ChemicalBook >> CAS DataBase List >>9,9-Dimethylfluorene

9,9-Dimethylfluorene

CAS No.
4569-45-3
Chemical Name:
9,9-Dimethylfluorene
Synonyms
9,9-DIMETHYLFLUORENE;9H-Fluorene, 9,9-dimethyl-;9,9-Dimethyl-9H-fluo;9,9'-Dimethylfluorenee;9,9- two Methylfluorene;9,9-dimethyl-fluororene;9,9-Dimethylfluorene>9,9-Dimethyl-9H-fluoren;9,9-Dimethyl-9H-fluorene;9,9-DiMethyl-9H-fluoreneV
CBNumber:
CB2146845
Molecular Formula:
C15H14
Molecular Weight:
194.27
MDL Number:
MFCD00114670
MOL File:
4569-45-3.mol
MSDS File:
SDS
Last updated:2026-01-13 11:14:08
Product description Number Pack Size Price
9,9-Dimethylfluorene >98.0%(GC) D3235 1g $67
9,9-Dimethylfluorene >98.0%(GC) D3235 5g $196
9,9-Dimethylfluorene (purified by sublimation) >99.0%(GC) D3810 1g $71
9,9-Dimethyl-9H-fluorene D477768 100mg $60
9,9-Dimethylfluorene (purified by sublimation) FD62946 2g $50
More product size

9,9-Dimethylfluorene Properties

Melting point 96°C
Boiling point 287 °C
Density 1.040±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color White to Almost white
λmax 301nm(EtOH)(lit.)
Major Application battery manufacturing
InChI InChI=1S/C15H14/c1-15(2)13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h3-10H,1-2H3
InChIKey ZHQNDEHZACHHTA-UHFFFAOYSA-N
SMILES C1(C)(C)C2=C(C=CC=C2)C2=C1C=CC=C2
CAS DataBase Reference 4569-45-3(CAS DataBase Reference)
FDA UNII RFQ75I78LQ
NIST Chemistry Reference 9H-Fluorene, 9,9-dimethyl-(4569-45-3)
UNSPSC Code 12352401
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Risk Statements  20/21/22-36/37/38
Safety Statements  26-37/39
WGK Germany  WGK 3
HS Code  2902.90.9000
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
Aquatic Chronic 2
NFPA 704
0
1 0

9,9-Dimethylfluorene price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D3235 9,9-Dimethylfluorene >98.0%(GC) 4569-45-3 1g $67 2026-04-30 Buy
TCI Chemical D3235 9,9-Dimethylfluorene >98.0%(GC) 4569-45-3 5g $196 2026-04-30 Buy
TCI Chemical D3810 9,9-Dimethylfluorene (purified by sublimation) >99.0%(GC) 4569-45-3 1g $71 2026-04-30 Buy
TRC D477768 9,9-Dimethyl-9H-fluorene 4569-45-3 100mg $60 2021-12-16 Buy
Biosynth Carbosynth FD62946 9,9-Dimethylfluorene (purified by sublimation) 4569-45-3 2g $50 2021-12-16 Buy
Product number Packaging Price Buy
D3235 1g $67 Buy
D3235 5g $196 Buy
D3810 1g $71 Buy
D477768 100mg $60 Buy
FD62946 2g $50 Buy

9,9-Dimethylfluorene Chemical Properties,Uses,Production

Uses

This product offered here allows an ambient-air-tolerant method for negative electrode prelithiation prior to assembly of Li ion batteries. The redox potential of this product makes it useful for those most reported negative electrodes including Si with high capacities and short processing time. It could not only compensate for the initial active lithium loss, but also enable the pairing with high-capacity lithium-free positive electrodes (e.g. sulfur, oxygen, V2O5 etc.) th at requires the supply of Li source from the negative electrode to configure Li ion batteries with high energy densities.
Recommended instructions (this should be a separate document):Soak your electrode with the anode material coated on a copper current collector in this prelithiation reagent for a set amount of time. Discard the solution and then wash your electrode twice with THF. For a 1cm diameter electrode with 1∼3 mg acitve material per cm2, use 0.5∼1 mL of prelithiation solution will be enough. You can use an empty coin cell casing as the treatment vessel. Electrode soaking time is important and may need to be optimized for your application. A good time to try is ∼10 min. Longer prelithiation time may cause eletrode structure deformation, leading to a decreased discharge/charge capacity.

