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(-)-Taddol

(-)-Taddol Structure
(-)-Taddol structure
CAS No.
93379-48-7
Chemical Name:
(-)-Taddol
Synonyms
TADDOL;(R,R)-TADDOL;((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol);5R)-2;a'(-)-TADDOL;SEEBACH REAGENT;(-)-TADDOL 98%, (99% E.E.);(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-;(2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY
CBNumber:
CB1399332
Molecular Formula:
C31H30O4
Molecular Weight:
466.58
MDL Number:
MFCD00064467
MOL File:
93379-48-7.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:33:35
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(-)-Taddol Properties

Melting point 193-195 °C(lit.)
alpha -65.5 º (c=1, CHCl3)
Boiling point 489.39°C (rough estimate)
Density 1.0864 (rough estimate)
refractive index -69 ° (C=1, CHCl3)
storage temp. Inert atmosphere,Room Temperature
form Powder
pka 12.28±0.29(Predicted)
color white
optical activity [α]19/D 62.6°, c = 1 in chloroform
BRN 3657855
InChIKey RNSJHECWLNVNFE-KYJUHHDHSA-N
SMILES C(C1C=CC=CC=1)(C1C=CC=CC=1)([C@@H]1OC(C)(C)O[C@H]1C(C1C=CC=CC=1)(C1C=CC=CC=1)O)O |&1:13,19,r|
CAS DataBase Reference 93379-48-7(CAS DataBase Reference)
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P301+P312-P302+P352-P304+P340-P305+P351+P338
PPE Eyeshields, Gloves, type N95 (US)
Hazard Codes  Xi,Xn
Risk Statements  36/38-36/37/38-20/21/22
Safety Statements  24/25-36-26
WGK Germany  3
HS Code  29329970
Storage Class 11 - Combustible Solids

(-)-Taddol price More Price(58)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 265004 (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol 97% 93379-48-7 1g $118 2026-04-30 Buy
TCI Chemical B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane >97.0%(HPLC) 93379-48-7 1g $56 2026-04-30 Buy
TCI Chemical B1614 (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane >97.0%(HPLC) 93379-48-7 5g $169 2026-04-30 Buy
Strem Chemicals 08-2008 (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL 93379-48-7 500mg $90 2026-04-30 Buy
Strem Chemicals 08-2008 (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL 93379-48-7 2g $268 2026-04-30 Buy
Product number Packaging Price Buy
265004 1g $118 Buy
B1614 1g $56 Buy
B1614 5g $169 Buy
08-2008 500mg $90 Buy
08-2008 2g $268 Buy

(-)-Taddol Chemical Properties, Uses, Production

Chemical Properties

white to light yellow crystal powde

Uses

Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bonding

Catalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amides

Reactant or reagent involved in:

  • Enantioswitching of catalytic asymmetric hydroboration
  • Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
  • Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
  • Addition of deactivated alkyl Grignard reagents to aldehydes

(-)-Taddol Preparation Products And Raw materials

Raw materials

p-Toluenesulfonic acid D-(-)-Tartaric Acid Bromobenzene Tetrahydrofuran Ethyl acetate
Dichloromethane Methanol

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Preparation Products

1,3-Dioxolane, 4,5-bis(chlorodiphenylmethyl)-2,2-dimethyl-, (4R,5R)-

(-)-Taddol Suppliers

Global Suppliers ( 179)
Supplier Tel Email Country ProdList Advantage
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 4094 50
Chongqing Botao Biotechnology Co., LTD 15223382610 danny@chemdad.com China 2030 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Adamas Reagent, Ltd. 400-6009262 15618770481 yhx@titansci.com China 14098 59
Accela ChemBio Co.,Ltd. 021-50795510 4000665055 marketing@accelachem.com China 10972 64
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Supplier Advantage
Tianjin Derchemist Science & Technology Co., Ltd. 50
Chongqing Botao Biotechnology Co., LTD 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Capot Chemical Co., Ltd 66
Adamas Reagent, Ltd. 59
Accela ChemBio Co.,Ltd. 64
Shanghai Longsheng chemical Co.,Ltd. 59

View Latest Price from (-)-Taddol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(-)-Taddol pictures 2019-07-06 (-)-Taddol
93379-48-7
 $2.00 1kg 99% 100kg Career Henan Chemical Co
  • (-)-Taddol pictures
  • (-)-Taddol
    93379-48-7
  • $2.00
  • 99%
  • Career Henan Chemical Co

(-)-Taddol Spectrum

(-)-Taddol(93379-48-7)MS(-)-Taddol(93379-48-7)1HNMR(-)-Taddol(93379-48-7)13CNMR(-)-Taddol(93379-48-7)IR1(-)-Taddol(93379-48-7)IR2(-)-Taddol(93379-48-7)Raman

93379-48-7 ((-)-Taddol) Related Search:

