ChemicalBook >> CAS DataBase List >>TRIPHENYLPHOSPHINE DIBROMIDE

TRIPHENYLPHOSPHINE DIBROMIDE

CAS No.
1034-39-5
Chemical Name:
TRIPHENYLPHOSPHINE DIBROMIDE
Synonyms
DIBROMOTRIPHENYLPHOSPHORANE;Triphenyldibromophosphorane;SKL183;phosphine dibromide;dibromo(triphenyl)-;dibromotriphenyl-phosphoran;DIBROMO TRIPHENYL PHOSPHINE;TRIPHENYLPHOSPHINE DIBROMIDE;Triphenylphosphane dibromide;Phosphorane, dibromotriphenyl-
CBNumber:
CB1670688
Molecular Formula:
C18H15Br2P
Molecular Weight:
422.09
MDL Number:
MFCD00000054
MOL File:
1034-39-5.mol
MSDS File:
SDS
Last updated:2026-01-13 11:13:53
Product description Number Pack Size Price
Triphenylphosphine dibromide 96% 270946 5g $44.1
Triphenylphosphine dibromide 96% 270946 25g $163
Dibromotriphenylphosphorane, 98% 15-0990 10g $60
Dibromotriphenylphosphorane, 98% 15-0990 50g $231
Triphenylphosphine dibromide T889173 500mg $60
More product size

TRIPHENYLPHOSPHINE DIBROMIDE Properties

Melting point 235 °C (dec.) (lit.)
storage temp. Inert atmosphere,Room Temperature
form Crystalline Powder
color Light yellow to light pink
Water Solubility Soluble in water, dichloromethane, acetonitrile, phenyl cyanide, dimethyl formamide, ether, chloroform, alcohol, carbon tetrachloride, acetic acid and carbon disulfide. Sparingly soluble in phenyl chloride, triphenylphosphine and phenyl hydride. Insoluble in aqueous bromine.
Sensitive Moisture Sensitive
BRN 917652
InChI InChI=1S/C18H15Br2P/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChIKey OCXGTPDKNBIOTF-UHFFFAOYSA-N
SMILES P(Br)(Br)(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference 1034-39-5(CAS DataBase Reference)
FDA UNII 7Y0J6R63JD
EPA Substance Registry System Phosphorane, dibromotriphenyl- (1034-39-5)
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
3-10-21
TSCA  TSCA listed
HazardClass  8
PackingGroup  II
HS Code  29319019
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
0
3 0

TRIPHENYLPHOSPHINE DIBROMIDE price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 270946 Triphenylphosphine dibromide 96% 1034-39-5 5g $44.1 2026-03-19 Buy
Sigma-Aldrich 270946 Triphenylphosphine dibromide 96% 1034-39-5 25g $163 2026-03-19 Buy
Strem Chemicals 15-0990 Dibromotriphenylphosphorane, 98% 1034-39-5 10g $60 2024-03-01 Buy
Strem Chemicals 15-0990 Dibromotriphenylphosphorane, 98% 1034-39-5 50g $231 2024-03-01 Buy
TRC T889173 Triphenylphosphine dibromide 1034-39-5 500mg $60 2021-12-16 Buy
Product number Packaging Price Buy
270946 5g $44.1 Buy
270946 25g $163 Buy
15-0990 10g $60 Buy
15-0990 50g $231 Buy
T889173 500mg $60 Buy

TRIPHENYLPHOSPHINE DIBROMIDE Chemical Properties,Uses,Production

Chemical Properties

light yellow to light pink crystalline powder

Uses

Triphenylphosphine dibromide is used as a reagent for conversion of aldoximes into nitriles. It acts as a reagent for cleavage of acetals. It reacts with amines to give iminophosphoranes. Further, it serves as a reagent in the preparation of alkyl and aryl bromides from alcohols and phenols without rearrangement.

Purification Methods

It recrystallises from MeCN/Et2O. Although it has been recrystallised from EtOH, this is not recommended as it converts alcohols to alkyl bromides. It deteriorates on keeping, and it is best to prepare it afresh. [Anderson & Freenor J Am Chem Soc 86 5037 1964, Horner et al. Justus Liebigs Ann Chem 626 26 1959, Beilstein 16 III 864.]

791-28-6
1034-39-5
Synthesis of TRIPHENYLPHOSPHINE DIBROMIDE from Triphenylphosphine oxide

TRIPHENYLPHOSPHINE DIBROMIDE Preparation Products And Raw materials

Global( 195)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Kaitian Chemical Co., LTD
+86-13337816511 +86-13337835376 kt_chem@126.com China 91 58
Hebei Yanxi Chemical Co., Ltd.
+8618531123677 faithe@yan-xi.com China 5853 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-86-13131129325 +8613131129325 sales1@chuanghaibio.com China 5235 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21592 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29821 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49977 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81139210 +86-18192627656 1059@dideu.com China 3590 58
Neostar United (Changzhou) Industrial Co., Ltd.
+86-0519-85551759 +8613506123987 marketing1@neostarunited.com China 8828 58
SIMAGCHEM CORP
+86-5922680277 +86-13806087780 sale@simagchem.com China 17346 58

View Lastest Price from TRIPHENYLPHOSPHINE DIBROMIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TRIPHENYLPHOSPHINE DIBROMIDE pictures 2026-03-30 TRIPHENYLPHOSPHINE DIBROMIDE
1034-39-5
US $0.00-0.00 / KG 1KG 98% 2000 Shenzhen Nexcon Pharmatechs Ltd.
Dibromotriphenylphosphorane   pictures 2025-12-12 Dibromotriphenylphosphorane
1034-39-5
US $1.00-0.00 / KG 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd
TRIPHENYLPHOSPHINE DIBROMIDE pictures 2025-09-16 TRIPHENYLPHOSPHINE DIBROMIDE
1034-39-5
US $0.00-0.00 / kg 1kg 98% 10 tons Nanjing Kaitian Chemical Co., LTD
TRIPHENYLPHOSPHINE DIBROMIDE DIBROMO TRIPHENYL PHOSPHINE BROMOTRIPHENYLPHOSPHONIUM BROMIDE dibromotriphenyl-phosphoran phosphine dibromide Dibromotriphenylphosphorane,98% Phosphorane, dibromotriphenyl- Bromotriphenylphosphonium bromide, Dibromotriphenylphosphorane Triphenyldibromophosphorane dibroMotriphenyl-$l^{5}-phosphane Triphenylphosphine dibroMide 96% Triphenylphosphine dibromide, ca. 33% bromine Triphenylphosphine dibromide, tech. 90% Triphenylphosphine dibromide,Bromotriphenylphosphonium bromide, Dibromotriphenylphosphorane Triphenylphosphine dibromide, 95%, for synthesis SKL183 Triphenylphosphonium Dibromide pure, 98% dibromo(triphenyl)- Triphenylphosphane dibromide DIBROMOTRIPHENYLPHOSPHORANE 1034-39-5 C6H53PBr2 C18H15BrP C18H15Br2P Bromination Synthetic Reagents C-X Bond Formation (Halogen) organophosphorus compound 1