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2-Amino-3-cyanotoluene

2-Amino-3-cyanotoluene Structure
2-Amino-3-cyanotoluene structure
CAS No.
69797-49-5
Chemical Name:
2-Amino-3-cyanotoluene
Synonyms
2-Amino-3-cyanotoluene;2-Cyano-6-methylaniline;3-methyl-2-Amino-benzonitrile;2-AMINO-3-METHYL-BENZONITRILE;Benzonitrile, 2-aMino-3-Methyl-;2-amino-3-methylbenzenemethylnitrile
CBNumber:
CB32452268
Molecular Formula:
C8H8N2
Molecular Weight:
132.16
MDL Number:
MFCD09880087
MOL File:
69797-49-5.mol
MSDS File:
SDS
Last updated:2026-09-12 18:51:52
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2-Amino-3-cyanotoluene Properties

storage temp. Keep in dark place,Inert atmosphere,Room temperature
Appearance Light yellow to brown Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
HS Code  2926907090

2-Amino-3-cyanotoluene price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 250mg $21 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 1g $24 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 5g $77 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 25g $232 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 100g $901 2026-06-04 Buy
Product number Packaging Price Buy
OR906433 250mg $21 Buy
OR906433 1g $24 Buy
OR906433 5g $77 Buy
OR906433 25g $232 Buy
OR906433 100g $901 Buy

2-Amino-3-cyanotoluene Chemical Properties, Uses, Production

Application

3-Amino-2-methylbenzonitrile is an aniline heterocyclic compound mainly used in laboratory organic synthesis processes.

Synthesis

2-BROMO-6-METHYLANILINE

53848-17-2

Copper(I) Cyanide

544-92-3

2-AMINO-3-CYANOTOLUENE

69797-49-5

The general procedure for the synthesis of 2-amino-3-methylbenzonitrile from 2-bromo-6-methylaniline and cuprous cyanide was as follows: cuprous cyanide (CuCN, 197 mg, 2.2 mmol) was added to an anhydrous N-methylpyrrolidone (NMP, 3 mL) solution of 2-bromo-6-methylaniline (126 μL, 1 mmol). The reaction mixture was placed in a microwave reactor and irradiated at 220 °C for 40 min. Upon completion of the reaction, the mixture was cooled to room temperature and poured into a mixture consisting of ammonia (50% w/v, 10 mL) and ice. Subsequently, the mixture was stirred for 30 min and the target product was extracted with dichloromethane (3 x 20 mL). The organic layers were combined, washed sequentially with water and saturated saline, dried with anhydrous magnesium sulfate (MgSO4), and then concentrated. The crude product was purified by silica gel column chromatography (eluent: 50% ethyl acetate/hexane) to give a brown oil, which was crystallized after standing (128 mg, 96% yield). The structure of the product was confirmed by 1H NMR (400 MHz, DMSO-d6) and mass spectrometry (MS): 1H NMR δ 2.08 (s, 3H), 5.68 (bs, 2H), 6.51-6.55 (t, 1H), 7.17-7.19 (d, 1H), 7.22-7.24 (dd, 1H); MS m/z 133 ([M+H ]+).

References

[1] Patent: US2008/306053, 2008, A1. Location in patent: Page/Page column 60

2-Amino-3-cyanotoluene Preparation Products And Raw materials

Raw materials

2-Bromo-6-methylaniline Copper(I) Cyanide

Preparation Products

2-(Aminomethyl)-6-methylaniline

2-Amino-3-cyanotoluene Suppliers

Global Suppliers ( 72)
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Beijing Ouhe Technology Co., Ltd 13552068683 13522913783 2355560935@qq.com China 11777 60
Suzhou Guide Fine Material Co.Ltd. 0512-66627360 13914021065 706938434@qq.com China 202 60
Candia Thamtech Company Limited 0371-86615086 18203638366 0371-86159066 13526786601 China 2011 60
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 18201 56
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29977 65
SynAsst Chemical. 021-60343070 China 12731 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Shanghai Xingui Biotechnology Co., Ltd. 15121041756 xingui2022@126.com China 9954 58
ShangHai AmK Pharmaceutical Technology Co., Ltd. 微信 18019252918 18019252918 sale@amkchem.com China 14982 55
Supplier Advantage
Energy Chemical 61
Beijing Ouhe Technology Co., Ltd 60
Suzhou Guide Fine Material Co.Ltd. 60
Candia Thamtech Company Limited 60
9ding chemical ( Shanghai) Limited 56
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
SynAsst Chemical. 55
Bide Pharmatech Ltd. 60
Shanghai Xingui Biotechnology Co., Ltd. 58
ShangHai AmK Pharmaceutical Technology Co., Ltd. 55

2-Amino-3-cyanotoluene Spectrum

2-AMINO-3-CYANOTOLUENE(69797-49-5)1HNMR

69797-49-5 (2-Amino-3-cyanotoluene) Related Search:

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2-Nitroisophthalonitrile 2-[[4-(diethylamino)-2-methylphenyl]azo]-5-methylbenzene-1,3-dicarbonitrile 5'-Amino-4-bromo-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile 5'-Amino-3,4-dimethoxy-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile Ethyl 4-amino-5-cyano-2-hydroxy-3-methylbenzoate
5'-Amino-4-methyl-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile 5'-Amino-3-nitro-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile 5'-Amino-4''-bromo-3,4-dimethoxy-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile 5'-Amino-4''-bromo-3-nitro-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile 5'-Amino-4''-chloro-4-methyl-[1,1':3',1'']terphenyl-4',6'-dicarbonitrile
N-(2,4-Dicyano-6-methylphenyl)acetamide 1-(2,6-Dicyanophenyl)-4-piperidinecarboxamide 2-Morpholinoisophthalonitrile

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2-AMINO-3-METHYL-BENZONITRILE Benzonitrile, 2-aMino-3-Methyl- 2-Cyano-6-methylaniline 3-methyl-2-Amino-benzonitrile 2-amino-3-methylbenzenemethylnitrile 2-Amino-3-cyanotoluene 69797-49-5