9-ALLYLCARBAZOLE
- CAS No.
- 3998-04-7
- Chemical Name:
- 9-ALLYLCARBAZOLE
- Synonyms
- 9-ALLYLCARBAZOLE;9-Allyl-9H-carbazol;9H-Carbazole, 9-(2-propen-1-yl)-
- CBNumber:
- CB22752167
- Molecular Formula:
- C15H13N
- Molecular Weight:
- 207.27
- MDL Number:
- MFCD00093414
- MOL File:
- 3998-04-7.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
9-ALLYLCARBAZOLE price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | A3812 | 9-Allyl-9H-carbazole min. 98.0 % | 3998-04-7 | 1G | $69 | 2026-04-30 | Buy |
| TCI Chemical | A3812 | 9-Allyl-9H-carbazole min. 98.0 % | 3998-04-7 | 5G | $207 | 2026-04-30 | Buy |
| Activate Scientific | AS49640 | 9-Allyl-9H-carbazole 95% | 3998-04-7 | 1g | $61 | 2026-06-04 | Buy |
| Activate Scientific | AS49640 | 9-Allyl-9H-carbazole 95% | 3998-04-7 | 5g | $190 | 2026-06-04 | Buy |
| Synthonix | A58173 | 9-Allyl-9H-carbazole 95+% | 3998-04-7 | 250mg | $44 | 2026-05-06 | Buy |
9-ALLYLCARBAZOLE Chemical Properties, Uses, Production
Synthesis
86-74-8
106-95-6
3998-04-7
The general procedure for the synthesis of 9-allyl-9H-carbazole from carbazole and 3-bromo-1-propenyl was as follows: firstly, 1,2-polybutadiene was functionalized using S-[3-(9-carbazolyl)propyl] ester of thiobenzoic acid (16), which in turn led to the synthesis of 9-allylcarbazole (15). This was carried out as follows: carbazole (10.1 g, 0.057 mol) and potassium hydroxide (88% wt pellets, crushed, 7.1 g, 0.11 mol) were dissolved in 100 mL of DMSO and stirred at 50 °C for 30 min. Subsequently, allyl bromide (14.7 g, 0.118 mol) was added slowly and dropwise. After 15 minutes of reaction, the mixture was poured into a 500 mL dispensing funnel containing 100 mL of chloroform and washed five times with 200 mL of water. After evaporation of the solvent under reduced pressure at 60 °C, compound 15 was obtained with >99% purity as a dark brown viscous syrupy substance, which solidified to a solid on cooling (11.9 g, 0.057 mol, 100% yield). The product was analyzed by 1H NMR (300 MHz, CDCl3) showing δ=8.14-8.06 (m, 2H, carbazole), 7.49-7.32 (m, 4H, carbazole), 7.28-7.19 (m, 2H, carbazole), 6.04-5.90 (m, 1H, CH=CH2), 5.19-5.10 (m, 1H, Z-HCH= CH), 5.07-4.97 (m, 1H, E-HCH=CH), 4.92-4.85 (m, 2H, NCH2). 13C NMR (300 MHz, CDCl3) analysis showed δ=140.34, 132.27, 125.67, 122.90, 120.33, 119.00, 116.74, 108.74, 45.21. 108.74, 45.21.
References
[1] Patent: WO2009/52148, 2009, A1. Location in patent: Page/Page column 35
[2] Journal of Heterocyclic Chemistry, 2014, vol. 51, # 3, p. 683 - 689
[3] Synthetic Communications, 2010, vol. 40, # 15, p. 2291 - 2301
[4] Journal of the American Chemical Society, 2018, vol. 140, # 40, p. 12705 - 12709
[5] Russian Chemical Bulletin, 1993, vol. 42, # 8, p. 1372 - 1376
9-ALLYLCARBAZOLE Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
9-ALLYLCARBAZOLE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Tianjin Derchemist Science & Technology Co., Ltd. | 22-58627059 13920586291 | zdcomcon@126.com | China | 4094 | 50 |
| Zhengzhou Guancheng Laboratory equipment Sales | 0371-88888888 qq272369594;2159423853qq | 2723695949@qq.com | China | 4990 | 50 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| Aikon International Limited | 025-58859352 13913916777 | dt3@aikonchem.com | China | 15490 | 58 |
| Tianjin heowns Biochemical Technology Co., Ltd. | 400-6387771-6039 18920764717 | sales@heowns.com | China | 24650 | 60 |
| Henan Weituxi Chemical Technology Co., Ltd. | 0371-63284658 18135795563 | 3905209149@qq.com | China | 9707 | 58 |
| Shanghai Haohong Pharmaceutical Co., Ltd. | 400-8210725 4008210725 | malulu@leyan.com | China | 39796 | 58 |
| Guangdong wengjiang Chemical Reagent Co., Ltd. | 0751-2815987 13927875076 | 3007432263@qq.com | China | 9999 | 58 |
| Bide Pharmatech Ltd. | 400-1647117 13681763483 | product02@bidepharm.com | China | 59929 | 58 |
