ChemicalBook >> CAS DataBase List >>1-Bromo-2,4-dimethoxybenzene

1-Bromo-2,4-dimethoxybenzene

CAS No.
17715-69-4
Chemical Name:
1-Bromo-2,4-dimethoxybenzene
Synonyms
1-Bromo-2,4-dimethox;3-Methoxy-4-bromoanisole;2,4-DIMETHOXYBROMOBENZENE;2,4-diMethoxylbroMophenol;2,4-Dimethoxyphenyl bromide;1,3-Dmethoxy-4-bromobenzene;1,3-DIMETHOXY-4-BROMOBENZENE;1-BROMO-2,4-DIMETHOXYBENZENE;4-Bromo-1,3-dimethoxybenzene;Benzene, 1-bromo-2,4-dimethoxy-
CBNumber:
CB3137482
Molecular Formula:
C8H9BrO2
Molecular Weight:
217.06
MDL Number:
MFCD00009844
MOL File:
17715-69-4.mol
MSDS File:
SDS
Last updated:2026-01-13 11:18:57
Product description Number Pack Size Price
1-Bromo-2,4-dimethoxybenzene 97% 157554 25g $25.55
1-Bromo-2,4-dimethoxybenzene >97.0%(GC) B1481 5g $41
1-Bromo-2,4-dimethoxybenzene >97.0%(GC) B1481 25g $120
1-Bromo-2,4-dimethoxybenzene 409175 500mg $305
1-Bromo-2,4-dimethoxybenzene B689043 500mg $45
More product size

1-Bromo-2,4-dimethoxybenzene Properties

Melting point 25-26 °C(lit.)
Boiling point 153-155 °C18 mm Hg(lit.)
Density 1.507 g/mL at 25 °C(lit.)
refractive index n20/D 1.572(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,Room Temperature
form Liquid
color Clear slightly yellow
Specific Gravity 1.507
Water Solubility insoluble
BRN 1867593
InChI InChI=1S/C8H9BrO2/c1-10-6-3-4-7(9)8(5-6)11-2/h3-5H,1-2H3
InChIKey NIUZVSQOXJIHBL-UHFFFAOYSA-N
SMILES C1(Br)=CC=C(OC)C=C1OC
CAS DataBase Reference 17715-69-4(CAS DataBase Reference)
FDA UNII QU54UE5GSE
NIST Chemistry Reference Benzene, 1-bromo-2,4-dimethoxy-(17715-69-4)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HazardClass  IRRITANT
HS Code  29093090
Storage Class 10 - Combustible liquids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
0
2 0

1-Bromo-2,4-dimethoxybenzene price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 157554 1-Bromo-2,4-dimethoxybenzene 97% 17715-69-4 25g $25.55 2025-07-31 Buy
TCI Chemical B1481 1-Bromo-2,4-dimethoxybenzene >97.0%(GC) 17715-69-4 5g $41 2025-07-31 Buy
TCI Chemical B1481 1-Bromo-2,4-dimethoxybenzene >97.0%(GC) 17715-69-4 25g $120 2025-07-31 Buy
Usbiological 409175 1-Bromo-2,4-dimethoxybenzene 17715-69-4 500mg $305 2021-12-16 Buy
TRC B689043 1-Bromo-2,4-dimethoxybenzene 17715-69-4 500mg $45 2021-12-16 Buy
Product number Packaging Price Buy
157554 25g $25.55 Buy
B1481 5g $41 Buy
B1481 25g $120 Buy
409175 500mg $305 Buy
B689043 500mg $45 Buy

1-Bromo-2,4-dimethoxybenzene Chemical Properties,Uses,Production

Chemical Properties

clearslightlyyellowliqui

Uses

1-Bromo-2,4-dimethoxybenzene was used in the synthesis of 2,3-disubstituted benzo[b]furans. It was also used in the synthesis of dendrimer Si[CH2CH2Si(Me)2-2,4-(MeO)2-C6H3]4.

Synthesis

1,3-Dimethoxybenzene

151-10-0

1-Bromo-2,4-dimethoxybenzene

17715-69-4

Carbon tetrabromide (0.075 mmol), AQN-2-CO2H (0.03 mmol) and anhydrous ethanol (5 mL) were added to a Pyrex test tube using 1,3,5-trimethoxybenzene (1a, 0.3 mmol) as the raw material. The reaction mixture was irradiated and stirred in air for 20 h at room temperature using a 21 W fluorescent lamp. Upon completion of the reaction, the mixture was concentrated in vacuum, quenched with sodium thiosulfate (Na2S2O3) solution and extracted with ethyl acetate (EtOAc). The organic layers were combined and dried with anhydrous magnesium sulfate (MgSO4), followed by vacuum concentration to remove the solvent. Purification of the residue by rapid chromatography on silica gel (eluent ratio hexane/ethyl acetate = 6:1) afforded the target product 2-bromo-1,3,5-trimethoxybenzene (2a) (66.8 mg, 90% yield) as a white solid.

References

[1] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[2] Journal of Organic Chemistry, 2013, vol. 78, # 20, p. 10360 - 10368
[3] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 2, p. 591 - 593
[4] Canadian Journal of Chemistry, 2009, vol. 87, # 2, p. 440 - 447
[5] Tetrahedron Letters, 1997, vol. 38, # 25, p. 4415 - 4416

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View Lastest Price from 1-Bromo-2,4-dimethoxybenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Bromo-2,4-dimethoxybenzene pictures 2026-01-30 1-Bromo-2,4-dimethoxybenzene
17715-69-4
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Chuanghai Biotechnology Co., Ltd
1-Bromo-2,4-dimethoxybenzene pictures 2025-12-24 1-Bromo-2,4-dimethoxybenzene
17715-69-4
US $0.10 / KG 1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd
1-Bromo-2,4-dimethoxybenzene pictures 2025-09-25 1-Bromo-2,4-dimethoxybenzene
17715-69-4
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
1-BROMO-2,4-DIMETHOXYBENZENE 1,3-DIMETHOXY-4-BROMOBENZENE 1-BROMO-2 4-DIMETHOXYBENZENE 96% 2,4-DIMETHOXYBROMOBENZENE 4-BROMORESOCINOL DIMETHYL ETHER 4-BROMORESORCINOL DIMETHYL ETHER 2,4-Dimethoxyphenyl bromide 4-Bromo-1,3-dimethoxybenzene 1-Bromo-2,4-dimethoxybenzene, GC 98% Benzene, 1-bromo-2,4-dimethoxy- 3-Methoxy-4-bromoanisole 1-Bromo-2,4-dimethoxybenzene,98% 1,3-Dmethoxy-4-bromobenzene 1-Bromo-2,4-dimethox 2,4-diMethoxylbroMophenol 1-BroMo-2,4-diMethoxybenzene, 98% 5ML 1-broMo -2,4- twoMethoxybenzene 1-Bromo-2,4-dimethoxybenzene > 1-Bromo-2,4-dimethoxybenzene ISO 9001:2015 REACH 17715-69-4 17775-69-4 11715-69-4 17715-69-1 17717-69-4 C8H9BrO2 Building Blocks ARYL HALIDE Oxygen Compounds Organic Building Blocks Ethers Alcohol& Phenol& Ethers Benzene derivates Anisoles, Alkyloxy Compounds & Phenylacetates Bromine Compounds Ethers Organic Building Blocks Oxygen Compounds Aromatic Ethers Anisole bc0001