-31 | Buy |
TCI Chemical | D4030 | 3,4-Diaminofurazan >98.0%(GC) | 17220-38-1 | 5g | $351 | 2025-07-31 | Buy |
TRC | D416440 | 3,4-Diaminofurazan | 17220-38-1 | 5g | $195 | 2021-12-16 | Buy |
AK Scientific | 8855AA | 3,4-Diaminofurazan | 17220-38-1 | 10g | $241 | 2021-12-16 | Buy |
3,4-Diaminofurazan Chemical Properties,Uses,Production
Description
3,4-Diaminofurazan (DAF) is a simple furanocyclic compound. Since DAF molecule has two highly reactive neighbouring amino groups, it is considered to be the basic structure for the preparation of other complex energetic compounds by oxidation, acylation and azide reactions. Energetic compounds based on DAF include: aminonitrofurazan (ANF), 3,4-dinitrofurazan (DNF), 4,4-diamino-3,3-diazofurazan (DAAF) and 4,4-diamino-3,3-diazofurazan (DAAzF).
Chemical Properties
white to slightly beige crystalline powder
Uses
3,4-Diaminofurazan is a building block used to prepare magnesium and zinc alkynylated salicylaldehyde-diamine Schiff base complexes. 3,4-Diaminofurazan is also used to prepare aryl(hydroxy)oxadiazolopyrazines via oxidation of acetophenones followed by heterocyclization with antibacterial-activities.
Synthesis

2580-79-2

17220-38-1
The general procedure for the synthesis of 3,4-diaminofurazan from diaminoglyoxime is as follows: Example 1: Synthesis of 3,4-diaminofurazan. In a 500 mL round-bottomed flask equipped with a mechanical stirrer and a thermometer, ethylene glycol (150 mL) was heated to 120 °C. To this hot solution, diaminoglyoxime (50 g, 0.42 mol) and potassium hydroxide (24 g, 0.42 mol) were added sequentially. The reaction mixture was warmed to 170 °C and maintained at this temperature for 1 hour. Upon completion of the reaction, the clarified reaction solution was cooled to room temperature and subsequently slowly poured into a mixture consisting of ice (500 g) and water (100 mL). The mixture was stirred vigorously for 5 minutes until 3,4-diaminofurazan precipitated as solid crystals. The precipitate was collected by filtration, washed with cold water (20 mL) and subsequently dried in air overnight to give 22 g of an off-white solid product (52% yield) with a melting point of 179-181 °C (literature value: Gunasekaran, A. et al., 179-180 °C). The 1H NMR (DMSO-d6) data of the product were as follows: δ 5.81 (s) ppm.
structure and hydrogen bonding
The unit cell parameter for monoclinic crystals of 3,4-Diaminofurazan at 20℃: a = 3.6035(3), b = 11.141(2), c = 10.329(1)Å, β = 94.80(1) , V = 413.2(1)Å3, Z = 4, dcalc = 1.61 g/cm 3, space group C2/c[1].
References
[1] A. S. Batsanov, Yu. T. Struchkov. “Crystal structure of 3,4-diaminofurazan and 3-amino-4-nitrofurazan.” Journal of Structural Chemistry 26 1 (1985): 52–56.
3,4-Diaminofurazan Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Wuhan Jingkang en Biomedical Technology Co., Ltd | +8613720134139 | orders@jknbiochem.com | China | 5221 | 58 |
Hebei Chuanghai Biotechnology Co., Ltd | +8617732866630 | abby@chuanghaibio.com | China | 8773 | 58 |
Hebei Mujin Biotechnology Co.,Ltd | +8613288715578 | sales@hbmojin.com | China | 12464 | 58 |
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 | jiuyitime@fdachem.com | China | 8684 | 58 |
Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29733 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2136 | 58 |
Biochempartner | 0086-13720134139 | candy@biochempartner.com | CHINA | 965 | 58 |
Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
View Lastest Price from 3,4-Diaminofurazan manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2025-08-29 | 3,4-Diaminofurazan
17220-38-1
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mujin Biotechnology Co.,Ltd | |
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2025-06-24 | 3,4-Diaminofurazan
17220-38-1
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
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2025-06-19 | 3,4-Diaminofurazan
17220-38-1
|
US $1.60-6.60 / kg | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD |
-
- 3,4-Diaminofurazan
17220-38-1
- US $0.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
-
- 3,4-Diaminofurazan
17220-38-1
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 3,4-Diaminofurazan
17220-38-1
- US $1.60-6.60 / kg
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
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