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Sulfometuron-methyl

CAS No.
74222-97-2
Chemical Name:
Sulfometuron-methyl
Synonyms
SULFOMETURON METHYL;DPX-T5648;oust;aa5648;Oust[R];dpx5648;Oust 75DF;Oust(Du Pont);Sulfometuron-m;sulfometuron-me
CBNumber:
CB2721994
Molecular Formula:
C15H16N4O5S
Molecular Weight:
364.38
MDL Number:
MFCD00128060
MOL File:
74222-97-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 00:50:03
Product description Number Pack Size Price
Sulfometuron methyl PESTANAL 34224 100mg $226
Sulfometuron-methyl 98% Z238395 100MG $315
Sulfometuron-methyl 98% Z238395 250MG $630
Sulfometuron-Methyl 97% API-1308 5g $740
Sulfometuron methyl ester 289383 50mg $463
More product size

Sulfometuron-methyl Properties

Melting point 203-205°C
Boiling point 197°C (rough estimate)
Density 1.48
refractive index 1.6000 (estimate)
pka 5.7(at 25℃)
Henry's Law Constant 8.2×1012 mol/(m3Pa) at 25℃, Armbrust (2000)
Major Application agriculture
environmental
InChI 1S/C15H16N4O5S/c1-9-8-10(2)17-14(16-9)18-15(21)19-25(22,23)12-7-5-4-6-11(12)13(20)24-3/h4-8H,1-3H3,(H2,16,17,18,19,21)
InChIKey ZDXMLEQEMNLCQG-UHFFFAOYSA-N
SMILES COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(C)cc(C)n2
CAS DataBase Reference 74222-97-2(CAS DataBase Reference)
FDA UNII JLY5D60J1A
EPA Substance Registry System Sulfometuron methyl (74222-97-2)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Environment (GHS09)
GHS09
Signal word  Warning
Hazard statements  H400
Precautionary statements  P273-P391-P501
PPE Eyeshields, Gloves
Hazard Codes  N
Risk Statements  50
Safety Statements  61
RIDADR  UN3077 9/PG 3
WGK Germany  2
RTECS  DG9096550
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Acute 1
Hazardous Substances Data 74222-97-2(Hazardous Substances Data)
Toxicity LD50 in male, female rats (mg/kg): >5000, >5000 orally (Harding)

Sulfometuron-methyl price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 34224 Sulfometuron methyl PESTANAL 74222-97-2 100mg $226 2026-04-30 Buy
ACHEMBLOCK Z238395 Sulfometuron-methyl 98% 74222-97-2 100MG $315 2026-05-27 Buy
ACHEMBLOCK Z238395 Sulfometuron-methyl 98% 74222-97-2 250MG $630 2026-05-27 Buy
AHH API-1308 Sulfometuron-Methyl 97% 5g $740 2026-05-26 Buy
Usbiological 289383 Sulfometuron methyl ester 74222-97-2 50mg $463 2021-12-16 Buy
Product number Packaging Price Buy
34224 100mg $226 Buy
Z238395 100MG $315 Buy
Z238395 250MG $630 Buy
API-1308 5g $740 Buy
289383 50mg $463 Buy

Sulfometuron-methyl Chemical Properties,Uses,Production

Chemical Properties

The prodrug is white solid. m.p. 203~205℃, vapor pressure 7.39×10-14Pa, relative density 1.48. At 25℃, the solubility is: acetone 2.4g/kg, acetonitrile 1.5g/kg, ethanol 137mg/kg, ether 32mg/kg, xylene 37mg/kg, water 8mg/L (pH=5), 70mg/L (pH =7). The partition coefficient was 0.31 (pH=7). The hydrolysis half-life of the aqueous suspension was 18d at pH=5, and it was stable at pH=7-9. The half-life in soil was about 28d.

Uses

Metsulfuron-methyl is a sulfonylurea herbicide that inhibits the synthesis of branched-chain amino acids, thereby inhibiting cell division at the growing tips of plants, preventing the growth of weeds, and leading to chlorosis and necrosis. It is suitable for the control of annual and perennial grass weeds and broadleaf weeds in forestry.

Preparation

Sulfometuron-methyl is produced by reaction of 2-sulfonylisocyanate methylbenzoate with 2-amino-4,6-dimethylpyrimidine.

Definition

ChEBI: Sulfometuron methyl is a benzoate ester that is the methyl ester of 2-{[(4,6-dimethylpyrimidin-2-yl)carbamoyl]sulfamoyl}benzoic acid. It has a role as a herbicide and an EC 2.2.1.6 (acetolactate synthase) inhibitor. It is a member of pyrimidines, a benzoate ester and a N-sulfonylurea. It is functionally related to a sulfometuron.

Agricultural Uses

Herbicide: Used to control annual and perennial grasses and broadleaf weeds on landscapes, rights-of-ways, fence rows, forests, industrial structure areas and non-crop land. Not listed for use in EU countries. Registered for use in the U.S.

