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Dibutyl phosphate

CAS No.
107-66-4
Chemical Name:
Dibutyl phosphate
Synonyms
DIBUTYL HYDROGEN PHOSPHATE;DIBUTYL PHOSPHONATE;DI-N-BUTYL PHOSPHATE;hdbp;BUTYL PHOSPHATE;MONOBUTYL PHOSPHATE;di-n-butylphosphoric acid;di-n-butylhydrogenphosphate;Phosphorsuredi-n-butylester;Di-n-butylphos
CBNumber:
CB1489161
Molecular Formula:
C8H19O4P
Molecular Weight:
210.21
MDL Number:
MFCD00015245
MOL File:
107-66-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 23:39:51

Dibutyl phosphate Properties

Melting point -13 °C
Boiling point 250 °C
Density 1.06 g/mL at 20 °C (lit.)
vapor pressure 0Pa at 20℃
refractive index n20/D 1.428
Flash point 188 °C
storage temp. Store below +30°C.
solubility Chloroform (Soluble), Methanol (Slightly)
pka 1.53±0.50(Predicted)
form Liquid
Specific Gravity 1.1
color Clear
Water Solubility insoluble
BRN 607224
Henry's Law Constant 2.3×103 mol/(m3Pa) at 25℃, HSDB (2015)
Exposure limits ACGIH:TLV-TWA 5 mg/m3 (0.6 ppm),Inhalable fraction and vapor
OSHA:PEL-TWA 1 ppm (5 mg/m3)
NIOSH:REL-TWA 1 ppm; REL-STEL 2 ppm
InChI 1S/C8H19O4P/c1-3-5-7-11-13(9,10)12-8-6-4-2/h3-8H2,1-2H3,(H,9,10)
InChIKey JYFHYPJRHGVZDY-UHFFFAOYSA-N
SMILES CCCCOP(O)(=O)OCCCC
LogP -0.9 at 25℃
CAS DataBase Reference 107-66-4(CAS DataBase Reference)
FDA UNII 0072NN74TN
EPA Substance Registry System Dibutyl phosphate (107-66-4)
UNSPSC Code 12352106
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Health Hazard (GHS08)
GHS05,GHS08
Signal word  Danger
Hazard statements  H314-H351
Precautionary statements  P201-P202-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi,C
Risk Statements  37/38-41-38-34-40
Safety Statements  26-39-45-36/37/39-25
OEB B
OEL TWA: 1 ppm (5 mg/m3), STEL: 2 ppm (10 mg/m3)
RIDADR  3261
WGK Germany  1
RTECS  TB9605000
TSCA  TSCA listed
HazardClass  8
PackingGroup  III
HS Code  29199000
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Carc. 2
Eye Dam. 1
Skin Corr. 1B
Hazardous Substances Data 107-66-4(Hazardous Substances Data)
IDLA 30 ppm
REACH Registrations Active
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
1
3 0

Dibutyl phosphate price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 68572 Dibutyl phosphate ≥97.0% (T) 107-66-4 250ml $53.8 2026-04-30 Buy
Sigma-Aldrich 8.20251 Butyl phosphate (mixture of mono and di esters) for synthesis 1l $98.4 2026-04-30 Buy
Sigma-Aldrich 68572 Dibutyl phosphate ≥97.0% (T) 107-66-4 1l $183 2026-04-30 Buy
Sigma-Aldrich 8.20251 Butyl phosphate (mixture of mono and di esters) for synthesis 100ml $43.6 2025-07-31 Buy
TCI Chemical P0260 Dibutyl Phosphate >97.0%(T) 107-66-4 25g $22 2026-04-30 Buy
Product number Packaging Price Buy
68572 250ml $53.8 Buy
8.20251 1l $98.4 Buy
68572 1l $183 Buy
8.20251 100ml $43.6 Buy
P0260 25g $22 Buy

Dibutyl phosphate Chemical Properties, Uses, Production

Description

Dibutyl phosphate is a pale amber to brown,odorless liquid. Molecular weight = 210.24; Specificgravity (H2O:1) = 1.06; Boiling point = (decomposes)135-138℃; Freezing/Melting point = 213℃; Vapor pressure-1 mmHg at 20℃; Flash point = 188℃ (oc);Autoignition temperature = 420℃. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 2, Reactivity 0. Practically insoluble in water.

Chemical Properties

Dibutyl phosphate is a pale amber to brown, odorless liquid. It is used as a catalyst for cross-linking in the paint industry and antistatics for the textile industry. It is stable in neutral, acidic or alkaline solution, and is classified as "not readily biodegradable" but inhererently biodegradable.The half-life time of 4.99 years is estimated for the degradation of dibutyl phosphate in air by the reaction with photochemically produced OH radicals. (MITI, Japan).

Uses

Pale amber liquid

Uses

Dibutyl phosphate is used as a plasticizer for polymer system and hydraulic fluid directly and used as a catalyst for cross-linking in paint industry. It is used as an antifoam agent in ore separation process and as an antistatic agent in the textile industry. It can be used as a precursor for antistatics, as a mould release agent in polyurethane applications and, as a non volatile acidic catalyst soluble in organic media.

