ChemicalBook >> CAS DataBase List >>3'-METHOXYPHENACYL BROMIDE

3'-METHOXYPHENACYL BROMIDE

3'-METHOXYPHENACYL BROMIDE structure

CAS No.: 5000-65-7

Chemical Name:: 3'-METHOXYPHENACYL BROMIDE

Synonyms: NSC 405833;AKOS BBS-00003869;3'-MethoxyphenacyL;3-(BROMOACETYL)ANISOLE;M-METHOXYPHENACYL BROMIDE;3-METHOXYPHENACYL BROMIDE;m-Mehtoxyphenacyl Bromide;3'-Methoxyphenacyl Bromide;3'-MethoxyphenacylBromide>α-Bromo-m-methoxyacetophenone

CBNumber:: CB3100727

Molecular Formula:: C9H9BrO2

Molecular Weight:: 229.07

MDL Number:: MFCD00000199

MOL File:: 5000-65-7.mol

MSDS File:: SDS

Last updated:2026-01-13 11:17:25

Product description	Number	Pack Size	Price
2-Bromo-3′-methoxyacetophenone 98%	115673	1g	$30.1
2-Bromo-3′-methoxyacetophenone 98%	115673	10g	$114
3'-Methoxyphenacyl Bromide >98.0%(T)	M0815	5g	$45
3'-Methoxyphenacyl Bromide [for HPLC Labeling] >99.0%(T)	A5505	5g	$78
2-Bromo-3′-methoxyacetophenone 98%	115673	25g	$252
More product size

Request For Quotation

3'-METHOXYPHENACYL BROMIDE Properties

Melting point	60-62 °C(lit.)
Boiling point	215.8°C (rough estimate)
Density	1.4921 (rough estimate)
refractive index	1.5500 (estimate)
storage temp.	2-8°C
solubility	soluble in Methanol
form	Crystalline Powder
color	White to slightly yellow-green
BRN	510128
InChI	InChI=1S/C9H9BrO2/c1-12-8-4-2-3-7(5-8)9(11)6-10/h2-5H,6H2,1H3
InChIKey	IOOHBIFQNQQUFI-UHFFFAOYSA-N
SMILES	C(=O)(C1=CC=CC(OC)=C1)CBr
CAS DataBase Reference	5000-65-7(CAS DataBase Reference)
FDA UNII	CQB4BZ4WTK
NIST Chemistry Reference	2-Bromo-3'-methoxyacetophenone(5000-65-7)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H314-H335

Precautionary statements

P260-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338

target organs

Respiratory system

PPE

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Codes

Risk Statements

34-36/37-22

Safety Statements

26-27-28-36/37/39-45-34

RIDADR

UN 3261 8/PG 2

WGK Germany

HazardClass

PackingGroup

III

HS Code

29147000

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Eye Dam. 1
Skin Corr. 1B
STOT SE 3

NFPA 704

	1
3		0

3'-METHOXYPHENACYL BROMIDE price More Price(30)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	115673	2-Bromo-3′-methoxyacetophenone 98%	5000-65-7	1g	$30.1	2026-03-19	Buy
Sigma-Aldrich	115673	2-Bromo-3′-methoxyacetophenone 98%	5000-65-7	10g	$114	2026-03-19	Buy
TCI Chemical	M0815	3'-Methoxyphenacyl Bromide >98.0%(T)	5000-65-7	5g	$45	2026-03-19	Buy
TCI Chemical	A5505	3'-Methoxyphenacyl Bromide [for HPLC Labeling] >99.0%(T)	5000-65-7	5g	$78	2026-03-19	Buy
Sigma-Aldrich	115673	2-Bromo-3′-methoxyacetophenone 98%	5000-65-7	25g	$252	2026-03-19	Buy

Product number	Packaging	Price	Buy
115673	1g	$30.1	Buy
115673	10g	$114	Buy
M0815	5g	$45	Buy
A5505	5g	$78	Buy
115673	25g	$252	Buy

3'-METHOXYPHENACYL BROMIDE Chemical Properties,Uses,Production

Chemical Properties

WHITE TO SLIGHTLY YELLOW-GREEN CRYST. POWDER

Uses

Derivatizing reagent.

Uses

2-bromo-3′-methoxyacetophenone, an alkylating agent, has been used to stabilize clopidogrel active metabolite (AM) in human plasma. It has also been used in the derivatisation of active metabolites in blood to ensure its stability during sample processing and storage.

Preparation

Obtained by reaction of bromine with 3-methoxyacetophenone in chloroform at 0° for 3 h (88%).

Synthesis

586-37-8

5000-65-7

General procedure for the synthesis of 2-bromo-3'-methoxyacetophenone from 3-methoxyacetophenone: To a stirred yellow solution of clarified 1-(3-methoxyphenyl)acetophenone (20 mL, 139 mmol) in tetrahydrofuran (250 mL) was added in batches of tribromobenzyltrimethylammonium (54.7 g, 145 mmol) and stirring was continued for 1 h at room temperature. After completion of the reaction, the ammonium salt was removed by filtration and the filter cake was washed with ether. Subsequently, the filtrate was concentrated under reduced pressure to give the oily product 2-bromo-1-(3-methoxyphenyl)ethanone (32.6 g, 142 mmol) which could be used without further purification in quantitative yield.

References

[1] Patent: WO2015/16729, 2015, A1. Location in patent: Page/Page column 30
[2] Journal of Medicinal Chemistry, 2017, vol. 60, # 22, p. 9239 - 9250
[3] Bioorganic and Medicinal Chemistry, 2010, vol. 18, # 15, p. 5715 - 5723
[4] Journal of the Chemical Society of Pakistan, 2016, vol. 38, # 5, p. 859 - 863
[5] Journal of the American Chemical Society, 1984, vol. 106, # 11, p. 3354 - 3356

3'-METHOXYPHENACYL BROMIDE Preparation Products And Raw materials

Raw materials

3-Methoxyacetophenone Phenyltrimethylammonium tribromide Tetrahydrofuran

Preparation Products

3-Methoxyacetophenone 5-(4-(2-(3-METHOXYPHENYL)-2-OXOETHOXY)BENZYL)THIAZOLIDINE-2,4-DIONE 3-Methoxybenzoylacetonitrile 2-Bromo-3′-hydroxyacetophenone Propanedioic acid, 2-(acetylamino)-2-[2-(3-methoxyphenyl)-2-oxoethyl]-, 1,3-diethyl ester

3-METHOXYPHENYLGLYOXAL HYDRATE 4-(3-Methoxyphenyl)oxazole

1of2

3'-METHOXYPHENACYL BROMIDE Suppliers

Global( 246)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4241	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49977	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29795	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 +86-17392581500	1015@dideu.com	China	3986	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Nanjing Fred Technology Co., Ltd.	+86-02584696168 15380713688	Austin@fredchem.cn	CHINA	865	58
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	8807	58
Dayang Chem (Hangzhou) Co.,Ltd.	+86-0571-88938639 +8617705817739	info@dycnchem.com	China	52722	58

Supplier	Advantage
Changzhou Ansciep Chemical Co., Ltd.	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Shaanxi Dideu Medichem Co. Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Nanjing Fred Technology Co., Ltd.	58
Shanghai UCHEM Inc.	58
Dayang Chem (Hangzhou) Co.,Ltd.	58

View Lastest Price from 3'-METHOXYPHENACYL BROMIDE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-12-27	3'-METHOXYPHENACYL BROMIDE 5000-65-7	US $1.00 / g	1g	99%	200kg	Career Henan Chemical Co

3'-METHOXYPHENACYL BROMIDE
5000-65-7
US $1.00 / g
99%
Career Henan Chemical Co

3'-METHOXYPHENACYL BROMIDE Spectrum

3'-METHOXYPHENACYL BROMIDE(5000-65-7)MS 3'-METHOXYPHENACYL BROMIDE(5000-65-7)¹HNMR 3'-METHOXYPHENACYL BROMIDE(5000-65-7)IR1 3'-METHOXYPHENACYL BROMIDE(5000-65-7)IR2

5000-65-7(3'-METHOXYPHENACYL BROMIDE)Related Search:

3-Methoxyacetophenone 2-Bromo-4'-methoxyacetophenone 1-(1,3-BENZODIOXOL-5-YL)-2-BROMOETHAN-1-ONE 3'-METHOXYPHENACYL BROMIDE 2-BROMO-1-(2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL)ETHAN-1-ONE

2-BROMO-1-(3,4-DIHYDRO-2H-1,5-BENZODIOXEPIN-7-YL)ETHAN-1-ONE 2-BROMO-2',5'-DIMETHOXYACETOPHENONE 2'-METHOXYPHENACYL BROMIDE,2-METHOXYPHENACYL BROMIDE,2-Methoxyphenacyl bromide 98%,O-METHOXYPHENACYL BROMIDE 3-FLUORO-4-METHOXYPHENACYL BROMIDE 2-BROMO-2,3-DIHYDRO-5,6-DIMETHOXY-1H-INDEN-1-ONE

2-BROMO-3'-ACETYLOXYLACETOPHENONE 2-BROMO-7-METHOXY-3,4-DIHYDRONAPHTHALEN-1(2H)-ONE 2-FLUORO-4-METHOXYPHENACYL BROMIDE AURORA KA-4115 2-BROMO-2,3-DIHYDRO-4,7-DIMETHOXY-1H-INDEN-1-ONE

ALPHA,ALPHA'-DIBROMO-2,5-DIMETHOXY-1,4-DIACETYLBENZENE AURORA KA-4114 RARECHEM BW GA 0297

1of4

3'-Methoxyphenacyl Bromide [for HPLC Labeling] Ethanone, 2-bromo-1-(3-methoxyphenyl)- bromomethyl 3-methoxyphenyl ketone AKOS BBS-00003869 ALPHA-BROMO-M-METHOXYACETOPHENONE ALPHA-BROMO-3'-METHOXYACETOPHENONE M-METHOXYPHENACYL BROMIDE 2-BROMO-3''-METHOXYACETOPHENONE 97% JR-8901, 2-Bromo-3'-methoxyacetophenone, 97% m-Mehtoxyphenacyl Bromide 1-(Bromoacetyl)-3-methoxybenzene α-Bromo-3'-methoxyacetophenone α-Bromo-m-methoxyacetophenone 2-Bromo-3'-methoxyacetophenone,97% 2-bromo-3-methyoxyacetophenone NSC 405833 3-(Bromoacetyl)anisole alpha-Bromo-3'-methoxyacetophenone 3-(Bromoacetyl)anisole 2-Bromo-3'-methoxyacetophenone 2-Bromo-3'-methoxyacetophenone, 2-Bromo-1-(3-methoxyphenyl)ethan-1-one, 3-(Bromoacetyl)anisole 2-BroMo-3'-Methoxyacetophenone, derivatization grade 2-Bromo-3'-methoxyacetophenone 2-Bromo-1-(3-methoxyphenyl)ethanone 3-(BROMOACETYL)ANISOLE 3-METHOXYPHENACYL BROMIDE A-BROMO-M-METHOXYACETOPHENONE 2-Bromo-3'-methoxyacetophenone, 98%, derivatization grade 2-BROMO-1-(3-METHOXYPHENYL)ETHANONE 2-Bromo-3'-methoxyacetophenone, 98%, for analysis 3'-MethoxyphenacylBromide> 3'-Methoxyphenacyl Bromide [for HPLC Labeling]> 3'-MethoxyphenacyL 2-Bromo-3'-methoxyacetophenone?New 2-Bromo-3'-methoxyacetophenone 3'-Methoxyphenacyl Bromide 2-Bromo-3′-methoxyacetophenone, CAS 5000-65-7 2-Bromo-3'-methoxyacetophenone 5000-65-7 5000-645-7 50000-65-7 CH3OC6H4COCH2Br Carbonyl Compounds C9 Building Blocks Organic Building Blocks Ketones HPLC Labeling Reagents UV Detection (HPLC Labeling Reagents) Carboxyl Group Labeling Reagents for HPLC Aromatics Intermediates Aromatic Halides (substituted) Analytical Chemistry Carboxyl Group Labeling Reagents for HPLC HPLC Labeling Reagents UV Detection (HPLC Labeling Reagents)