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(1S)-(+)-3-Carene

(1S)-(+)-3-Carene structure

CAS No.: 498-15-7

Chemical Name:: (1S)-(+)-3-Carene

Synonyms: (+)-3-Carene;(1S,6R)-3-Carene;()-3-Carene;(+)-car-3-ene;(+)-3-Δ-CARENE;(+)-D-3-Carene;(+)-Δ-3-Carene;Einecs 207-856-6;(1S)-(+)-3-CARENE;(+)-Δ-3-Carene-RM

CBNumber:: CB3208717

Molecular Formula:: C10H16

Molecular Weight:: 136.23

MDL Number:: MFCD00066417

MOL File:: 498-15-7.mol

MSDS File:: SDS

Last updated:2025-01-27 09:38:02

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(1S)-(+)-3-Carene Properties

Melting point	25°C (estimate)
alpha	17 º (NEAT)
Boiling point	170-172 °C(lit.)
Density	0.865 g/mL at 25 °C(lit.)
vapor pressure	2.73hPa at 20℃
refractive index	n20/D 1.473
Flash point	131 °F
storage temp.	-20°C
solubility	soluble in Acetone,Ethanol,Benzene
form	liquid (clear)
color	clear very slightly yellow
Odor	sweet
optical activity	[α]20/D +17°, neat
Water Solubility	3.7mg/L at 20℃
Merck	14,1836
BRN	1902767
LogP	4.38 at 37℃
CAS DataBase Reference	498-15-7(CAS DataBase Reference)
FDA UNII	XBL40A7IA6
NIST Chemistry Reference	Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S)-(498-15-7)
EPA Substance Registry System	Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S,6R)- (498-15-7)
UNSPSC Code	85151701
NACRES	NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07,GHS09

Signal word

Warning

Hazard statements

H226-H317-H410

Precautionary statements

Hazard Codes

Risk Statements

Safety Statements

RIDADR

UN 2319 3/PG 3

WGK Germany

RTECS

FH8400000

10-23

HS Code

2902.19.0050

HazardClass

PackingGroup

III

NFPA 704

	2
1		0

(1S)-(+)-3-Carene price More Price(20)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	21986	(+)-3-Carene analytical standard	498-15-7	5ml	$147	2024-03-01	Buy
Sigma-Aldrich	00410590	(+)-3-δ-Carene primary reference standard	498-15-7	100mg	$314	2023-06-20	Buy
Sigma-Aldrich	CRM40416	(+)-3-Carene solution certified reference material, 2000?μg/mL in methanol, ampule of 1?mL	498-15-7	1mL	$159	2022-05-15	Buy
TCI Chemical	C0047	(+)-3-Carene >90.0%(GC)	498-15-7	25mL	$24	2024-03-01	Buy
TCI Chemical	C0047	(+)-3-Carene >90.0%(GC)	498-15-7	500mL	$76	2024-03-01	Buy

Product number	Packaging	Price	Buy
21986	5ml	$147	Buy
00410590	100mg	$314	Buy
CRM40416	1mL	$159	Buy
C0047	25mL	$24	Buy
C0047	500mL	$76	Buy

(1S)-(+)-3-Carene Chemical Properties,Uses,Production

Uses

Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.

Production Methods

3-Carene is obtained exclusively by fractional distillation of certain turpentines.

Definition

ChEBI: A car-3-ene (3,7,7-trimethylbicyclo[4.1.0]hept-3-ene) that has S configuration at position 1 and R configuration at position 6.

General Description

(1S)-(+)-3-Carene is a monoterpene.

Chemical Reactivity

3-Carene readily undergoes autoxidation and resinification in air. Addition of pyrogallol or resorcinol as stabilizers is recommended. On treatment with peracetic acid in glacial acetic acid and subsequent saponification, 3-carene is oxidized to 3,4- caranediol. Pyrolysis at 300–580 ℃ in the presence of Fe(III) oxide on carriers gives p-cymene as the main product.

(1S)-(+)-3-Carene synthesis

Synthesis of (1S)-(+)-3-Carene from [1S-(1alpha,3beta,5beta,7alpha)]-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane

(1S)-(+)-3-Carene Preparation Products And Raw materials

Raw materials

Benzotrifluoride Toluene Chlorine Ferric chloride Iron chloride hexahydrate

[1S-(1alpha,3beta,5beta,7alpha)]-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane (+)-2-CARENE (S)-1-PHENYL-BUT-3-EN-1-OL Methyllithium

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Preparation Products

p-Cymene

(1S)-(+)-3-Carene Suppliers

Global( 93)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+86-29-81139210 +86-18192627656	1059@dideu.com	China	3047	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29807	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18134	58
TargetMol Chemicals Inc.		support@targetmol.com	United States	38663	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	+86-0512-83500002 +8618501500038	3899766280@qq.com	China	26362	58
LEAPCHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	43340	58
Shanghai Acmec Biochemical Technology Co., Ltd.	+86-18621343501; +undefined18621343501	product@acmec-e.com	China	33338	58
Aladdin Scientific		tp@aladdinsci.com	United States	57505	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	+8613817748580	cooperation@kean-chem.com	China	40066	58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.	+8618950047208	ellena@amitychem.com	China	43416	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
career henan chemical co	58
Hebei Chuanghai Biotechnology Co., Ltd	58
TargetMol Chemicals Inc.	58
SUZHOU SENFEIDA CHEMICAL CO.,LTD	58
LEAPCHEM CO., LTD.	58
Shanghai Acmec Biochemical Technology Co., Ltd.	58
Aladdin Scientific	58
SHANGHAI KEAN TECHNOLOGY CO., LTD.	58
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.	58

View Lastest Price from (1S)-(+)-3-Carene manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2024-07-24	(1S)-(+)-3-Carene 498-15-7	US $30.00-20.00 / KG	1KG	99%	3000KG	Shaanxi Dideu Medichem Co. Ltd
	2020-02-14	(1S)-(+)-3-Carene 498-15-7	US $1.00 / KG	1KG	99%	200kgs	Career Henan Chemical Co

(1S)-(+)-3-Carene
498-15-7
US $30.00-20.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

(1S)-(+)-3-Carene
498-15-7
US $1.00 / KG
99%
Career Henan Chemical Co

(1S)-(+)-3-Carene Spectrum

(1S)-(+)-3-Carene(498-15-7)¹HNMR (1S)-(+)-3-Carene(498-15-7)¹³CNMR (1S)-(+)-3-Carene(498-15-7)IR1 (1S)-(+)-3-Carene(498-15-7)Raman

498-15-7((1S)-(+)-3-Carene)Related Search:

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METHYLCYCLOPENTADIENE DIMER 3-CARENE 4-ACETYL CARENE (+)-2-CARENE WITH GC,CARENE, (1S-CIS)-2-,(1S-CIS)-2-CARENE,(+)-2-CARENE,2-CARENE 95+% 4-delta-carene,delta-2-Carene,delta-4-carene,2-CARENE

[1S,3S,6R,(-)]-4-Carene,(1S,3S)-TRANS-4-CARENE,4-Carene, (1S, 2S, 6R)-(-)- 3-Carene oxide 4-Carene,[1S,3R,6R,(-)]-4-Carene,(1S,3R)-CIS-4-CARENE (±)-Car-3-ene-2,5-dione Carene-4

(1S)-(+)-3-Carene CARENE, (1S-cis)-2-(SG) CIS-CARENE

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(1S)-(+)-car-3-ene (1S)-3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE (1S)-(+)-3-CARENE (+)-3-CARENE, TERPENE STANDARD Bicyclo4.1.0hept-3-ene, 3,7,7-trimethyl-, (1S,6R)- (+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene (1S,6R)-3-Carene (1S,6α)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene (1α,6α)-3,7,7-Trimethylbicyclo[4.1.0]hepta-3-ene 3-Carene, (1S,6R)-(+)- Bicyclo(4.1.0)hept-3-ene, 3,7,7-trimethyl-, (1S)- Einecs 207-856-6 (1S)-(+)-3-Carene,(+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene (1S)-(+)-3-Carene 99% (+)-3-CARENE SOLUTION (+)-3-Δ-CARENE (1S)-(+)-3-Carene Solution (+)-3-Carene@100 μg/mL in Methanol (+)-3-delta-Carene (+)-car-3-ene (+)-3-Carene (+)-D-3-Carene (+)-3-Carene 1000 μg/mL in Isopropanol ()-3-Carene (+)-Δ-3-Carene CA11042000 (1S,6R)-3-Carene (+)-Δ-3-Carene-RM (1S)-(+)-3-Carene 498-15-7 Terpenes Bicyclic Monoterpenes Chiral Building Blocks CA - CG Asymmetric Synthesis Analytical Standards Analytical Chromatography Product Catalog Alkenes Alphabetic Organic Building Blocks