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2-Amino-4-chlorobenzaldehyde

2-Amino-4-chlorobenzaldehyde Structure
2-Amino-4-chlorobenzaldehyde structure
CAS No.
59236-37-2
Chemical Name:
2-Amino-4-chlorobenzaldehyde
Synonyms
2-Amino-4-chlorobenzaldehyde;Benzaldehyde, 2-amino-4-chloro-;Benzo[i]dipyrido[3,2-a:2',5'-c]phenazine
CBNumber:
CB22136347
Molecular Formula:
C7H6ClNO
Molecular Weight:
155.58
MDL Number:
MFCD10696881
MOL File:
59236-37-2.mol
MSDS File:
SDS
Last updated:2026-05-27 23:59:56
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2-Amino-4-chlorobenzaldehyde Properties

Boiling point 297.0±25.0 °C(Predicted)
Density 1.348±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka -0.70±0.10(Predicted)
Appearance Off-white to light yellow Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
HS Code  2922390090

2-Amino-4-chlorobenzaldehyde price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR927314 2-Amino-4-chlorobenzaldehyde 97% 59236-37-2 100mg $21 2026-06-04 Buy
Apolloscientific OR927314 2-Amino-4-chlorobenzaldehyde 97% 59236-37-2 250mg $25 2026-06-04 Buy
Apolloscientific OR927314 2-Amino-4-chlorobenzaldehyde 97% 59236-37-2 1g $30 2026-06-04 Buy
Apolloscientific OR927314 2-Amino-4-chlorobenzaldehyde 97% 59236-37-2 5g $130 2026-06-04 Buy
Activate Scientific AS110398 2-Amino-4-chlorobenzaldehyde 97% 59236-37-2 1g $42 2026-06-04 Buy
Product number Packaging Price Buy
OR927314 100mg $21 Buy
OR927314 250mg $25 Buy
OR927314 1g $30 Buy
OR927314 5g $130 Buy
AS110398 1g $42 Buy

2-Amino-4-chlorobenzaldehyde Chemical Properties, Uses, Production

Uses

2-Amino-4-chlorobenzaldehyde is a reagent used in the synthesis of pharmaceuticals such as robenidine analogues which are active against MRSA and VRE.

Synthesis

2-AMINO-4-CHLORO-BENZENEMETHANOL

37585-16-3

2-Amino-4-chlorobenzaldehyde

59236-37-2

General procedure for the synthesis of 2-amino-4-chlorobenzaldehyde from (2-amino-4-chlorophenyl)methanol: In a 2L three-necked round-bottomed flask, (2-amino-4-chlorophenyl)methanol (32 g, 203.82 mmol) was dissolved in dichloromethane (765 mL), and manganese dioxide (150 g, 1.724 mol) was slowly added under stirring. The reaction mixture was stirred continuously for 40 hours at room temperature and under argon protection. Upon completion of the reaction, the reaction mixture was filtered through a diatomaceous earth pad and the solid residue was washed well with dichloromethane (1000 mL). The filtrates were combined and concentrated under reduced pressure to give 2-amino-4-chlorobenzaldehyde as an orange solid. Yield: 24 g (76.2% yield).

References

[1] Bioorganic and Medicinal Chemistry, 2012, vol. 20, # 19, p. 5810 - 5831
[2] ChemistryOpen, 2015, vol. 4, # 2, p. 107 - 110
[3] Angewandte Chemie - International Edition, 2017, vol. 56, # 35, p. 10573 - 10576
[4] Angew. Chem., 2017, vol. 129, # 35, p. 10709 - 10712,4
[5] Synlett, 2017, vol. 28, # 14, p. 1724 - 1728

2-Amino-4-chlorobenzaldehyde Preparation Products And Raw materials

Raw materials

2-Amino-4-chloro-benzenemethanol 4-Chloro-2-nitrobenzaldehyde Iron Dichloromethane Manganese dioxide

Preparation Products

7-Chloro-2-Methylquinolin-3-aMine 7-chloro-1,2-dihydro-2-oxo-3-Quinolinecarboxylic acid 7-Chloro-2-quinolinecarboxylic acid

2-Amino-4-chlorobenzaldehyde Suppliers

Global Suppliers ( 57)
Supplier Tel Email Country ProdList Advantage
Shanghai Sunway Pharmaceutical Technology Co., Ltd 13761987713 hxzheng@sunwaypharm.cn China 8663 57
SuZhou ShiYa Biopharmaceuticals, Inc. 86(512)5235 8471 17715136450 sales@shiyabiopharm.com China 4167 58
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Hangzhou Milestone Pharmtech Co., Ltd. 0571-82896630 18969958410 sales_hz@milestonepharmtech.com China 4906 55
DebyeTec.com Inc. 18086626237 18086626237 2693528373@qq.com China 2936 56
Shanghai SuperLan Chemcial Technique Centre 0-2022843681 15618226720 chaolaichem@foxmail.com China 9996 58
Amadis Chemical Company Limited 571-89925085 sales@amadischem.com China 131885 58
Sichuan BoYou Biotechnology Co., Ltd. 028-65791793 18140026355 568470422@qq.com China 9961 58
Aikon International Limited 025-58859352 19370895928 sales01@aikonchem.com China 15078 58
Suzhou Nuoouman Biological Technology Co., Ltd. 15026866316 180642609@qq.com China 4966 58
Supplier Advantage
Shanghai Sunway Pharmaceutical Technology Co., Ltd 57
SuZhou ShiYa Biopharmaceuticals, Inc. 58
Bide Pharmatech Ltd. 60
Hangzhou Milestone Pharmtech Co., Ltd. 55
DebyeTec.com Inc. 56
Shanghai SuperLan Chemcial Technique Centre 58
Amadis Chemical Company Limited 58
Sichuan BoYou Biotechnology Co., Ltd. 58
Aikon International Limited 58
Suzhou Nuoouman Biological Technology Co., Ltd. 58

2-Amino-4-chlorobenzaldehyde Spectrum

2-Amino-4-chlorobenzaldehyde(59236-37-2)1HNMR

59236-37-2 (2-Amino-4-chlorobenzaldehyde) Related Search:

Ferrous sulfate Calcium phosphate monobasic o-Phthalaldehyde 2-Amino-4-chlorobenzonitrile 4-Chloro-2-nitrobenzaldehyde
2-Amino-4-chlorobenzoic acid

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2-Amino-4-chlorobenzaldehyde Benzaldehyde, 2-amino-4-chloro- Benzo[i]dipyrido[3,2-a:2',5'-c]phenazine 59236-37-2