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Diallyldimethylammonium chloride

CAS No.
7398-69-8
Chemical Name:
Diallyldimethylammonium chloride
Synonyms
DADMAC;DIMETHYLDIALLYLAMMONIUM CHLORIDE;dadmac 65%;diallyldimethylammonium chloride solution;Dimethyldiallylaminium·chloride;N,N-Diallyl-N,N-dimethylammonium chloride;Diallydimethylammonium Chloride Solution;Nsc59284;oride soL;Elionfix G conc
CBNumber:
CB3101991
Molecular Formula:
C8H16ClN
Molecular Weight:
161.67
MDL Number:
MFCD00043200
MOL File:
7398-69-8.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-31 17:49:05

Diallyldimethylammonium chloride Properties

Melting point 140-148 °C
Boiling point 118℃ at 101.325kPa
Density 1.03-1.05g/cm3 at 25℃
refractive index n20/D 1.460
storage temp. Sealed in dry,Room Temperature
solubility Methanol (Slightly), Water
form Oil
color Colourless
BRN 5830817
InChI InChI=1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1
InChIKey GQOKIYDTHHZSCJ-UHFFFAOYSA-M
SMILES [N+](C)(C)(CC=C)CC=C.[Cl-]
LogP -2.49 at 20℃ and pH7
Indirect Additives used in Food Contact Substances DIALLYLDIMETHYL AMMONIUM CHLORIDE
CAS DataBase Reference 7398-69-8(CAS DataBase Reference)
FDA 21 CFR 176.170
FDA UNII 8MC08B895B
EPA Substance Registry System Dimethyldiallylammonium chloride (7398-69-8)
UNSPSC Code 12352103
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H412
Precautionary statements  P273-P501
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25
WGK Germany  1
RTECS  UC6660000
3-10
TSCA  TSCA listed
HS Code  29239000
Storage Class 11 - Combustible Solids
Hazardous Substances Data 7398-69-8(Hazardous Substances Data)
REACH Registrations Active
NFPA 704
0
2 0

Diallyldimethylammonium chloride price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 348279 Diallyldimethylammonium chloride solution 65wt. % in H 7398-69-8 1l $170 2026-04-30 Buy
Sigma-Aldrich 32598 Diallyldimethylammonium chloride ≥97.0% (AT) 7398-69-8 10g $239 2026-04-30 Buy
TCI Chemical D2003 Diallyldimethylammonium Chloride (60% in Water) 7398-69-8 25mL $21 2026-04-30 Buy
TCI Chemical D2003 Diallyldimethylammonium Chloride (60% in Water) 7398-69-8 500mL $40 2026-04-30 Buy
ChemScene CS-0167991 Diallyldimethylammonium (chloride) (60% in water) 60%inwater 7398-69-8 1kg $57 2026-06-04 Buy
Product number Packaging Price Buy
348279 1l $170 Buy
32598 10g $239 Buy
D2003 25mL $21 Buy
D2003 500mL $40 Buy
CS-0167991 1kg $57 Buy

Diallyldimethylammonium chloride Chemical Properties, Uses, Production

Description

Diallyldimethylammonium chloride solution (DADMAC) is a hydrophilic quaternary ammonium compound that can be dissolved in an aqueous solution as a positively charged colloid.

Chemical Properties

Colorless to Light yellow to Light orange clear liquid.
Diallyldimethylammonium chloride (DADMAC) and Polydiallyldimethylammonium chloride (polyDADMAC) are contaminants that may be present in potential drinking water sources.
PolyDADMAC is a polymer manufactured from DADMAC. PolyDADMAC is often used to help remove suspended particulates from water. DADMAC has no direct uses, but may be present when polyDADMAC is used.
PolyDADMAC is used in:
Wastewater treatment
Paper making
Textile printing
Silica sand mining

Uses

DADMAC is used as a cationic monomer solution for the fabrication of ion-selective polyelectrolytic anodized aluminium oxide (AAO) membranes which can be used for the development of electrical power generation systems. It may be grafted on carboxymethyl cellulose (CMC) for use as an absorbent for cationic dyes.

Uses

Diallyldimethylammonium chloride (DADMAC) is a viscous, colourless to pale yellow liquid with slight odour. mainly used as cationic monomer in resins production. DADMAC is a quaternary ammonium salt with high density charge and can be dissolved in water very easily. It is non-flammable, non-explosive and stable at room temperature. The polymers occurring by DADMAC reaction is also known as poly-DADMAC and finds its application in a wide range of industrial application.

Application

Diallyldimethylammonium chloride (DADMAC) is a polymer monomer belonging to the quaternary ammonium compounds. The structure of DADMAC is strongly charged and has good water solubility. Therefore, DADMAC and PolyDADMAC are widely used in the field of water treatment as flocculants and flocculation aids, which can effectively flocculate and remove suspended solids, algae, organic matter and other substances. In addition, it can be used as an antimicrobial agent, surfactant or binder in various industrial applications, commonly found in paper, textiles and personal care products.

