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2-Bromopropane

CAS No.
75-26-3
Chemical Name:
2-Bromopropane
Synonyms
ISOPROPYL BROMIDE;2-Brompropan;iso-C3H7Br;2-BROMOPROPANE;2-bromo-propan;bromo-2propane;propane,2-bromo-;bromo isopropane;PropylBromide~98%;sec-propylbromide
CBNumber:
CB1854219
Molecular Formula:
C3H7Br
Molecular Weight:
122.99
MDL Number:
MFCD00000147
MOL File:
75-26-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-10 10:27:06
Product description Number Pack Size Price
2-Bromopropane 99% B78114 100g $33.7
2-Bromopropane 99% B78114 500g $101
2-Bromopropane for synthesis 8.01668 250ML $46.5
2-Bromopropane for synthesis 8.01668 1L $131
2-Bromopropane >99.0%(GC) B0639 25g $28
More product size

2-Bromopropane Properties

Melting point -89 °C (lit.)
Boiling point 59 °C (lit.)
Density 1.31 g/mL at 25 °C (lit.)
vapor pressure 224 hPa (20 °C)
refractive index n20/D 1.425(lit.)
Flash point 67 °F
storage temp. Store below +30°C.
solubility 3.18g/l
form Liquid
color Clear colorless to very light brown
explosive limit 4.6%(V)
Water Solubility 0.3 g/100 mL
Merck 14,5210
BRN 741852
Henry's Law Constant 9.0×10-4 mol/(m3Pa) at 25℃, Brockbank (2013)
Dielectric constant 9.4600000000000009
Stability Stable. Flammable. Incompatible with strong oxidizing agents.
InChI 1S/C3H7Br/c1-3(2)4/h3H,1-2H3
InChIKey NAMYKGVDVNBCFQ-UHFFFAOYSA-N
SMILES CC(C)Br
CAS DataBase Reference 75-26-3(CAS DataBase Reference)
EWG's Food Scores 6
FDA UNII R651XOV97Z
NIST Chemistry Reference Propane, 2-bromo-(75-26-3)
Proposition 65 List 2-Bromopropane (2-BP)
EPA Substance Registry System Propane, 2-bromo- (75-26-3)
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS08
Signal word  Danger
Hazard statements  H225-H360F-H373
Precautionary statements  P201-P210-P308+P313
PPE Eyeshields, Faceshields, Gloves
Hazard Codes  F,T
Risk Statements  60-11-48/20-66
Safety Statements  53-16-45
RIDADR  UN 2344 3/PG 2
WGK Germany  1
RTECS  TX4111000
TSCA  TSCA listed
HazardClass  3
PackingGroup  II
HS Code  29033036
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 2
Repr. 1A
STOT RE 2 Inhalation
Hazardous Substances Data 75-26-3(Hazardous Substances Data)
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
2 0

2-Bromopropane price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B78114 2-Bromopropane 99% 75-26-3 100g $33.7 2026-03-19 Buy
Sigma-Aldrich B78114 2-Bromopropane 99% 75-26-3 500g $101 2026-03-19 Buy
Sigma-Aldrich 8.01668 2-Bromopropane for synthesis 75-26-3 250ML $46.5 2026-03-19 Buy
Sigma-Aldrich 8.01668 2-Bromopropane for synthesis 75-26-3 1L $131 2026-03-19 Buy
TCI Chemical B0639 2-Bromopropane >99.0%(GC) 75-26-3 25g $28 2026-03-19 Buy
Product number Packaging Price Buy
B78114 100g $33.7 Buy
B78114 500g $101 Buy
8.01668 250ML $46.5 Buy
8.01668 1L $131 Buy
B0639 25g $28 Buy

2-Bromopropane Chemical Properties,Uses,Production

Description

2-Bromopropane, also known as isopropyl bromide and 2-propyl bromide, is the halogenated hydrocarbon with the formula CH3CHBrCH3. It is a colorless liquid. It is used for introducing the isopropyl functional group in organic synthesis. 2-Bromopropane is prepared by heating isopropanol with hydrobromic acid.

Chemical Properties

colourless liquid

Uses

2-Bromopropane is a general reagent used to introduce isopropyl group as in the case of the synthesis of various Buchwald ligands. It can also be used as a starting material in the total synthesis of lamellarin D, lamellarin H, ningalin B and (±)-dichroanal. It is sometimes used as an alternative to ozone-depleting cleaning solvents such as chlorofluorocarbons.

