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4-tert-Butylbenzyl bromide

4-tert-Butylbenzyl bromide structure

CAS No.: 18880-00-7

Chemical Name:: 4-tert-Butylbenzyl bromide

Synonyms: 4-(TERT-BUTYL)BENZYL BROMIDE;4-tert-Butylbenzyl b;P-T-BUTYLBENZYL BROMIDE;P-TERT-BUTYLBENZYL BROMIDE;4-Tert-Buthylbenzyl Bromide;α-bromo-4-(tert-butyl)toluene;4-(tert-Butyl)benzylbromide,97%;4-(TERT-BUTYL)BENZYLBROMIDE 97%;ALPHA-BROMO-4-(TERT-BUTYL)TOLUENE;4-tert-Butylbenzyl bromide

CBNumber:: CB1454718

Molecular Formula:: C11H15Br

Molecular Weight:: 227.14

MDL Number:: MFCD00000180

MOL File:: 18880-00-7.mol

MSDS File:: SDS

Last updated:2025-09-09 18:15:22

Product description	Number	Pack Size	Price
4-tert-Butylbenzyl bromide 97%	270768	5g	$29.23
4-tert-Butylbenzyl bromide 97%	270768	25g	$135.49
1-(Bromomethyl)-4-tert-butylbenzene min. 98.0 %	B6337	5G	$79
1-(Bromomethyl)-4-tert-butylbenzene min. 98.0 %	B6337	25G	$237
4-tert-Butylbenzyl bromide	B692456	10g	$80
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4-tert-Butylbenzyl bromide Properties

Melting point	8-12 °C (lit.)
Boiling point	93-94 °C/1.5 mmHg (lit.)
Density	1.236 g/mL at 25 °C (lit.)
refractive index	n20/D 1.545(lit.)
Flash point	>230 °F
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	Chloroform (Slightly), Ethyl Acetate (Slightly)
form	Liquid
color	Clear light yellow
Specific Gravity	1.236
BRN	471674
InChI	InChI=1S/C11H15Br/c1-11(2,3)10-6-4-9(8-12)5-7-10/h4-7H,8H2,1-3H3
InChIKey	QZNQSIHCDAGZIA-UHFFFAOYSA-N
SMILES	C1(CBr)=CC=C(C(C)(C)C)C=C1
CAS DataBase Reference	18880-00-7(CAS DataBase Reference)
FDA UNII	49N4J7MYP3
NIST Chemistry Reference	p-tert-Butylbenzyl bromide(18880-00-7)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H314

Precautionary statements

P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405

Hazard Codes

C,Xi

Risk Statements

Safety Statements

26-36/37/39-45

RIDADR

UN 3265 8/PG 2

WGK Germany

HazardClass

PackingGroup

HS Code

29036990

NFPA 704

	0
3		0

4-tert-Butylbenzyl bromide price More Price(19)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	270768	4-tert-Butylbenzyl bromide 97%	18880-00-7	5g	$29.23	2025-07-31	Buy
Sigma-Aldrich	270768	4-tert-Butylbenzyl bromide 97%	18880-00-7	25g	$135.49	2025-07-31	Buy
TCI Chemical	B6337	1-(Bromomethyl)-4-tert-butylbenzene min. 98.0 %	18880-00-7	5G	$79	2025-07-31	Buy
TCI Chemical	B6337	1-(Bromomethyl)-4-tert-butylbenzene min. 98.0 %	18880-00-7	25G	$237	2025-07-31	Buy
TRC	B692456	4-tert-Butylbenzyl bromide	18880-00-7	10g	$80	2021-12-16	Buy

Product number	Packaging	Price	Buy
270768	5g	$29.23	Buy
270768	25g	$135.49	Buy
B6337	5G	$79	Buy
B6337	25G	$237	Buy
B692456	10g	$80	Buy

4-tert-Butylbenzyl bromide Chemical Properties,Uses,Production

Chemical Properties

colorless to light yellow liquid

Uses

4-tert-Butylbenzyl bromide, a hydrophobic reactant, was used to keep the loaded mesoporous material particles under continuous stirring.

General Description

The nucleophilic substitution reaction of 4-tert-butylbenzyl bromide and potassium iodide was carried out in oil-in-water microemulsions based on various surfactants.

Synthesis

98-51-1

18880-00-7

General procedure for the synthesis of 4-tert-butylbenzyl bromide from 4-tert-butyltoluene: Referring to Example 19 Preparation of N-(4-tert-butylbenzyl)methanamine (Alternative method), 4-tert-butyltoluene (14.8 g, 0.10 mol) was dissolved in carbon tetrachloride, and N-bromosuccinimide (17.8 g, 0.10 mol) and benzoyl peroxide (200 mg) were added . The reaction mixture was refluxed for 2 h and subsequently cooled to room temperature. The insoluble material was removed by filtration and the filtrate was washed with carbon tetrachloride. The filtrate was concentrated under reduced pressure and the resulting residue was dissolved in hexane and dried with magnesium sulfate. Finally, the solvent was evaporated under reduced pressure to give 22.7 g of 4-tert-butylbenzyl bromide (yield: 100%).