Synthesis

Dimethylamine

124-40-3

Allyl chloride

107-05-1

Diallyldimethylammonium chloride

7398-69-8

1. 150 parts of a 33% solution of dimethylamine are added to the reactor, heated and stirred until foaming starts at 30°C. Subsequently, 43 parts of 33% dimethylamine solution were added from the receiving tank and the temperature was controlled at 7°C. 2. Two parts of 50% sodium hydroxide solution were added, stirred and heated to 85°C to promote evaporation of the dimethylamine. Continue heating to 100 °C to end this step. An incomplete product of 83.4 parts with 2.2% dimethylamine content was obtained; and 103 parts of dimethylamine solution (including the absorbent) with 56.4% dimethylamine content. 3. In a three-necked flask equipped with a stirrer, a thermometer, a condenser tube and a titration funnel, 100 parts of a 56.4% solution of dimethylamine were added and 30% allyl chloride was slowly added at 0 °C. 4. 180 parts of allyl chloride and 100 parts of 50% sodium hydroxide solution were added dropwise simultaneously at 3°C to 5°C to control the pH between 9.5 and 10.5. 5. After completion of the addition, the temperature was raised to 44°C for refluxing until the pH of the reaction dropped to 6.4, the heating was stopped and cooling was carried out. 6. The reaction mixture was filtered to obtain 64.8 parts of NaCl and 325.3 parts of an aqueous solution of dimethyldiallylammonium chloride. The content of dimethyldiallylammonium chloride was determined to be 60.8% and the yield was 97.65% (based on amine calculations).

References

[1] Patent: CN104557569, 2016, B. Location in patent: Paragraph 0031; 0032; 0033
[2] Patent: CN108329217, 2018, A. Location in patent: Paragraph 0020-0021; 0025-0026; 0030-0031
[3] Russian Chemical Bulletin, 2007, vol. 56, # 3, p. 535 - 539
[4] Patent: CN104370754, 2016, B. Location in patent: Paragraph 0025; 0026

124-40-3
107-05-1
7398-69-8
Synthesis of Diallyldimethylammonium chloride from Dimethylamine and Allyl chloride

Diallyldimethylammonium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Global Suppliers ( 485)
Supplier Tel Email Country ProdList Advantage
Zhejiang Xinhaitian Bio-Technology Co., Ltd. 008615925805416 elainexu_zjxht@163.com China 22 58
Wuhan Jushun Chemical Co., Ltd 13349917800 13349917800 3629602341@qq.com China 4956 58
Minglong (Xianning) Pharmaceutical Co., LTD 186-7296-9259 18771307593 3919539926@qq.com China 4254 58
Hubei Chuanhe Chemical Co., Ltd 187-7130-7593 18672969259 3919539926@qq.com China 2624 58
Hangzhou Haier Xi Livestock Technology Co., Ltd 15988836457 13336065779 pan@healthy-tech.com.cn China 32 58
Boxuan Chemical (Shandong) Co., Ltd. 17653188518 1280242276@qq.com China 999 58
Changzhou Xichenxi Biotechnology Co., Ltd 13900000000 497839497@qq.com China 966 58
Tianjin Zhongxin Chemtech Co., Ltd. 022-66880623 sales@tjzxchem.com China 612 60
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62

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Diallyldimethylammonium chloride pictures 2026-09-18 Diallyldimethylammonium chloride
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Diallyldimethylaminium·chloride Dimethylbis(2-propenyl)aminium·chloride Dimethyldiallylaminium·chloride (CH2=CHCH2)2N(Cl)(CH3)2 Ammonium, diallyldimethyl-, chloride Nsc59284 diallyldimethyl-ammoniuchloride diallyldimethylammoniumchloride(60%aq.) dimethyldiallylaminechloride n,n-dimethyl-n-2-propenyl-2-propen-1-aminiuchloride DIALLYLDIMETHYLAMMONIUM CHLORIDE Diallyldimethylammoniumchlorid N,N-Diallyl-N,N-dimethylammonium chloride Dially Dimethyl ammonium chloride DIALLYLDIMETHYLAMMONIUM CHLORIDE SOL., ~ 65% IN WATER DIALLYLDIMETHYLAMMONIUM CHLORIDE, 65 WT. % SOLUTION IN WATER DiallylDimethylAmmoniumChloride(Dadmac) diallyldimethylammonium chloride solution oride soL DIALLILDIMETILAMMONIOCLORURO Diallyldimethylammonium chloride solution,Dimethyldiallylammonium chloride Diallyldimethylammonium chloride purum DiallyldiMethylaMMoniuM chloride DMDAAC DiMethyldiallylaMMoniuM Chloride (DIMDAC / DADMAC) Elionfix G conc Diallyldimethylammonium chloride solution, 65 wt. % in water N-Allyl-N,N-diMethylprop-2-en-1-aMiniuM chloride DiallyldiMethylaMMoniuM chloride soluti DiallyldiMethylaMMoniuM chloride >=97.0% (AT) DiallyldiMethylaMMoniuM chloride solution 65 wt. % in H2O n,n-dimethyl-n-2-propenyl-2-propen-1-aminium chloride N,N-DIMETHYL DIALLYL AMMONIA CHLORIDE 2-Propen-1-aminium,N,N-dimethyl-N-2-propenyl-,chloride Diallyldimethylammonium Chloride (60% in Water) 2-Propen-1-aminium, N,N-dimethyl-N-2-propen-1-yl-, chloride (1:1) Diallyldimethylammonium Chloride (60% w/w in Water) 65% Diallyldimethylammonium Chloride Solution Dimethyldiallylammonium chloride (DADMAC) Diallyesldimethyeslammonium chloride Diallyldimethylammonium chlori dadmac 65% DADMAC Diallydimethylammonium Chloride Solution DIMETHYLDIALLYLAMMONIUM CHLORIDE 29-Diene Propyl diMethylchloroammonium dimethyl-bis(prop-2-enyl)azanium chloride 7398-69-8 NCH32C3H52Cl CH32NCH2CHCH22Cl Phase Transfer Catalysts Synthetic Reagents Quaternary Ammonium Compounds Ammonium Chlorides (Quaternary) Ammonium Salts Water treatment Ammonium Chlorides (Quaternary) Quaternary Ammonium Compounds Pharmaceutical Intermediates