N,N-Dimethylformamide Dimethyl sulfoxide Dimethyl sulfide Dimethyl fumarate Chlorodimethylphenylsilane
Selenium dioxide Dimethyl phthalate Dimethyl ether 1,4-Dioxane Ethane
Dioxopromethazine HCl 1,3-Dioxolane (+)-Taddol,(+)-TADDOL,(+)-Taddol,(+)-TADDOL Dioxopromethazine (4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol
(3aR,8aR)-(-)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine 2,2-Dimethyl-1,3-dioxolane L-THREITOL

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(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL (-)-TADDOL SEEBACH REAGENT (4R,5R)-2,2-DIMETHYL-ALPHA, ALPHA, ALPHA', ALPHA'-TETRAPHENYLDIOXOLANE-4,5-DIMETHANOL (4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol TADDOL, (4R,5R)-4,5-Bis(diphenylhydroxymethyl)-2,2-dimethyldioxolane, 1,1,4,4-Tetraphenyl-2,3-O-isopropylidene-L-threitol, (-)-trans-α,αμ-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol), (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol (-)-trans-a,a'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) [(4R,5R)-5-(hydroxy-diphenyl-methyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-diphenyl-methanol 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-a,a,a',a'-tetraphenyl-, (4R,5R)- (4R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4β,5α-bismethanol (4R,5R)-2,2-Dimethyl-4,5-bis(hydroxydiphenylmethyl)-1,3-dioxolane (4R,5R)-4,5-Bis(hydroxydiphenylmethyl)-2,2-dimethyl-1,3-dioxolane (4R,5R)-α,α,α',α'-Tetraphenyl-2,2-dimethyl-1,3-dioxolane-4,5-bismethanol α,α'-[(4R,5R)-2,2-Dimethyl-1,3-dioxolane-4β,5α-diyl]bis(diphenylmethanol) (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol(-TADDOL) (-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol, TADDOL (4R,5R)-2,2-Dimethyl-α,α,α′,α′-tetraphenyldioxolane-4,5-dimethanol ,97% (4R,5R)-(-)-2,2-Dimethyl-a,a,a',a'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol (-)-TRANS-4,5-BIS-(DIPHENYL-HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-TRANS-ALPHA,ALPHA'-(2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL) (-)-TRANS-ALPHA,ALPHA'-(DIMETHYL-1,3-DIOXOLANE-4,5-DIYL)BIS(DIPHENYLMETHANOL) (-)-2,3-O-Isopropylidene-1,1,4,4-Tetraphenyl-L-Threitol(4R,5R)-2,2-Dimethyl-Alpha,Alpha,Alpha',Alpha'-Tetraphenyldioxolane-4,5-Dimethanol (4R,5R)-2,2-Dimethyl-a,a,a',a'-tetraphenyldioxolane-4,5-dimethanol ( - )-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl- L-threitol [(4R,5R)-2,2-Dimethyl-a,a,a’, a’-tetraphenyldioxolane-4,5-dimethanol (-)-2,3-O-Isopropylidene-1,1,4,4-tetrphenyl-L-threitol (-)-TRANS-A,A'-(2,2-DIMETHYL-1,3-DIOXOLA NE -4,5-DIYL)BIS(DIPHENYLMETHANOL) (4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)2, 2-DIMETHYL (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethan (-)-Trans-A,A'-(2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Bis(Diphenylmethanol),ChemAbs (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol[(4R,5R)-2,2-
Dimethyl-a,a,aatetraphenyldioxolane-4,5-dimethanol (4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanol(R,R)-TADDOL (4r,5r)-2,2-dimethyl-α,α,α',α'-tetraphenyldioxolane-4,5-dimethanol (-)-TADDOL 98%, (99% E.E.) (2R,3R)-(-)-1,1,4,4-TETRAPHENYL-2,3-(2-PROPYLIDENEDIOXY)-BUTANE-1,4-DIOL (2R,3R)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-1,2,3,4-BUTANETETROL (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL (-)-(4R,5R)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOL (-)-trans-alpha,alpha'-(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (2R,3R)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-1,2,3,4-butanetetrol (-)-2,3-O-Isopropylidene-1,1,4,4-tetraphenyl-L-threitol (2R,3R)-(-)-4,5-BIS(DIPHENYLHYDROXYMETHY (-)-Taddol (-)-trans-alpha,alpha'-(Dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) (4R,5R)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyldioxolane-4,5-dimethanol 97% 5R)-2 (R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL '-tetraphenyl-1,3-dioxolane-4,5-dimethanol (R,R)-TADDOL (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane > (-)-trans-α,α'-(2,2-Dimethyl-1,3-dioxane-4,5-diyl)bis(diphenylmethanol) 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetraphenyl-, (4R,5R)- (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxol... (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol, (R,R)-TADDOL (4R,5R)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanol