3-Amino-2-bromopyridine
- CAS No.
- 39856-58-1
- Chemical Name:
- 3-Amino-2-bromopyridine
- Synonyms
- TIMTEC-BB SBB005539;3-Amino-2-bromopyrid;2-BROMO-PYRIDINEAMINE;2-bromopyridin-3-amine;2-Bromo-3-pyridinamine;2-BROMO-3-PYRIDINEAMINE;2-BROMOPYRIDINE-3-AMINE;2-BROMO-3-AMINOPYRIDINE;3-AMINO-2-BROMOPYRIDINE;3-Pyridinamine, 2-bromo-
- CBNumber:
- CB2730581
- Molecular Formula:
- C5H5BrN2
- Molecular Weight:
- 173.01
- MDL Number:
- MFCD00234064
- MOL File:
- 39856-58-1.mol
| Product description | Number | Pack Size | Price |
| 3-Amino-2-bromopyridine 97% | 661228 | 1g | $33.47 |
| 3-Amino-2-bromopyridine >98.0%(GC)(T) | A1898 | 1g | $33 |
| 3-Amino-2-bromopyridine >98.0%(GC)(T) | A1898 | 5g | $102 |
| 3-Amino-2-bromopyridine | A602123 | 50mg | $60 |
| 3-Amino-2-bromopyridine | A602123 | 10mg | $45 |
| More product size | |||
| Melting point | 76-80 °C |
|---|---|
| Boiling point | 292.5±20.0 °C(Predicted) |
| Density | 1.710±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| pka | 1.72±0.10(Predicted) |
| form | Crystalline Powder |
| color | Beige to dark brown |
| Water Solubility | Slightly soluble in water. |
| BRN | 109830 |
| InChI | 1S/C5H5BrN2/c6-5-4(7)2-1-3-8-5/h1-3H,7H2 |
| InChIKey | HKDVVTLISGIPFE-UHFFFAOYSA-N |
| SMILES | Nc1cccnc1Br |
| CAS DataBase Reference | 39856-58-1(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H315-H318-H335 | |||||||||
| Precautionary statements | P280-P301+P310+P330-P302+P352-P305+P351+P338+P310 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Faceshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-37/38-41-36/37/38 | |||||||||
| Safety Statements | 26-36/39-37/39 | |||||||||
| RIDADR | UN 2811 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29333990 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Acute Tox. 3 Oral Eye Dam. 1 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
3-Amino-2-bromopyridine price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 661228 | 3-Amino-2-bromopyridine 97% | 39856-58-1 | 1g | $33.47 | 2025-07-31 | Buy |
| TCI Chemical | A1898 | 3-Amino-2-bromopyridine >98.0%(GC)(T) | 39856-58-1 | 1g | $33 | 2025-07-31 | Buy |
| TCI Chemical | A1898 | 3-Amino-2-bromopyridine >98.0%(GC)(T) | 39856-58-1 | 5g | $102 | 2025-07-31 | Buy |
| TRC | A602123 | 3-Amino-2-bromopyridine | 39856-58-1 | 50mg | $60 | 2021-12-16 | Buy |
| TRC | A602123 | 3-Amino-2-bromopyridine | 39856-58-1 | 10mg | $45 | 2021-12-16 | Buy |
3-Amino-2-bromopyridine Chemical Properties,Uses,Production
Chemical Properties
Light yellow Cryst
Uses
Used in a palladium-catalyzed synthesis of indole systems containing fused medium- and large-ring heterocycles. pyrrole derivatives ahs been prepared using 3-Amino-2-bromopyridine. Used in P-C coupling reaction.
Synthesis
19755-53-4
39856-58-1
Preparation of Example S-1: 2-Bromo-3-nitropyridine (3 g, 15 mmol) was dissolved in a solvent mixture of tetrahydrofuran (15 mL) and water (5 mL), followed by the addition of iron powder (1 g, 18 mmol) and ammonium chloride (2 g, 37 mmol). The reaction mixture was stirred at 60°C to 70°C for 5 hours. Upon completion of the reaction, the reaction mixture was filtered through a diatomaceous earth pad and the filtrate was washed with brine and extracted with ethyl acetate. The organic layers were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. The resulting crude product was purified by silica gel column chromatography (eluent: ethyl acetate/hexane=1:4) to afford 2-bromo-3-aminopyridine (2.6 g, 15 mmol, quantitative yield).1H-NMR (DMSO-d6) δ (ppm): 5.47 (2H, brs), 7.07-7.09 (2H, m), 7.54 (1H, dd, J=). 2.0,3.6Hz).
References
[1] Patent: EP1782811, 2007, A1. Location in patent: Page/Page column 63
[2] Patent: EP1669348, 2006, A1. Location in patent: Page/Page column 71
[3] Bulletin de la Societe Chimique de France, 1992, # 1, p. 79 - 84
[4] Journal of the Chemical Society, 1952, p. 2042,2044
[5] Tetrahedron, 2002, vol. 58, # 17, p. 3323 - 3328
3-Amino-2-bromopyridine Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 880 | 50 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29831 | 58 |
| Zhejiang ZETian Fine Chemicals Co. LTD | +8618957127338 | stella@zetchem.com | China | 2994 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10405 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | 52513593@qq.com | CHINA | 2972 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
View Lastest Price from 3-Amino-2-bromopyridine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2025-06-25 | 3-Amino-2-bromopyridine
39856-58-1
|
US $21.00 / KG | 1KG | 99.0% min | 100 tons | Shaanxi Dideu Medichem Co. Ltd | |
![]() |
2025-06-25 | 3-Amino-2-bromopyridine
39856-58-1
|
US $1.10 / g | 1g | 99.0% min | 100 tons min | Shaanxi Dideu Medichem Co. Ltd | |
![]() |
2025-04-04 | 3-Amino-2-bromopyridine
39856-58-1
|
US $0.00-0.00 / kg | 1kg | 98% | 10Ton | Henan Aochuang Chemical Co.,Ltd. |
-

- 3-Amino-2-bromopyridine
39856-58-1
- US $21.00 / KG
- 99.0% min
- Shaanxi Dideu Medichem Co. Ltd
-

- 3-Amino-2-bromopyridine
39856-58-1
- US $1.10 / g
- 99.0% min
- Shaanxi Dideu Medichem Co. Ltd
-

- 3-Amino-2-bromopyridine
39856-58-1
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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