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2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER

CAS No.
832735-54-3
Chemical Name:
2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER
Synonyms
2-Benzyloxy-5-pyridineboronic acid pinacol ester;2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER;6-benzoxypyridine-3-borate frequency alcohol ester;6-(Benzyloxy)pyridine-3-boronic acid pinacol ester;2-BENZYLOXY-5-(4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXABOROLAN-2-YL)PYRIDINE;Pyridine, 2-(phenylmethoxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
CBNumber:
CB2380762
Molecular Formula:
C18H22BNO3
Molecular Weight:
311.18
MDL Number:
MFCD06798263
MOL File:
832735-54-3.mol
Last updated:2025-07-24 18:13:54
Product description Number Pack Size Price
2-Benzyloxy-5-pyridineboronic acid pinacol ester 97% 715484 1g $252
6-Benzyloxypyridine-3-boronicacid,pinacolester B288883 500mg $65
6-Benzyloxypyridine-3-boronicacid,pinacolester B288883 100mg $45
2-Benzyloxy-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridine FB33104 250mg $45
2-(Benzyloxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 95+% P000663198 1g $61

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Properties

Melting point 138-142°C
Boiling point 429.6±35.0 °C(Predicted)
Density 1.11±0.1 g/cm3(Predicted)
storage temp. 2-8°C
form solid
pka 3.91±0.24(Predicted)
color Yellow
CAS DataBase Reference 832735-54-3
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
HS Code  2933399990
NFPA 704
0
2 0

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 715484 2-Benzyloxy-5-pyridineboronic acid pinacol ester 97% 832735-54-3 1g $252 2023-06-20 Buy
TRC B288883 6-Benzyloxypyridine-3-boronicacid,pinacolester 832735-54-3 500mg $65 2021-12-16 Buy
TRC B288883 6-Benzyloxypyridine-3-boronicacid,pinacolester 832735-54-3 100mg $45 2021-12-16 Buy
Biosynth Carbosynth FB33104 2-Benzyloxy-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridine 832735-54-3 250mg $45 2021-12-16 Buy
Ark Pharm P000663198 2-(Benzyloxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 95+% 832735-54-3 1g $61 2021-12-16 Buy
Product number Packaging Price Buy
715484 1g $252 Buy
B288883 500mg $65 Buy
B288883 100mg $45 Buy
FB33104 250mg $45 Buy
P000663198 1g $61 Buy

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Chemical Properties,Uses,Production

Synthesis

2-BENZYLOXY-5-BROMOPYRIDINE

83664-33-9

Bis(pinacolato)diboron

73183-34-3

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER

832735-54-3

General procedure: to a 50 mL solution of 1,4-dioxane was added sequentially 2-benzyloxy-5-bromopyridine (3.76 g, 14.2 mmol, 1.0 eq.), pinacol ester of bis(boronic acid) (4.34 g, 17.1 mmol, 1.2 eq.), potassium acetate (3.48 g, 35.5 mmol, 2.5 eq.), and [1,1'-bis(diphenylphosphino) ferrocene]palladium dichloride (1.16 g, 1.4 mmol, 0.1 eq.). The reaction mixture was heated to 100 °C under nitrogen protection and refluxed overnight. After completion of the reaction, the reaction mixture was concentrated and dried, and the residue was purified by column chromatography (eluent: petroleum ether/dichloromethane=2:1) to afford 6-benzyloxypyridine-3-boronic acid pinacol ester (2.63 g, 59.5% yield).

References

[1] Patent: CN106588937, 2017, A. Location in patent: Paragraph 0197

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Preparation Products And Raw materials

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Suppliers

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View Lastest Price from 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER pictures 2019-12-31 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER
832735-54-3
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co

2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER Spectrum

2-Benzyloxy-5-pyridineboronic acid pinacol ester 2-BENZYLOXY-5-(4,4,5,5-TETRAMETHYL-[1,3,2]-DIOXABOROLAN-2-YL)PYRIDINE 2-BENZYLOXYPYRIDINE-5-BORONIC ACID, PINACOL ESTER 6-(Benzyloxy)pyridine-3-boronic acid pinacol ester Pyridine, 2-(phenylmethoxy)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- 6-benzoxypyridine-3-borate frequency alcohol ester 832735-54-3 C18H22BNO3 Heterocyclic Compounds