4-Fluoronaphtalene-1-boronic acid
- CAS No.
- 182344-25-8
- Chemical Name:
- 4-Fluoronaphtalene-1-boronic acid
- Synonyms
- AKOS BRN-0210;CAS:182344-25-8;1-Borono-4-fluoronaphthalene;4-flunaphthene-1-boronic acid;(4-fluoro-1-naphthyl)boronicacid;4-FLUORONAPHTALENE-1-BORONIC ACID;4-FLUORONAPHTHALENE-1-BORONIC ACID;4-FLUORO-1-NAPHTHALENEBORONIC ACID;(4-fluoronaphthalen-1-yl)boronicaci;(4-fluoro-1-naphthalenyl)boronic acid
- CBNumber:
- CB2228372
- Molecular Formula:
- C10H8BFO2
- Molecular Weight:
- 189.98
- MDL Number:
- MFCD04039221
- MOL File:
- 182344-25-8.mol
| Product description | Number | Pack Size | Price |
| 4-Fluoro-1-naphthaleneboronic Acid (contains varying amounts of Anhydride) | F1080 | 200mg | $47 |
| 4-Fluoro-1-naphthaleneboronic Acid (contains varying amounts of Anhydride) | F1080 | 1g | $140 |
| 4-Fluoronaphthalene-1-boronicacid | F593853 | 500mg | $115 |
| 4-Fluoronaphthalene-1-boronicacid | F593853 | 1g | $160 |
| 4-Fluoronaphthalene-1-boronic acid 98% | 090436 | 5g | $257 |
| More product size | |||
| Melting point | 240-242℃ |
|---|---|
| Boiling point | 374.0±44.0 °C(Predicted) |
| Density | 1.30±0.1 g/cm3(Predicted) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | powder to crystal |
| pka | 8.60±0.30(Predicted) |
| color | White to Orange to Green |
| InChI | InChI=1S/C10H8BFO2/c12-10-6-5-9(11(13)14)7-3-1-2-4-8(7)10/h1-6,13-14H |
| InChIKey | IDCGAEJGZLYEAZ-UHFFFAOYSA-N |
| SMILES | B(C1=C2C(C=CC=C2)=C(F)C=C1)(O)O |
| CAS DataBase Reference | 182344-25-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 20/21/22 | |||||||||
| Safety Statements | 36/37 | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
4-Fluoronaphtalene-1-boronic acid price More Price(36)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | F1080 | 4-Fluoro-1-naphthaleneboronic Acid (contains varying amounts of Anhydride) | 182344-25-8 | 200mg | $47 | 2025-07-31 | Buy |
| TCI Chemical | F1080 | 4-Fluoro-1-naphthaleneboronic Acid (contains varying amounts of Anhydride) | 182344-25-8 | 1g | $140 | 2025-07-31 | Buy |
| TRC | F593853 | 4-Fluoronaphthalene-1-boronicacid | 182344-25-8 | 500mg | $115 | 2021-12-16 | Buy |
| TRC | F593853 | 4-Fluoronaphthalene-1-boronicacid | 182344-25-8 | 1g | $160 | 2021-12-16 | Buy |
| Matrix Scientific | 090436 | 4-Fluoronaphthalene-1-boronic acid 98% | 182344-25-8 | 5g | $257 | 2021-12-16 | Buy |
4-Fluoronaphtalene-1-boronic acid Chemical Properties,Uses,Production
Chemical Properties
White solid
Synthesis
5419-55-6
341-41-3
182344-25-8
In a 500 mL three-necked flask, 1-bromo-4-fluoronaphthalene (27.9 g, 0.124 mol) was dissolved in anhydrous tetrahydrofuran (200.0 mL), followed by the addition of triisopropyl borate (26.8 g, 0.142 mol), and the reaction mixture was cooled to -78°C. At -78°C, a solution of n-butyllithium (9.5 g, 0.149 mol) was slowly added dropwise. ) to the solution, and the dropwise addition lasted for 0.5 hours. After the dropwise addition was completed, the reaction mixture was allowed to gradually warm up to room temperature. Upon completion of the reaction, the reaction was quenched by addition of saturated aqueous ammonium chloride solution. After adjusting the pH of the reaction mixture to strongly acidic, it was extracted with ethyl acetate (200.0 mL x 3). The organic phases were combined, washed with saturated brine and dried over anhydrous sodium sulfate. Subsequently, the solvent was removed by distillation under reduced pressure. The residue was pulped with hexane and filtered to give 21.2 g of 4-fluoronaphthalene-1-boronic acid solid in 90.2% yield.
References
[1] Patent: CN106478376, 2017, A. Location in patent: Paragraph 0022-0024; 0049-0051; 0076-0078; 0085-0087
4-Fluoronaphtalene-1-boronic acid Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 8626 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29833 | 58 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10405 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49977 | 58 |
| Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
View Lastest Price from 4-Fluoronaphtalene-1-boronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-01-27 | 4-Fluoronaphtalene-1-boronic acid
182344-25-8
|
US $79.00-289.00 / g | 5g | 0.98 | 25kg | Shanghai UCHEM Inc. | |
 |
2019-07-06 | 4-Fluoronaphtalene-1-boronic acid
182344-25-8
|
US $1.00 / kg | 1kg | 98% | 100KG | Career Henan Chemical Co |
-
- 4-Fluoronaphtalene-1-boronic acid
182344-25-8
- US $79.00-289.00 / g
- 0.98
- Shanghai UCHEM Inc.
-
- 4-Fluoronaphtalene-1-boronic acid
182344-25-8
- US $1.00 / kg
- 98%
- Career Henan Chemical Co
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