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DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)

CAS No.
52611-08-2
Chemical Name:
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
Synonyms
Nsc148042;Bis(methyldiphenylphosphin;Palladium,dichlorobis(methyldiphenylphosphine)-;DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II);BIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;Bis(methyldiphenylphosphine)palladium(II) Dichloride >Dichlorobis[methylene-bis(diphenylphosphine)]dipalladium(II);Bis(methyldiphenylphosphine)palladium(II) Dichloride (cis- and trans- mixture)
CBNumber:
CB2126788
Molecular Formula:
C26H26Cl2P2Pd
Molecular Weight:
577.76
MDL Number:
MFCD00216594
MOL File:
52611-08-2.mol
MSDS File:
SDS
Last updated:2026-05-27 23:54:49
Product description Number Pack Size Price
Dichlorobis(methyldiphenylphosphine)palladium(II) 97% 431885 1g $112
Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) B2161 1g $142
Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) B2161 5g $435
Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported 267174 500mg $312
Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported 267174 1g $429
More product size

DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Properties

Melting point >120*C (dec.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heat
form Solid
color Light Yellow to Yellow
InChI 1S/2C13H13P.2ClH.Pd/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;;;/h2*2-11H,1H3;2*1H;/q;;;;+2/p-2
InChIKey GTSFBKGHQLDFHU-UHFFFAOYSA-L
SMILES Cl[Pd]Cl.CP(c1ccccc1)c2ccccc2.CP(c3ccccc3)c4ccccc4
UNSPSC Code 12352300
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  2931.90.6000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 431885 Dichlorobis(methyldiphenylphosphine)palladium(II) 97% 52611-08-2 1g $112 2023-06-20 Buy
TCI Chemical B2161 Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) 52611-08-2 1g $142 2026-04-30 Buy
TCI Chemical B2161 Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) 52611-08-2 5g $435 2023-06-20 Buy
Usbiological 267174 Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported 52611-08-2 500mg $312 2026-06-03 Buy
Usbiological 267174 Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported 52611-08-2 1g $429 2026-06-03 Buy
Product number Packaging Price Buy
431885 1g $112 Buy
B2161 1g $142 Buy
B2161 5g $435 Buy
267174 500mg $312 Buy
267174 1g $429 Buy

DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Chemical Properties,Uses,Production

Uses

Catalyst for:

  • Ullmann reactions (homocoupling reactions)
  • Cross coupling reaction of tributyltin hydride with aryl iodides
  • Double silylation, double carbonylation and cyclocarbonylation reactions

Application

Dichlorobis(methyldiphenylphosphine)palladium(II) is a catalyst for the dicarbonylation of aryl halides with amines.

Preparation

Dichlorobis(methyldiphenylphosphine)palladium(II) is prepared by treating commercially available K2PdCl2 (in DMF) with methyldiphenylphosphine (in CH2Cl2), or  from K2PdCl2 (in H2O) and methyldiphenylphosphine (in CH2Cl2) using Bu4NCl (in CH2Cl2) as a phase-transfer catalyst.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 66)Suppliers
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ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
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Aladdin Scientific
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DAYANG CHEM (HANGZHOU) CO.,LTD
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View Lastest Price from DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Palladium,dichlorobis(methyldiphenylphosphine)- pictures 2026-04-17 Palladium,dichlorobis(methyldiphenylphosphine)-
52611-08-2
$2.00-5.00 99% ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Dichlorobis(methyldiphenylphosphine)palladium(II) pictures 2020-11-16 Dichlorobis(methyldiphenylphosphine)palladium(II)
52611-08-2
$20.00 1KG 99% 10000KG Longyan Tianhua Biological Technology Co., Ltd
Nsc148042 Dichlorobis[methylene-bis(diphenylphosphine)]dipalladium(II) Bis(methyldiphenylphosphine)palladium(II) Dichloride (cis- and trans- mixture) Bis(methyldiphenylphosphin BIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Bis(methyldiphenylphosphine)palladium(II) Dichloride > Palladium,dichlorobis(methyldiphenylphosphine)- 52611-08-2 C6H52PCH32PdCl2 C26H26Cl2P2Pd C26H28Cl2P2Pd 2C13H13PCl2Pd Homogeneous Pd Catalysts Pd (Palladium) Compounds Transition Metal Compounds Metal Complexes Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Catalysis and Inorganic Chemistry Catalysis and Inorganic Chemistry Homogeneous Pd Catalysts Palladium Synthetic Organic Chemistry Transition Metal Compounds Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes Pd (Palladium) Compounds