References

[1] Patent: US6586633, 2003, B1
[2] Patent: CN105315127, 2016, A. Location in patent: Paragraph 0044-0050
[3] Tetrahedron Letters, 2009, vol. 50, # 16, p. 1861 - 1865
[4] Synthesis, 2009, # 11, p. 1807 - 1810
[5] Synthetic Communications, 2010, vol. 40, # 7, p. 998 - 1003

4-tert-Butylbenzyl bromide synthesis

Synthesis of 4-tert-Butylbenzyl bromide from 4-tert-Butyltoluene

4-tert-Butylbenzyl bromide Preparation Products And Raw materials

Raw materials

Benzene, 1-(dibromomethyl)-4-(1,1-dimethylethyl)- Benzene-13C, (1,1-dimethylethyl)- (9CI) N-Bromosuccinimide Hexane Carbon tetrachloride

Benzoyl peroxide Formaldehyde 4-tert-Butyltoluene

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Preparation Products

1-tert-Butyl-4-(2,2,2-trifluoroethyl)benzene 4-tert-Butylbenzaldehyde 2-bromo-1-methyl-4-tert-butyl-benzene 4-TERT-BUTYLBENZYL ALCOHOL 4-TERT-BUTYLPHENYLACETIC ACID

4-tert-Butylbenzyl bromide Suppliers

Global( 241)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shandong Liteng Biotechnology Co. , Ltd.	+86-18663721413 +86-15552573001	rosy@litengpharm.com	China	3283	58
Shanghai 3S Technology Co., Ltd	+86-18221206281 +86-18221206281	luqing@3s-tech.net	China	64	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8772	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-81139210 +86-18192627656	1059@dideu.com	China	3587	58
Sichuan Zhuoyu Yantang Technology Co., Ltd.	+8613288715578	sales@sichuanzyyt.com	China	12245	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20174	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
Shanghai Yingrui Biopharma Co., Ltd.	+86-21-33585366 - 03@	sales03@shyrchem.com	CHINA	738	60
Fluoropharm Co., Ltd.	+86-0571-85586753 +86-13336034509	sales@fluoropharm.com	China	1445	60
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58

Supplier	Advantage
Shandong Liteng Biotechnology Co. , Ltd.	58
Shanghai 3S Technology Co., Ltd	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Shaanxi Dideu Medichem Co. Ltd	58
Sichuan Zhuoyu Yantang Technology Co., Ltd.	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Yingrui Biopharma Co., Ltd.	60
Fluoropharm Co., Ltd.	60
Alchem Pharmtech,Inc.	58

View Lastest Price from 4-tert-Butylbenzyl bromide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-10-21	4-tert-Butylbenzyl bromide 18880-00-7	US $0.00-0.00 / KG	1KG	99%	20 mt	Hebei Chuanghai Biotechnology Co., Ltd
2025-09-25	4-tert-Butylbenzyl bromide 18880-00-7	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2025-09-09	4-tert-Butylbenzyl bromide 18880-00-7	US $0.00 / KG	1KG	99%	50000KG/month	Sichuan Zhuoyu Yantang Technology Co., Ltd.

4-tert-Butylbenzyl bromide
18880-00-7
US $0.00-0.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

4-tert-Butylbenzyl bromide
18880-00-7
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

4-tert-Butylbenzyl bromide
18880-00-7
US $0.00 / KG
99%
Sichuan Zhuoyu Yantang Technology Co., Ltd.

4-tert-Butylbenzyl bromide Spectrum

4-tert-Butylbenzyl bromide(18880-00-7)MS 4-tert-Butylbenzyl bromide(18880-00-7)¹HNMR 4-tert-Butylbenzyl bromide(18880-00-7)¹³CNMR 4-tert-Butylbenzyl bromide(18880-00-7)IR1 4-tert-Butylbenzyl bromide(18880-00-7)Raman

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α-Bromo-4-(tert-butyl)toluene, 1-Bromomethyl-4-tert-butylbenzene 4-tert-Butyl-1-(bromomethyl)benzene 4-tert-Butylbenzyl b 4-(tert-Butyl)benzylbroMide, 97% 25GR 4-(tert-Butyl)benzylbroMide, 97% 5GR 4-tert-Butylbenzyl bromide 4-(tert-Butyl)benzylbromide,97% 1-(BROMOMETHYL)-4-TERT-BUTYLBENZENE 4-(TERT-BUTYL)BENZYL BROMIDE ALPHA-BROMO-4-(TERT-BUTYL)TOLUENE P-T-BUTYLBENZYL BROMIDE P-TERT-BUTYLBENZYL BROMIDE Benzene, 1-(bromomethyl)-4-(1,1-dimethylethyl)- 4-Tert-Buthylbenzyl Bromide 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene 4-(TERT-BUTYL)BENZYLBROMIDE 97% α-bromo-4-(tert-butyl)toluene 4-tertButylbenzyl bromide, GC 97% 4-tert-Butylbenzyl bromide ISO 9001：2015 REACH 18880-00-7 18880-100-7 CH33CC6H4CH2Br BENZYL HALIDE Organic Building Blocks Halogenated Hydrocarbons Building Blocks C9 to C12 Aryl Building Blocks C9 to C12 Chemical Synthesis Halogenated Hydrocarbons Organic Building Blocks Aryl Halogen toluene Fluorobenzene OLED