Definition

9,9-Dimethylfluorene is an organic electroluminescent material intermediate. The fluorene derivative is a kind of organic electroluminescent material commercialized at present, wherein 9, 9-dimethyl fluorene is an essential intermediate for synthesizing OLED material.

Synthesis

The method comprises taking dimethyl carbonate as a methylating agent under alkaline substances and reacting with fluorene in an organic solvent system within a certain temperature range to prepare the 9,9-Dimethylfluorene. The method uses dimethyl carbonate as a methylating agent so that the reaction process is stabilized and the economy is greatly improved; meanwhile, the use of dimethyl carbonate avoids the use of low-boiling-point hypertoxic such as methyl iodide, methyl bromide, and the like, is environment-friendly, and the generated wastewater has single component and is convenient to treat.

9,9-Dimethylfluorene Preparation Products And Raw materials

Global( 242)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd
+8615350571055 Sibel@chuanghaibio.com China 8738 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20124 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-2158073036 info@dakenam.com China 13843 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21590 55
China Synchem Technology Co.,Ltd.
+86-0552-4929304 +86-18055277008 wangxuhui1985@126.com China 65 55
AB PharmaTech,LLC
323-480-4688 sales@acrospharmatech.com United States 989 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29819 58
SHAANXI WEISHINUO THE NEW MATERIALCO,.LTD
18792503214 Beryl@weishino.com CHINA 256 58
BAYNOE CHEM CO.,LTD
+86-21-34783353 +8615000719740 baynoe@baynoe.com CHINA 934 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58

View Lastest Price from 9,9-Dimethylfluorene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
9,9-Dimethyl-9H-fluorene pictures 2026-03-20 9,9-Dimethyl-9H-fluorene
4569-45-3
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
9,9-Dimethyl-9H-fluorene  pictures 2025-11-18 9,9-Dimethyl-9H-fluorene
4569-45-3
US $1.10 / g 1g 99.00% 100 Tons Dideu Industries Group Limited
9,9-Dimethylfluorene pictures 2025-09-25 9,9-Dimethylfluorene
4569-45-3
US $200.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • 9,9-Dimethylfluorene pictures
  • 9,9-Dimethylfluorene
    4569-45-3
  • US $200.00-1.00 / KG
  • 99%, 99.5% Sublimated
  • Henan Fengda Chemical Co., Ltd
9,9-DIMETHYLFLUORENE 9,9-Dimethyl-9H-fluorene 9,9-dimethyl-fluororene 9,9-Dimethylfluorene (purified by sublimation) 9,9'-Dimethylfluorenee 9,9-Dimethyl-9H-fluo 9,9-DiMethylfluorene, 9,9-DiMethyl-9H-fluorene 9,9- two Methylfluorene 9,9-DiMethyl-9H-fluoreneV 9H-Fluorene, 9,9-dimethyl- 9,9-Dimethyl-9H-fluoren 9,9-Dimethylfluorene(purifiedbysublimation)> 9,9-Dimethylfluorene> 9,9-Dimethyl-9H-fluorene ISO 9001:2015 REACH 1 M 9,9-dimethylfluorene in THF 4569-45-3 4669-45-3 4659-45-3 C15H14 Fluorenes Fluorenes & Fluorenones Halogenated Heterocycles ,Thiophenes ,Thiazolines/Thiazolidines Fluorene Series Fluorenes & Fluorenones Electronic Chemicals Fluorenes Fluorene Derivatives