Trade name

DPX-T5648®; KNOCKOUT®; LANDMARK® MP (sulfometuron-methyl + chlorsulfuron); OUST®; OUSTAR®; RIVERDALE®; STAMPRO®

Environmental Fate

Soil. In unsterilized soils, 58% of 14C-labeled sulfometuron-methyl degraded after 24 weeks. Metabolites identified were 2,3-dihydro-3-oxobenzisosulfonazole (saccharin), methyl-2-(aminosulfonyl)benzoate, 2-aminosulfonyl benzoic acid, 2-(((aminocarbonyl)amino)sulfonyl)benzoate and [14C]carbon dioxide. The rate of degradation in aerobic soils was primarily dependent upon pH and soil type (Anderson and Dulka, 1985). The reported half-life in soil was approximately 4 weeks (Hartley and Kidd, 1987).
Chemical/Physical. Sulfometuron-methyl is stable in water at pH values of 7 to 9 but is rapidly hydrolyzed at pH 5.0 forming methyl 2-(aminosulfonyl)benzoate and saccharin. When sulfometuron-methyl in an aqueous solution was exposed to UV light (λ = 300–400 nm), it degraded to the intermediate methyl benzoate which then mineralized to carbon dioxide (Harvey et al., 1985). The hydrolysis half-lives of metsulfuron-methyl at pH 5 and 25 and 45°C were 33 and 2.1 days, respectively. At pH 7 and 45°C, the hydrolysis half-life is 33 days (Beyer et al., 1988).

Metabolic pathway

Sulfometuron methyl is relatively stable at neutral and basic pH and undergoes cleavage of the sulfonylurea linkage to yield methyl-2-(aminosulfonyl)benzoate and 4,6-dimethyl-2-aminopyrimidine as major hydrolysis products, and saccharin as the terminal product. These products are also observed as major degradation products in soils. In plants, monohydroxymethylsulfometuron methyl is the primary metabolite which is also identified as a mammalian and soil metabolite and undergoes further degradation by mammals to give 2-amino-4-hydroxymethyl-6- methylpyrimidine.

767-15-7
26638-43-7
74222-97-2
Synthesis of Sulfometuron-methyl from 2-Amino-4,6-dimethylpyrimidine and Methyl 2-(chlorosulfonyl)benzoate
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View Lastest Price from Sulfometuron-methyl manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Sulfometuron-methyl pictures 2026-05-26 Sulfometuron-methyl
74222-97-2
$50.00-129.00 99.77% 10g TargetMol Chemicals Inc.
DPX-T5648 pictures 2021-07-13 DPX-T5648
74222-97-2
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
DPX-T5648 pictures 2021-07-10 DPX-T5648
74222-97-2
$10.00-15.00 1KG 99%+ HPLC Zhuozhou Wenxi import and Export Co., Ltd
  • DPX-T5648 pictures
  • DPX-T5648
    74222-97-2
  • $10.00-15.00
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
  • DPX-T5648 pictures
  • DPX-T5648
    74222-97-2
  • $10.00-15.00
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd

Sulfometuron-methyl Spectrum

Oust 75DF OUST WEED KILLER(R) oust methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulphonyl]benzoate DPX-5648(DU Pont) Oust(Du Pont) SULFOMETURON METHYL, 100MG, NEAT Sulfometuron methyl PESTANAL Oust[R] Methyl-2-((((4,6-dimethyl-2-pyrimidinyl)amino)crabonyl-amino)sulfonyl)benzoat Sulfometuron-methyl suspension Benzoic acid, 2-(4,6-dimethyl-2-pyrimidinyl)aminocarbonylaminosulfonyl-, methyl ester oust weed killer sulfometuron-methyl (bsi, e-iso, f-iso, ansi, wssa) SULPHOMETURON-METHYL METHYL2-(((((4,6-DIMETHYL-2-PYRIMIDINYL)AMINO)CARBONYL)AM. 2-(((((4,6-DIMETHYL-2-PYRIMIDINYL)AMINO)CARBONYL)AMINO)SUL. Sulfometuron-methyl soluble powder 2-[[[(4,6-dimethyl-2-pyrimidinyl)amino]-oxomethyl]sulfamoyl]benzoic acid methyl ester sulfometuron-me SULFOMETURON METHYL ESTER 2-(4,6-dimethylpyrimidin-2-ylcarbamoylsulfamoyl)benzoic acid methyl ester methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfamoyl]benzoate METHYL 2(((((4,6-DIMETHYL-2-PYRIMIDINYL)-AMINO)CARBONYL)AMINO)SULFONYL)BENZOATE aa5648 dpx5648 methyl2-(((((4,6-dimethyl-2-pyrimidinyl)amino)carbonyl)amino)sulfonyl)benzoa o-((3-(4,6-dimethyl-2-pyrimidinyl)ureido)sulfonyl)-benzoicacimethylester methyl-2(4,6-dimethylpyrimidinyl-2-carbamoyl sulfamoyl) benzoate Methyl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate 2-[(4,6-Dimethylpyrimidine-2-yl)carbamoylsulfamoyl]benzoic acid methyl ester 2-[3-(4,6-Dimethylpyrimidin-2-yl)ureidosulfonyl]benzoic acid methyl ester 2-[[[[(4,6-DIMETHYL-2-PYRIMIDINYL)AMINO]CARBONYL]AMINO]SULPHONYL]BENZOATEMETHYL Sulfometuron-m sulfometuron-methyl [ANSI] C17009000 Sulfometuron-methyl Sulfometuron-methyl, 10 mM in DMSO Methyl 2-(N-((4,6-dimethylpyrimidin-2-yl)carbamoyl)sulfamoyl)benzoate 75%Sulfometuron WDG 75%Sulfometuron 10%Sulfometuron WP 10%Sulfometuron DPX-T5648 SULFOMETURON METHYL 74222-97-2 C15H16N4O5S C15H16H4O5S SN - SZPesticides&Metabolites Alpha sort Environmental Standards Herbicides MetabolitesPesticides&Metabolites Pesticides&Metabolites Q-ZAlphabetic S Urea structure HERBICIDE