3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE
- CAS No.
- 259807-97-1
- Chemical Name:
- 3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE
- Synonyms
- SKL969;3-methyl-2-(tributyltin) pyridine;2-(Tributylstannyl)-3-Methylpyridine;3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE;tributyl-(3-methyl-2-pyridyl)stannane;Pyridine, 3-methyl-2-(tributylstannyl)-;tributyl-(3-methylpyridin-2-yl)stannane;3-Methyl-2-(tributylstannyl)pyridine 97%;3-Methyl-2-(tri-n-butylstannyl)pyridine,96%;3-Methyl-2-(tri-n-butylstannyl)pyridine, 96%
- CBNumber:
- CB1674969
- Molecular Formula:
- C18H33NSn
- Molecular Weight:
- 382.17
- MDL Number:
- MFCD07787404
- MOL File:
- Mol file
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 3-Methyl-2-(tributylstannyl)pyridine 97% | OR15616 | 1g | $305 |
| 3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE 95.00% | OGM0000006 | 250MG | $513.5 |
| 3-Methyl-2-(tributylstannyl)pyridine 97% | OR15616 | 250mg | $167 |
| 3-Methyl-2-(tributylstannyl)pyridine | 9H50-1-Y8 | 250mg | $175 |
| 3-Methyl-2-(tributylstannyl)pyridine 96% | 069510 | 500mg | $175 |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
|---|---|
| Appearance | Colorless to light yellow Liquid |
| Water Solubility | Sparingly soluble in water. |
| CAS DataBase Reference | 259807-97-1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
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|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H312-H315-H319-H372-H400-H410 | |||||||||
| Precautionary statements | P273-P280-P309-P310-P501a | |||||||||
| Hazard Codes | T | |||||||||
| HazardClass | 6.1 | |||||||||
| HS Code | 2933399990 | |||||||||
| NFPA 704 |
|
3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE price More Price(16)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR15616 | 3-Methyl-2-(tributylstannyl)pyridine 97% | 259807-97-1 | 1g | $305 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | OGM0000006 | 3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE 95.00% | 259807-97-1 | 250MG | $513.5 | 2021-12-16 | Buy |
| Apolloscientific | OR15616 | 3-Methyl-2-(tributylstannyl)pyridine 97% | 259807-97-1 | 250mg | $167 | 2021-12-16 | Buy |
| SynQuest Laboratories | 9H50-1-Y8 | 3-Methyl-2-(tributylstannyl)pyridine | 259807-97-1 | 250mg | $175 | 2021-12-16 | Buy |
| Matrix Scientific | 069510 | 3-Methyl-2-(tributylstannyl)pyridine 96% | 259807-97-1 | 500mg | $175 | 2021-12-16 | Buy |
3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE Chemical Properties,Uses,Production
Uses
3-Methyl-2-(tri-n-butylstannyl)pyridine is used as pharmaceutical intermediate.
Synthesis
1461-22-9
259807-97-1
The general procedure for synthesizing 3-methyl-2-(tributyltin)pyridine from tributyltin chloride was as follows: with reference to Example 195, 2-bromo-3-methylpyridine (1.0 g) was dissolved in tetrahydrofuran (10 mL) and cooled to -70°C. At this temperature, a hexane solution of 1.6 mol/L n-butyllithium (4.0 mL) was slowly added dropwise. After keeping the reaction at -70°C and stirring for 15 minutes, tributyltin chloride (2.2 g) was slowly added. Stirring was continued at the same temperature for 1 hour. After completion of the reaction, water was added to the reaction mixture and extracted with ethyl acetate. The organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate and concentrated under reduced pressure to remove the solvent. The resulting crude product was purified by silica gel column chromatography with hexane-ethyl acetate (19:1, v/v) as eluent to afford the target compound 3-methyl-2-(tributylstannyl)pyridine (1.75 g, 79% yield) in colorless oily form. The structure of the product was confirmed by 1H-NMR (CDCl3), δ: 0.85-0.95 (9H, m), 1.11-1.17 (6H, m), 1.29-1.37 (6H, m), 1.49-1.57 (6H, m), 2.36 (3H, s), 6.99-7.03 (1H, m), 7.31-7.34 (1H, m). 8.52-8.54 (1H, m).
References
[1] Patent: US2007/60623, 2007, A1. Location in patent: Page/Page column 52
3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29795 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Suzhou ARTK Medchem Co., Ltd. | +86-512-68323658 +86-18168183658 | sales1@artkmedchem.com | China | 39002 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39927 | 58 |
| Chongqing jooe co., ltd | +undefined86-15223382610 | info@jooe.com | China | 15976 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532; 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30123 | 84 |
| Chang Zhou Chemistar Chemistry Technology Co.,Ltd | +86 (519) 8689-6136 | kr@krchemistar.com | China | 181 | 55 |
| BeiJing Hwrk Chemicals Limted | 0757-86329057 18934348241 | sales4.gd@hwrkchemical.com | China | 14063 | 55 |
View Lastest Price from 3-METHYL-2-(TRIBUTYLSTANNYL)PYRIDINE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-03-08 | 3-Methyl-2-(tributylstannyl)pyridine
259807-97-1
|
US $10.00-100.00 / KG | 1KG | Min98% HPLC | g/kg/ton | Career Henan Chemical Co |
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- 3-Methyl-2-(tributylstannyl)pyridine
259807-97-1
- US $10.00-100.00 / KG
- Min98% HPLC
- Career Henan Chemical Co