Uses

2-Bromopropane serves as an alkylating agent in organic synthesis. It is also used as an intermediate to form alkylated amines and alkylated metallic compounds. Further, it acts as a solvent for industrial cleaning, degreasing, metal processing and finishing, electronics, aerospace and aviation, aerosols, textiles, adhesives and inks. In addition, it is used for introducing the isopropyl functional group in organic synthesis.

Preparation

2-Bromopropane is commercially available. It may be prepared in the ordinary manner of alkyl bromides, by reacting isopropanol with phosphorus and bromine, or with phosphorus tribromide.

Health Hazard

2-bromopropane, apparently caused ovarian failure, azoospermia, oligospermia, and anemia in a group of Korean workers. Experimental studies confirm specific reproductive effects in females and males. Hematopoietic effects and peripheral neuropathy also have been reported in animal studies. There is limited evidence of adverse effects in exposed workers similar to those seen in animals.

Safety Profile

Moderately toxic by intraperitoneal route. A very flammable liquid and dangerous fire hazard. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.

Purification Methods

Wash the bromide with 95% H2SO4 (concentrated acid partially oxidised it) until a fresh portion of acid did not become coloured after several hours, then with water, aqueous NaHSO3, aqueous 10% Na2CO3 and again with water. (The H2SO4 can be replaced by conc HCl.) Prior to this treatment, isopropyl bromide has been purified by bubbling a stream of oxygen containing 5% ozone through it for 1hour, followed by shaking with 3% hydrogen peroxide solution, neutralising with aqueous Na2CO3, washing with distilled water and drying. Alternatively, it has been treated with elemental bromine and stored for 4 weeks, then extracted with aqueous NaHSO3 and dried with MgSO4. After the acid treatment, isopropyl bromide can be dried with Na2SO4, MgSO4 or CaH2, and fractionally distilled. [Beilstein 1 IV 208.]

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View Lastest Price from 2-Bromopropane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromopropane pictures 2026-04-25 2-Bromopropane
75-26-3
US $0.00 / KG 1KG ≥99% 60 Tons/Month Yancheng Longshen Chemical Co.,Ltd.
2-Bromopropane pictures 2026-03-20 2-Bromopropane
75-26-3
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
2-Bromopropane pictures 2025-09-25 2-Bromopropane
75-26-3
US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • 2-Bromopropane pictures
  • 2-Bromopropane
    75-26-3
  • US $0.00 / KG
  • ≥99%
  • Yancheng Longshen Chemical Co.,Ltd.
  • 2-Bromopropane pictures
  • 2-Bromopropane
    75-26-3
  • US $0.00-0.00 / KG
  • 99%
  • Hebei Chuanghai Biotechnology Co., Ltd
  • 2-Bromopropane pictures
  • 2-Bromopropane
    75-26-3
  • US $50.00-1.00 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
2-BROMOPROPANE Iso-propyl bromide(2-bromopropane) 2-BROMOPROPANE, STANDARD FOR GC 2-BROMOPROPANE, 99+% PropylBromide~98% 2-BromopropaneForSynthesis 2-Bromopropane, 98+% ISOPROPYL BROMIDE pure 2-BROMOPROPANE FOR SYNTHESIS 1 L 2-BROMOPROPANE FOR SYNTHESIS 250 ML 2-BroMopropane, 99% 250ML 2 - broMine propane 2-bromo-propan 2-Brompropan bromo-2propane iso-C3H7Br propane,2-bromo- sec-Propyl bromide sec-propylbromide 2-bromopropane radical cation 2-BROMOPROPANE, 99%2-BROMOPROPANE, 99%2-BROMOPROPANE, 99%2-BROMOPROPANE, 99% 2-BROMOPROPANE2-BROMOPROPANE2-BROMOPROPANE2-BROMOPROPANE Olaparib Impurity 5 (2-Bromopropane) TAK438 Impurity 82 2-Bromopropane > 2-bromo-2-[14C1]-propane Isopropyl Bromide (Stab w/ Ag) pure, 99% bromo isopropane Bromodiisopropyl alcohol ISOPROPYL BROMIDE 75-26-3 75-26-6 CH32CHBr 75263 HALOGEN Alphabetic Alkyl Analytical Chromatography Product Catalog Building Blocks Analytical Standards BI - BZ Halogenated Hydrocarbons Organic Building Blocks Organics fine chemicals 75-26-3