DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
- CAS No.
- 52611-08-2
- Chemical Name:
- DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II)
- Synonyms
- Nsc148042;Bis(methyldiphenylphosphin;Palladium,dichlorobis(methyldiphenylphosphine)-;DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II);BIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) DICHLORIDE;Bis(methyldiphenylphosphine)palladium(II) Dichloride >Dichlorobis[methylene-bis(diphenylphosphine)]dipalladium(II);Bis(methyldiphenylphosphine)palladium(II) Dichloride (cis- and trans- mixture)
- CBNumber:
- CB2126788
- Molecular Formula:
- C26H26Cl2P2Pd
- Molecular Weight:
- 577.76
- MDL Number:
- MFCD00216594
- MOL File:
- 52611-08-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Dichlorobis(methyldiphenylphosphine)palladium(II) 97% | 431885 | 1g | $112 |
| Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) | B2161 | 1g | $142 |
| Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) | B2161 | 5g | $435 |
| Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported | 267174 | 500mg | $312 |
| Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported | 267174 | 1g | $429 |
| More product size | |||
| Melting point | >120*C (dec.) |
|---|---|
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Chloroform (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heat |
| form | Solid |
| color | Light Yellow to Yellow |
| InChI | 1S/2C13H13P.2ClH.Pd/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;;;/h2*2-11H,1H3;2*1H;/q;;;;+2/p-2 |
| InChIKey | GTSFBKGHQLDFHU-UHFFFAOYSA-L |
| SMILES | Cl[Pd]Cl.CP(c1ccccc1)c2ccccc2.CP(c3ccccc3)c4ccccc4 |
| UNSPSC Code | 12352300 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 |
| target organs | Respiratory system |
| PPE | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| HS Code | 2931.90.6000 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) price More Price(41)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 431885 | Dichlorobis(methyldiphenylphosphine)palladium(II) 97% | 52611-08-2 | 1g | $112 | 2023-06-20 | Buy |
| TCI Chemical | B2161 | Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) | 52611-08-2 | 1g | $142 | 2026-04-30 | Buy |
| TCI Chemical | B2161 | Bis(methyldiphenylphosphine)palladium(II) Dichloride >96.0%(T) | 52611-08-2 | 5g | $435 | 2023-06-20 | Buy |
| Usbiological | 267174 | Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported | 52611-08-2 | 500mg | $312 | 2026-06-03 | Buy |
| Usbiological | 267174 | Bis(methyldiphenylphosphine)palladium(II) Dichloride Asreported | 52611-08-2 | 1g | $429 | 2026-06-03 | Buy |
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Chemical Properties,Uses,Production
Uses
Catalyst for:
- Ullmann reactions (homocoupling reactions)
- Cross coupling reaction of tributyltin hydride with aryl iodides
- Double silylation, double carbonylation and cyclocarbonylation reactions
Application
Dichlorobis(methyldiphenylphosphine)palladium(II) is a catalyst for the dicarbonylation of aryl halides with amines.
Preparation
Dichlorobis(methyldiphenylphosphine)palladium(II) is prepared by treating commercially available K2PdCl2 (in DMF) with methyldiphenylphosphine (in CH2Cl2), or from K2PdCl2 (in H2O) and methyldiphenylphosphine (in CH2Cl2) using Bu4NCl (in CH2Cl2) as a phase-transfer catalyst.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-13017695106 +86-13676922317 | jiuyitime@fdachem.com | China | 16512 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5742 | 58 |
| Longyan Tianhua Biological Technology Co., Ltd | 0086 18039857276 18039857276 | CHINA | 2783 | 58 | |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30225 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 43333 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53803 | 58 |
View Lastest Price from DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-04-17 | Palladium,dichlorobis(methyldiphenylphosphine)-
52611-08-2
|
$2.00-5.00 | 99% | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |||
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2020-11-16 | Dichlorobis(methyldiphenylphosphine)palladium(II)
52611-08-2
|
$20.00 | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd |
-

- Palladium,dichlorobis(methyldiphenylphosphine)-
52611-08-2
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-

- Dichlorobis(methyldiphenylphosphine)palladium(II)
52611-08-2
- $20.00
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
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