methyl 4-(bromomethyl)-2-methoxybenzoate
- CAS No.
- 74733-27-0
- Chemical Name:
- methyl 4-(bromomethyl)-2-methoxybenzoate
- Synonyms
- )-2-methoxybenzoate;Oxirane, 2-[7-(phenylMethoxy)ethyl]-;methyl 4-(bromomethyl)-2-methoxybenzoate;Methyl 2-Methoxy-4-(bromomethyl)benzoate;4-broMoMethyl-2-Methoxy benzoic acid Methyl ester;2-Methoxy-4-(broMoMethyl)benzoic acid Methyl ester;Benzoic acid, 4-(bromomethyl)-2-methoxy-, methyl ester
- CBNumber:
- CB21561317
- Molecular Formula:
- C10H11BrO3
- Molecular Weight:
- 259.1
- MDL Number:
- MFCD11976783
- MOL File:
- 74733-27-0.mol
| Boiling point | 142-146 °C(Press: 1.8 Torr) |
|---|---|
| Density | 1.432±0.06 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| Appearance | White to off-white Solid |
| InChI | InChI=1S/C10H11BrO3/c1-13-9-5-7(6-11)3-4-8(9)10(12)14-2/h3-5H,6H2,1-2H3 |
| InChIKey | DCXFLSHDURQRML-UHFFFAOYSA-N |
| SMILES | C(OC)(=O)C1=CC=C(CBr)C=C1OC |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H332-H335 |
| Precautionary statements | P261-P280-P305+P351+P338 |
methyl 4-(bromomethyl)-2-methoxybenzoate price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M296535 | Methyl4-(Bromomethyl)-2-methoxybenzoate | 74733-27-0 | 50mg | $60 | 2021-12-16 | Buy |
| AK Scientific | W8234 | Methyl4-(bromomethyl)-2-methoxybenzoate | 74733-27-0 | 1g | $124 | 2021-12-16 | Buy |
| Matrix Scientific | 119176 | Methyl 4-(bromomethyl)-2-methoxybenzoate 95+% | 74733-27-0 | 1g | $143 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | HCH0048921 | METHYL 4-(BROMOMETHYL)-2-METHOXYBENZOATE 95.00% | 74733-27-0 | 1G | $195.3 | 2021-12-16 | Buy |
| Matrix Scientific | 119176 | Methyl 4-(bromomethyl)-2-methoxybenzoate 95+% | 74733-27-0 | 10g | $712 | 2021-12-16 | Buy |
methyl 4-(bromomethyl)-2-methoxybenzoate Chemical Properties,Uses,Production
Synthesis
81245-24-1
74733-27-0
General procedure for the synthesis of methyl 4-bromomethyl-2-methoxybenzoate from methyl 2-methoxy-4-methylbenzoate: over a period of 1.5 h, bromine (6.19 mL, 120 mmol) was slowly added dropwise over a period of 1.5 h to a reflux mixture of methyl 2-methoxy-4-methylbenzoate (21.625 g, 120 mmol) in carbon tetrachloride (240 mL) dissolved in a carbon tetrachloride (75 mL). During the dropwise addition, the reaction mixture was irradiated using a 250W tungsten lamp. After dropwise addition, the reaction was continued at reflux for 15 minutes. Upon completion of the reaction, the mixture was concentrated and the solvent was removed under vacuum to afford methyl 4-bromomethyl-2-methoxybenzoate as an oily product (29.864 g, 96% yield). The product was confirmed by NMR hydrogen spectrum (400 MHz, CDCl3): δ 2.40 (s, 3H), 3.87 (s, 3H), 3.91 (s, 3H), 4.44 (s, 2H). Mass spectrometry (FIA-MS) showed the molecular ion peak m/e: 259 ([M+1]+).
References
[1] Patent: WO2004/108677, 2004, A1. Location in patent: Page 199
[2] Synlett, 2014, vol. 25, # 17, p. 2485 - 2487
[3] Patent: US2009/209586, 2009, A1. Location in patent: Page/Page column 13
[4] Patent: KR2016/20674, 2016, A. Location in patent: Paragraph 0053; 0115; 0116
[5] Bulletin de la Societe Chimique de France, 1962, p. 2255 - 2261
methyl 4-(bromomethyl)-2-methoxybenzoate Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +8613336195806 | sales@capot.com | China | 29734 | 60 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29800 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14360 | 58 |
| Blocksynth Pharmaceutical Technology Co.,Ltd | 0086-19817745290; +8619817745290 | bd@blocksynth.com | China | 5661 | 58 |
| Hefei Hirisun Pharmatech Co., Ltd | +8615056975894 | shawn@hirisunpharm.com | CHINA | 9911 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
View Lastest Price from methyl 4-(bromomethyl)-2-methoxybenzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-12-04 | methyl 4-(bromomethyl)-2-methoxybenzoate
74733-27-0
|
US $0.00-0.00 / kg | 0.1kg | 98%+ | 100kg | Huida Pharmaceutical Technology (Shanghai) Co., Ltd. | |
 |
2023-12-04 | methyl 4-(bromomethyl)-2-methoxybenzoate
74733-27-0
|
US $0.00-0.00 / kg | 0.10000000149011612kg | 98% | 100kg | Huida Pharmaceutical Technology (Shanghai) Co., Ltd. | |
 |
2020-03-10 | methyl 4-(bromomethyl)-2-methoxybenzoate
74733-27-0
|
US $6.00 / KG | 1KG | 98% | 1kg, 10kg ,50kg | Career Henan Chemical Co |
-
- methyl 4-(bromomethyl)-2-methoxybenzoate
74733-27-0
- US $0.00-0.00 / kg
- 98%+
- Huida Pharmaceutical Technology (Shanghai) Co., Ltd.
-
- methyl 4-(bromomethyl)-2-methoxybenzoate
74733-27-0
- US $0.00-0.00 / kg
- 98%
- Huida Pharmaceutical Technology (Shanghai) Co., Ltd.
-
- methyl 4-(bromomethyl)-2-methoxybenzoate
74733-27-0
- US $6.00 / KG
- 98%
- Career Henan Chemical Co