Definition

ChEBI: Dibutyl phosphate is a dialkyl phosphate.

General Description

Pale-amber odorless liquid. Mp: -13°C, bp: 135-138°C. Density: 1.06 g cm-3. Moderately soluble in water (18 g / L at 20°C).

Reactivity Profile

Dibutyl phosphate Is non-flammable, but combustible (flash point 188°C). Auto-ignition temperature is 420°C. Emits irritating or toxic fumes in a fire. Is a moderately strong acid obtained by the partial esterification of phosphoric acid. Reacts exothermically and vigorously with bases. Incompatible with strong oxidizing agents, alkali metals, heat, or plastic. Reacts with many metals liberating flammable/explosive hydrogen gas.

Health Hazard

Dibutyl phosphate is an irritant of the eyes and mucous membranes.

Flammability and Explosibility

Non flammable

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of POx. See also PHOSPHATES.

Potential Exposure

This material is used as a catalyst in organic synthesis.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theDibutyl phosphate 901skin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water ormilk. Do not induce vomiting.

storage

Color Code—White: Corrosive or Contact Hazard;Store separately in a corrosion-resistant location. Prior toworking with this chemical you should be trained on its properhandling and storage. Dibutyl phosphate must be stored toavoid contact with strong oxidizers, such as chlorine, chlorinedioxide, and bromine, since violent reactions occur.

Shipping

UN1760 Corrosive liquids, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3261 Corrosive solid, acidic, organic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

Dibutyl phosphate is a medium strong acid. Incompatible with oxidizers (chlorates, nitrates, per- oxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Attacks many metals forming flammable and explosive hydrogen gas. Attacks some plas- tics, rubber, and coatings.

Toxics Screening Level

Two initial threshold screening levels (ITSLs) for dibutyl phosphate, included an JTSL of 86 μg/m3 based on an 8-hour averaging time, and an ITSL of 170 μg/m3 based on a 1-hour averaging time.

819-43-2
107-66-4
Synthesis of Dibutyl phosphate from Dibutyl chlorophosphate

Dibutyl phosphate Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 299)
Supplier Tel Email Country ProdList Advantage
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd. 021-69106960 13701823997 13701823733@163.com China 4634 60
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
3B Pharmachem (Wuhan) International Co.,Ltd. 18930552037 3bsc@sina.com China 15813 69
future industrial shanghai co., ltd 400-0066400 13621662912 sales@jonln.com China 1989 65
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Longsheng chemical Co.,Ltd. 58099637 13585536065 sales@shlschem.com China 9880 59
Shandong Xiya Chemical Co., Ltd 13355009207 13355009207 3007715519@qq.com China 18722 57

View Latest Price from Dibutyl phosphate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dibutyl phosphate   pictures 2026-08-07 Dibutyl phosphate
107-66-4
$1.00 1KG 99% 200000KG Shaanxi Dideu Medichem Co. Ltd
Dibutyl phosphate pictures 2026-03-20 Dibutyl phosphate
107-66-4
$10.00 1kg 99.5% 100 Hebei Chuanghai Biotechnology Co., Ltd
Dibutyl Phosphate pictures 2025-06-20 Dibutyl Phosphate
107-66-4
1kg 99% 20tons Hebei Yanxi Chemical Co., Ltd.
di-n-butylhydrogenphosphate dp4(couplingagent) phosphatededibutyle DIBUTYL PHOSPHATE (DBP) Di-n-butyl phosphate, 97+% Dibutyl Phosphate (Mono- and Di- Ester mixture) di-n-Butyl hydrogen phsophate Dibutoxyphosphinic acid O,O-Dibutyl phosphate Phosphoric acid hydrogen dibutyl ester Di-n-butyl phosphate, 95+% Dibutyl phosphate,97% Dibutylphospate DI-n-BUTYL PHOSPHATE, TECH Dibutyl phosphate, 97% 250GR Dibutyl phosphate, 97% 500GR DIBUTYL ACID O-PHOSPHATE DIBUTYL PHOSPHATE DI(BUTYL) PHOSPHORIC ACID BUTYL PHOSPHATE Dibutyl phosphate >=97.0% (T) Di-n-butylphos Di-n-butyl phosphate PHOSPHORIC ACID DI-N-BUTYL ESTER PHOSPHORIC ACID DIBUTYL ESTER PHOSPHORIC ACID BUTYL ESTER dibutylacidphosphate DibutylPhosphate> Xanthine Impurity 10 dinbutylphosphoric acidester DIBUTYL HYDROGEN PHOSPHATE DIBUTYL PHOSPHONATE di-n-butylphosphoric acid DI-N-BUTYL PHOSPHATE hdbp MONOBUTYL PHOSPHATE Phosphorsuredi-n-butylester 107-66-4 C8H19O4P C4H9O2HPO2 CH3CH2CH2CH2O2POOH CH3CH23O2POOH Building Blocks Organic Building Blocks Organic Phosphates/Phosphites Phosphorus Compounds bc0001