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Ethyl N-(diphenylmethylene)glycinate

CAS No.
69555-14-2
Chemical Name:
Ethyl N-(diphenylmethylene)glycinate
Synonyms
ethyl 2-[(diphenylMethylidene)aMino]acetate;ETHYL (DIPHENYLMETHYLENAMINO)ACETATE;N-(DIPHENYLMETHYLENE)GLYCINE ETHYL ESTER;(N,N-DIPHENYLMETHYLENE)GLYCINE ETHYL ESTER;NSC 263808;DPM-Gly-Oet;N-(DiphenyL;AURORA KA-6707;Ethyl N-(diphenylmet;N-Benzhydrylideneglycine ethyl
CBNumber:
CB1720354
Molecular Formula:
C17H17NO2
Molecular Weight:
267.32
MDL Number:
MFCD00010590
MOL File:
69555-14-2.mol
MSDS File:
SDS
Last updated:2025-07-24 18:12:19

Ethyl N-(diphenylmethylene)glycinate Properties

Melting point 51-53 °C(lit.)
Boiling point 195°C/2mmHg(lit.)
Density 1.0690 (rough estimate)
refractive index 1.5400 (estimate)
Flash point >110°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
pka 2.22±0.50(Predicted)
form Crystalline Powder or Crystals
color White to light yellow
λmax 247nm(Hexane)(lit.)
Sensitive Moisture Sensitive
BRN 1979922
Stability Moisture Sensitive
InChIKey QUGJYNGNUBHTNS-UHFFFAOYSA-N
LogP 1.35-3.18 at 25℃ and pH0-14
Dissociation constant 2.3 at 25℃
CAS DataBase Reference 69555-14-2(CAS DataBase Reference)
UNSPSC Code 12171500
NACRES NA.47

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS08
Signal word  Danger
Hazard statements  H350
Precautionary statements  P201-P202-P280-P308+P313-P405-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36/37-26
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
10-21
HS Code  29224999
NFPA 704
1
1 0

Ethyl N-(diphenylmethylene)glycinate price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 222542 N-(Diphenylmethylene)glycine ethyl ester 98% 69555-14-2 5g $130.15 2025-07-31 Buy
Sigma-Aldrich 222542 N-(Diphenylmethylene)glycine ethyl ester 98% 69555-14-2 25g $372.9 2025-07-31 Buy
TCI Chemical D3833 N-(Diphenylmethylene)glycine Ethyl Ester >97.0%(T) 69555-14-2 5g $40 2025-07-31 Buy
TCI Chemical D3833 N-(Diphenylmethylene)glycine Ethyl Ester >97.0%(T) 69555-14-2 25g $163 2025-07-31 Buy
TRC D491635 N-(Diphenylmethylene)glycine Ethyl Ester 69555-14-2 1g $65 2021-12-16 Buy
Product number Packaging Price Buy
222542 5g $130.15 Buy
222542 25g $372.9 Buy
D3833 5g $40 Buy
D3833 25g $163 Buy
D491635 1g $65 Buy

Ethyl N-(diphenylmethylene)glycinate Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystalline powder or

Uses

N-(Diphenylmethylene)glycine Ethyl Ester is used as a reagent in the synthesis of pyrazolopyrrolyl tetrahydropyran DPP-4 inhibitors.

Synthesis

Ethyl N-(diphenylmethylene)glycinate is prepared by transimination of Benzophenone Imine with alkyl glycinate hydrochloride (room temperature/CH2Cl2).

References

[1] Patent: EP1422220, 2004, A1. Location in patent: Page 5
[2] Patent: CN104557684, 2017, B. Location in patent: Paragraph 0021-0026; 0027; 0028; 0029; 0030-0033
[3] Tetrahedron Letters, 2005, vol. 46, # 16, p. 2795 - 2797
[4] Patent: US2010/173777, 2010, A1. Location in patent: Page/Page column 23
[5] Patent: WO2016/27285, 2016, A2. Location in patent: Page/Page column 50; 51

Global( 409)Suppliers
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Suzhou Highfine Biotech Co.,Ltd.
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View Lastest Price from Ethyl N-(diphenylmethylene)glycinate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethyl N-(diphenylmethylene)glycinate pictures 2025-06-27 Ethyl N-(diphenylmethylene)glycinate
69555-14-2
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
Ethyl N-(diphenylmethylene)glycinate pictures 2025-06-20 Ethyl N-(diphenylmethylene)glycinate
69555-14-2
US $20.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
Ethyl N-(diphenylmethylene)glycinate pictures 2025-04-04 Ethyl N-(diphenylmethylene)glycinate
69555-14-2
US $0.00-0.00 / KG 1KG 98% 1ton Henan Aochuang Chemical Co.,Ltd.
(N,N-DIPHENYLMETHYLENE)GLYCINE ETHYL ESTER N-(DIPHENYLMETHYLENE)GLYCINE ETHYL ESTER ETHYL N-(DIPHENYLMETHYLENE)GLYCINATE ETHYL (N-DIPHENYMETHYLENE)GLYCINATE ETHYL (DIPHENYLMETHYLENAMINO)ACETATE DIPHENYLMETHYLENE-GLYCINE ETHYL ESTER AURORA KA-6707 Ethyl N-benzhydrylideneglycinate N-(DIPHENYLMETHYLENE)GLYCINE ETHYL ESTER ,98% N-(DIPHENYLMETHYLENE)GLYCINE ETHYL ESTE& Ethyl N-(diphenylmethylene)glyciate N-(DIPHENYLMETHYLENE)GLYCINE ETHER ESTER ETHYL2-(DIPHENYLMETHYLENEAMINO)ACETATE Ethyl (diphenylmethyleneamino)acetate [(Diphenylmethylene)amino]acetic acid ethyl ester Benzhydrylideneaminoacetic acid ethyl ester N-(α-Phenylbenzylidene)glycine ethyl ester N-Benzhydrylideneglycine ethyl Ethyl N-(diphenylmethylene)glycinate,98% Ethyl N-(diphenylmet N-(Diphenylmethylene)glycine ethyl ester, [(Benzhydrylidene)amino]acetic acid ethyl ester DPM-Gly-OEt DiphenylMethylene-Glycine Ethyl esert Diphenylmethylene-GlycineEthylesert N-(Diphenylmethylene)glycine ethyl ester (Ethyl (diphenylmethylenamino) acetate) Ethyl N-(diphenylMethylene)glycinate, 98% 5GR Ethyl (benzhydrylideneaMino)acetate NSC 263808 Diphenyl Methyl glycine ethyl ester N-(Diphenylmethylene)glycine ethyl ester ethyl 2-[(diphenylMethylidene)aMino]acetate DPM-Gly-Oet Ethyl N-(diphenylmethylene)glycite ethyleN-(diphenylmethylene)glycinate N-(Diphenylmethylene)glycineEthylEster> N-(DiphenyL Glycine, N-(diphenylmethylene)-, ethyl ester Ethyl N-(diphenylmethylene)glycinate USP/EP/BP Ethyl 2-(benzhydrylideneamino)acetate TIANFUCHEM--69555-14-2--Ethyl N-(diphenylmethylene)glycinate factory price N-(Diphenylmethylene)glycine ethyl ester?New ethyl N-(diphenylmethylidene)glycinate Ethyl(diphenylmethylene)glycinate 69555-14-2 C6H52CNCH2CO2C2H5 Amino Acid Derivatives Peptide Synthesis Specialty Synthesis Triazoles Intermediates Miscellaneous Amino Acids