ChemicalBook >> CAS DataBase List >>(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE structure

CAS No.: 82499-43-2

Chemical Name:: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE

Synonyms: (bicyclo(2.2.1)hepta-2,5-diene)(1,4-bis-(diphenyl;bicycloheptadiene(diphenylphosphino)butane rhodium BF4;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)(1,4-BIS- (DIPHENYLPHOS)BUTANE)RH(I) BF4;[1,4-Bis(diphenylphosphino)butane](norbornadiene)rhodium (tetrafluoroborate);(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE;bicyclo[2.2.1]hepta-2,5-diene,4-diphenylphosphanylbutyl(diphenyl)phosphane,rhodium,tetrafluoroborate

CBNumber:: CB2698915

Molecular Formula:: C35H36BF4P2Rh

Molecular Weight:: 708.32

MDL Number:: MFCD00075218

MOL File:: 82499-43-2.mol

Last updated:2025-01-27 09:38:02

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Properties

Melting point	210 °C (dec.)(lit.)
storage temp.	Inert atmosphere,2-8°C
solubility	insol Et2O, pentane; sol CH2Cl2, MeOH, etc
UNSPSC Code	12161600
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302+H312+H332-H315-H319-H335
Precautionary statements	P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-36
WGK Germany	3

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE price More Price(11)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	341126	(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate	82499-43-2	100mg	$71	2025-07-31	Buy
TRC	B382845	(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate	82499-43-2	10mg	$55	2021-12-16	Buy
American Custom Chemicals Corporation	OGM0000781	(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE 95.00%	82499-43-2	1G	$809.55	2021-12-16	Buy
BLDpharm	BD246784	(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate 98%	82499-43-2	100mg	$99	2021-12-16	Buy
Arctom	AS556302	(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate 98%	82499-43-2	100mg	$182	2021-12-16	Buy

Product number	Packaging	Price	Buy
341126	100mg	$71	Buy
B382845	10mg	$55	Buy
OGM0000781	1G	$809.55	Buy
BD246784	100mg	$99	Buy
AS556302	100mg	$182	Buy

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Chemical Properties,Uses,Production

Uses

(Bicyclo[2.2.1]hepta-2,5-diene)[1,4-bis(diphenylphosphino)butane]rhodium(I) tetrafluoroborate is a catalyst for hydrogenation, hydrosilylation, hydroboration and aldol condensation reactions.

Preparation

a solution of [Rh(nbd)acac] in THF is treated with fluoroboric acid, followed by addition of 1,4-bis(diphenylphosphino)butane (dppb). The solution becomes deep red and ether is added to precipitate the catalyst, which is then isolated by filtration. The unpurified product is generally adequately pure for most applications. Recrystallization from methanol can be performed to obtain orange needles of [Rh(nbd)(dppb)]BF4. Although air-sensitive in solution, the crystalline complex is indefinitely stable when prepared pure and stored under N2 or Ar below 0 °C. A convenient preparation of the corresponding trifluoromethanesulfonate has been described. The cyclooctadiene (cod) analog has been characterized by X-ray crystallography, and the dynamic solution structure of related systems has been studied by multinuclear NMR techniques.

reaction suitability

core: rhodium
reagent type: catalyst

storage

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE should store under argon in freezer; stable as solid; solutions are air sensitive. Literature describes the use of perchlorate salts but their use cannot be recommended due to risk of detonation. Use in a fume hood.

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE Suppliers

Global( 42)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29800	58
Hubei Ipure Biology Co., Ltd	+8613367258412	ada@ipurechemical.com	China	10242	58
HONG KONG IPURE BIOLOGY CO.,LIMITED	86 18062405514 18062405514	ada@ipurechemical.com	CHINA	3461	58
Xi'an MC Biotech, Co., Ltd.	029-89275612 +8618991951683	mcbio_sales@163.com	China	2251	58
Henan Alfa Chemical Co., Ltd	+8615838112936	alfa10@alfachem.cn	China	12931	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6114	58
Aladdin Scientific		tp@aladdinsci.com	United States	57505	58
Amadis Chemical Company Limited	571-89925085	sales@amadischem.com	China	131957	58
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42952	64
Tianjin heowns Biochemical Technology Co., Ltd.	400 638 7771	sales@heowns.com	China	14435	57

Supplier	Advantage
career henan chemical co	58
Hubei Ipure Biology Co., Ltd	58
HONG KONG IPURE BIOLOGY CO.,LIMITED	58
Xi'an MC Biotech, Co., Ltd.	58
Henan Alfa Chemical Co., Ltd	58
Shaoxin Catsyn Co., Ltd.	58
Aladdin Scientific	58
Amadis Chemical Company Limited	58
Shanghai Hanhong Scientific Co.,Ltd.	64
Tianjin heowns Biochemical Technology Co., Ltd.	57

View Lastest Price from (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-03-06	(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE 82499-43-2	US $2.00 / g	1g	95~99.9%	5KG	Career Henan Chemical Co

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE
82499-43-2
US $2.00 / g
95~99.9%
Career Henan Chemical Co

82499-43-2((BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE)Related Search:

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE 1,4-Bis(diphenylphosphino)butane METHYLPHOSPHINE BORANE COMPLEX BORANE-DIPHENYLPHOSPHINE COMPLEX 2,5-Norbornadiene

1,4-BIS(DIMETHYLPHOSPHINO)BUTANE

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) TETRAFLUOROBORATE (bicyclo(2.2.1)hepta-2,5-diene)(1,4-bis-(diphenyl (BICYCLO(2.2.1)HEPTA-2,5-DIENE)(1,4-BIS- (DIPHENYLPHOS)BUTANE)RH(I) BF4 bicycloheptadiene(diphenylphosphino)butane rhodium BF4 bicyclo[2.2.1]hepta-2,5-diene,4-diphenylphosphanylbutyl(diphenyl)phosphane,rhodium,tetrafluoroborate [1,4-Bis(diphenylphosphino)butane](norbornadiene)rhodium (tetrafluoroborate) 82499-43-2 C35H36BF4P2Rh Catalysis and Inorganic Chemistry Catalysis and Inorganic Chemistry Chemical Synthesis Rhodium