2,6-Dimethoxyphenylboronic acid
- CAS No.
- 23112-96-1
- Chemical Name:
- 2,6-Dimethoxyphenylboronic acid
- Synonyms
- 2,6-DIMETHOXYBENZENEBORONIC ACID;AKOS BRN-0146;TIMTEC-BB SBB003736;RARECHEM AH PB 0108;CHEMBRDG-BB 3200972;2,6-Dimethoxyphenylboronic;2,6-DIMETHOXYPHENYLBORONIC ACID;(2,6-dimethoxyphenyl)boronicaci;2, 6-dimethoxy-phenylboric acid;2,6-Dimethoxyphenylboronic acid,97%
- CBNumber:
- CB2470607
- Molecular Formula:
- C8H11BO4
- Molecular Weight:
- 181.98
- MDL Number:
- MFCD01318987
- MOL File:
- 23112-96-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2,6-Dimethoxyphenylboronic acid ≥97% | 480096 | 5g | $30.9 |
| 2,6-Dimethoxyphenylboronic acid ≥97% | 480096 | 25g | $65.1 |
| 2,6-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) | D3861 | 5g | $52 |
| 2,6-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) | D3861 | 25g | $165 |
| 2,6-Dimethoxyphenylboronic acid Asreported | 273494 | 25g | $490 |
| More product size | |||
| Melting point | 110-112 °C (lit.) |
|---|---|
| Boiling point | 372.8±52.0 °C(Predicted) |
| Density | 1.19±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| pka | 8.58±0.58(Predicted) |
| form | Powder |
| color | White to beige |
| BRN | 3032352 |
| InChI | InChI=1S/C8H11BO4/c1-12-6-4-3-5-7(13-2)8(6)9(10)11/h3-5,10-11H,1-2H3 |
| InChIKey | BKWVXPCYDRURMK-UHFFFAOYSA-N |
| SMILES | B(C1=C(OC)C=CC=C1OC)(O)O |
| CAS DataBase Reference | 23112-96-1(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 37/39-26-36/37 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant/Keep Cold | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29319090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
2,6-Dimethoxyphenylboronic acid price More Price(88)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 480096 | 2,6-Dimethoxyphenylboronic acid ≥97% | 23112-96-1 | 5g | $30.9 | 2026-04-30 | Buy |
| Sigma-Aldrich | 480096 | 2,6-Dimethoxyphenylboronic acid ≥97% | 23112-96-1 | 25g | $65.1 | 2026-04-30 | Buy |
| TCI Chemical | D3861 | 2,6-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) | 23112-96-1 | 5g | $52 | 2026-04-30 | Buy |
| TCI Chemical | D3861 | 2,6-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) | 23112-96-1 | 25g | $165 | 2026-04-30 | Buy |
| Usbiological | 273494 | 2,6-Dimethoxyphenylboronic acid Asreported | 23112-96-1 | 25g | $490 | 2026-06-03 | Buy |
2,6-Dimethoxyphenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
white to beige powder
Uses
2,6-Dimethoxyphenylboronic acid can be used as a reagent in:
The palladium-catalyzed Suzuki-Miyaura coupling reaction to construct carbon-carbon bond.
The synthesis of 2H-imidazo[1,5-a]pyridin-4-ium bromides, which are utilized as precursors for the preparation of N-heterocyclic carbene ligands.
The preparation of monosubstituted benzothiazoloquinazolinones as potential monoamine oxidases inhibitors.
Reactant for:
Suzuki-Miyaura reactions
Synthesis
121-43-7
151-10-0
23112-96-1
The general procedure for the synthesis of 2,6-dimethoxyphenylboronic acid from trimethyl borate and m-phenylene dimethyl ether was as follows: 41.5 g (0.3 mol) of 1,3-dimethoxybenzene and 170 g of THF were added to a dry 1L three-neck flask. The reaction system was cooled to -30~-40°C under nitrogen protection and stirred. 240 ml (0.6 mol) of n-butyllithium in hexane solution was added slowly dropwise. After the dropwise addition, the reaction system was slowly warmed to 10~30°C and maintained at this temperature for 1 hour. Subsequently, the system was again cooled to -30~-40 °C and 62.4 g (0.6 mol) of trimethyl borate was slowly added dropwise. After the dropwise addition was completed, the reaction was maintained at this temperature for 1 hour. After the reaction was completed, 148 g of concentrated hydrochloric acid and 150 g of water were added to the system and stirred at 20-30 °C for 1 hour. After completion of the reaction, the solvent was removed by distillation under reduced pressure until no solvent evaporated. The residue was dissolved in 200 g of water and stirred for 20 min, followed by filtration using a Brinell funnel to give 45 g of white solid product in 90.0% yield. The product was analyzed by gas chromatography and the purity was 99.0%.
References
[1] Patent: WO2004/24738, 2004, A1. Location in patent: Page/Page column 13-14
[2] Patent: CN105348240, 2016, A. Location in patent: Paragraph 0059; 0060
[3] Organic and Biomolecular Chemistry, 2016, vol. 14, # 20, p. 4664 - 4668
[4] Organic Letters, 2012, vol. 14, # 16, p. 4250 - 4253
[5] Patent: KR2016/90242, 2016, A. Location in patent: Paragraph 0162; 0163; 0164; 0165; 0166; 0167; 0168
2,6-Dimethoxyphenylboronic acid Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Xinxiang Hongqi District Houyuan Trading Co.,Ltd | +86-0373-3695376 +86-13937349994 | HYJM@houyuanjm.com | China | 299 | 58 |
| Hebei Xinsheng New Material Technology Co., LTD. | +86-16632316109 | xinshengkeji@xsmaterial.com | China | 1085 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 | jiuyitime@fdachem.com | China | 16512 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14014 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29812 | 58 |
| Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2994 | 58 |
| SHAANXI WEISHINUO THE NEW MATERIALCO,.LTD | 18792503214 | Beryl@weishino.com | CHINA | 256 | 58 |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2950 | 58 |
View Lastest Price from 2,6-Dimethoxyphenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-04-17 | 2,6-Dimethoxyphenylboronic acid
23112-96-1
|
$2.20-8.80 | 1kg | 99%min | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2023-11-30 | 2,6-Dimethoxyphenylboronic acid
23112-96-1
|
1kg | 99.9% | 30000 Kg | Hebei Xinsheng New Material Technology Co., LTD. | ||
 |
2023-10-30 | 2,6-Dimethoxyphenylboronic acid
23112-96-1
|
$25.00-35.00 | 1kg | 99% | 20 Ton | Hebei Xinsheng New Material Technology Co., LTD. |
-
- 2,6-Dimethoxyphenylboronic acid
23112-96-1
- $2.20-8.80
- 99%min
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- 2,6-Dimethoxyphenylboronic acid
23112-96-1
- 99.9%
- Hebei Xinsheng New Material Technology Co., LTD.
-
- 2,6-Dimethoxyphenylboronic acid
23112-96-1
- $25.00-35.00
- 99%
- Hebei Xinsheng New Material Technology Co., LTD.
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