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p-Anisohydrazide

p-Anisohydrazide structure

CAS No.: 3290-99-1

Chemical Name:: p-Anisohydrazide

Synonyms: 4-METHOXYBENZOHYDRAZIDE;4-METHOXYBENZHYDRAZIDE;AKOS 92185;anisichydrazide;p-anisohydrazide;anisoylhydrazine;AKOS BBS-00004504;P-ANISOYLHYDRAZINE;P-ANISIC HYDRAZIDE;anisicacidhydrazide

CBNumber:: CB3128224

Molecular Formula:: C8H10N2O2

Molecular Weight:: 166.18

MDL Number:: MFCD00017073

MOL File:: 3290-99-1.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 00:56:35

Product description	Number	Pack Size	Price
4-Methoxybenzhydrazide 97%	558346	5g	$24.5
4-Methoxybenzhydrazide 97%	558346	25g	$83.2
4-Methoxybenzohydrazide >98.0%(GC)(T)	M1770	5g	$44
4-Methoxybenzohydrazide >98.0%(GC)(T)	M1770	25g	$136
4-Methoxybenzoic acid hydrazide Asreported	284340	25g	$337
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p-Anisohydrazide Properties

Melting point	136-140 °C(lit.)
Boiling point	294.38°C (rough estimate)
Density	1.2265 (rough estimate)
refractive index	1.6180 (estimate)
storage temp.	Sealed in dry,Room Temperature
form	powder to crystal
pka	12.65±0.10(Predicted)
color	White to Orange to Green
Water Solubility	Slightly soluble in water.
BRN	389017
InChI	1S/C8H10N2O2/c1-12-7-4-2-6(3-5-7)8(11)10-9/h2-5H,9H2,1H3,(H,10,11)
InChIKey	REKQLYUAUXYJSZ-UHFFFAOYSA-N
SMILES	COc1ccc(cc1)C(=O)NN
CAS DataBase Reference	3290-99-1(CAS DataBase Reference)
FDA UNII	33BK77102I
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P261-P305+P351+P338

PPE

Eyeshields, Gloves, type N95 (US)

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

RTECS

BZ4800000

HazardClass

IRRITANT

HS Code

2928009090

Storage Class

11 - Combustible Solids

Toxicity

LD50 ivn-mus: 178 mg/kg CSLNX* NX#00894

NFPA 704

	1
2		0

p-Anisohydrazide price More Price(72)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	558346	4-Methoxybenzhydrazide 97%	3290-99-1	5g	$24.5	2026-04-30	Buy
Sigma-Aldrich	558346	4-Methoxybenzhydrazide 97%	3290-99-1	25g	$83.2	2026-04-30	Buy
TCI Chemical	M1770	4-Methoxybenzohydrazide >98.0%(GC)(T)	3290-99-1	5g	$44	2026-04-30	Buy
TCI Chemical	M1770	4-Methoxybenzohydrazide >98.0%(GC)(T)	3290-99-1	25g	$136	2026-04-30	Buy
Usbiological	284340	4-Methoxybenzoic acid hydrazide Asreported	3290-99-1	25g	$337	2026-06-03	Buy

Product number	Packaging	Price	Buy
558346	5g	$24.5	Buy
558346	25g	$83.2	Buy
M1770	5g	$44	Buy
M1770	25g	$136	Buy
284340	25g	$337	Buy

p-Anisohydrazide Chemical Properties,Uses,Production

Uses

4-Methoxybenzhydrazide is used as pharmaceutical intermediates and it is also involved in a variety of organic synthesis.

Uses

4-Methoxybenzhydrazide may be used to synthesize:

N′-[(E)-5-bromo-2-hydroxy-3-methoxybenzylidene]-4-methoxybenzohydrazide monohydrate
2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole
hydrazone ligands, which readily forms ruthenium(II) hydrazone complexes via reaction with [RuHCl(CO)(PPh₃)₃]

Synthesis Reference(s)

Journal of Medicinal Chemistry, 27, p. 1565, 1984 DOI: 10.1021/jm00378a007

Safety Profile

Poison by intravenous route. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of Nox.

Synthesis

121-98-2

3290-99-1

4-Methoxybenzoic acid hydrazide was synthesized according to literature [22]. A mixture of methyl 4-methoxybenzoate (1.66 g, 10 mmol) with 80% hydrazine hydrate (3.6 mL, 60 mmol) in anhydrous ethanol (20 mL) was heated and refluxed for 6 hours. After completion of the reaction, the solvent was removed by distillation under reduced pressure to give a white precipitate. The crude product was recrystallized from anhydrous ethanol to give 4-methoxybenzohydrazide as colorless needle-like crystals. Yield 96%, melting point 138-139°C (literature values in accordance).

References

[1] Journal of the American Chemical Society, 2013, vol. 135, # 15, p. 5656 - 5668
[2] Journal of the Chilean Chemical Society, 2012, vol. 57, # 4, p. 1492 - 1496
[3] Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2017, vol. 174, p. 272 - 278
[4] European Journal of Medicinal Chemistry, 1985, vol. 20, # 3, p. 257 - 266
[5] Bioorganic and Medicinal Chemistry, 2005, vol. 13, # 16, p. 4842 - 4850

p-Anisohydrazide Preparation Products And Raw materials

Raw materials

Methyl anisate 4-Methoxybenzamide Ethyl 4-methoxybenzoate 4-Methoxybenzoic acid 4-Methoxybenzoyl chloride

Hydrazine hydrate Ethanol

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Preparation Products

N''-(CHLOROACETYL)-4-METHOXYBENZOHYDRAZIDE 5-(4-METHOXYPHENYL)-1 3 4-OXADIAZOLE-2-& 2-(4-methoxyphenyl)-1,3,4-oxadiazole 4-ALLYL-5-(4-METHOXYPHENYL)-4H-1,2,4-TRIAZOLE-3-THIOL 4-(5-(4-methoxyphenyl)-1,3,4-oxadiazol-2-yl)benzene-1,2-diamine

p-Anisohydrazide Suppliers

Global( 209)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-173 9270 1263	1057@dideu.com	China	3997	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29640	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21587	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29815	58
HaBo Hong Kong Co., Limited.	+86-25-18512596065	info@habotech.com	CHINA	933	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88298848	info@edengenechem.com	China	2165	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
Wuhan Chemwish Technology Co., Ltd	027-67849912	sales@chemwish.com	CHINA	10821	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49979	58
Jinan Liheng Biotechnology Co., Ltd.	15865262812	info@lihengpharm.com	CHINA	938	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
HaBo Hong Kong Co., Limited.	58
Changzhou Ditong Chemical Co.,Ltd	58
Alchem Pharmtech,Inc.	58
Wuhan Chemwish Technology Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
Jinan Liheng Biotechnology Co., Ltd.	58

View Lastest Price from p-Anisohydrazide manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2024-07-11	p-Anisohydrazide 3290-99-1	$1.00	1KG	99%	20T	Shaanxi Dideu Medichem Co. Ltd
	2019-07-06	p-Anisohydrazide 3290-99-1	$1.00	1KG	99%		Career Henan Chemical Co

p-Anisohydrazide
3290-99-1
$1.00
99%
Shaanxi Dideu Medichem Co. Ltd

p-Anisohydrazide
3290-99-1
$1.00
99%
Career Henan Chemical Co

p-Anisohydrazide Spectrum

p-Anisohydrazide(3290-99-1)MS p-Anisohydrazide(3290-99-1)¹HNMR p-Anisohydrazide(3290-99-1)¹³CNMR p-Anisohydrazide(3290-99-1)IR1 p-Anisohydrazide(3290-99-1)IR2

3290-99-1(p-Anisohydrazide)Related Search:

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p-anisohydrazide P-ANISIC HYDRAZIDE P-ANISOYLHYDRAZINE P-METHOXY BENZHYDRAZIDE 4-METHOXYBENZENE-1-CARBOHYDRAZIDE 4-METHOXY-BENZOIC ACID HYDRAZIDE 4-METHOXYBENZOYLHYDRAZINE LABOTEST-BB LT00025103 (p-methoxybenzoyl)hydrazine 4-methoxybenzoylhydrazide 4-methoxybenzoyl-hydrazin anisicacidhydrazide anisichydrazide anisoylhydrazine p-anisicacid,hydrazide p-methoxybenzoicacidhydrazide p-methoxy-benzoicacihydrazide p-methoxybenzoichydrazide AKOS 92185 AKOS BBS-00004504 4-Methoxybenzhydrazide, 98+% 1-(4-Methoxybenzoyl)hydrazine 4-Methoxybenzhydrazide 97% 4-Methoxybenzoylhydrazine p-Anisic Hydrazide p-Anisoylhydrazine 4-Methoxybenzohydrazide> Benzoic acid, 4-methoxy-, hydrazide 4-Methoxybenzoic hydrazide 4-METHOXYBENZOHYDRAZIDE 4-METHOXYBENZHYDRAZIDE 3290-99-1 H3COC6H4CONHNH2 Organic Building Blocks Hydrazides Building Blocks Carbonyl Compounds Building Blocks Carbonyl Compounds Chemical Synthesis Organic Building Blocks Carbonyl Compounds Hydrazides Organic Building Blocks Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes