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ChemicalBook >> CAS DataBase List >>BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Structure
BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER structure
CAS No.
99548-55-7
Chemical Name:
BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER
Synonyms
4-BROMO-2-METHYL-,METHYL ESTER;4-BroMo-2-Methyl-benzoic acid Methyl ester;Methyl 2-methyl-4-bromobenzoate;2- Methyl-4-broMo benzoic acidMethyl ester;BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER
CBNumber:
CB32456776
Molecular Formula:
C9H9BrO2
Molecular Weight:
229.07
MDL Number:
MFCD09954957
MOL File:
99548-55-7.mol
MSDS File:
SDS
Last updated:2025-08-08 17:45:00
Product description Number Pack Size Price
Methyl 4-Bromo-2-methylbenzoate min. 98.0 % M3630 5G $75
Methyl 4-Bromo-2-methylbenzoate min. 98.0 % M3630 25G $225
Methyl4-Bromo-2-methylbenzoate M295845 1g $55
Methyl4-bromo-2-methylbenzoate OR51873 1g $66
Methyl 4-bromo-2-methylbenzoate 2723-9-30 1g $72
More product size
Request For Quotation

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Properties

Melting point 9 °C
Boiling point 273.6±20.0 °C(Predicted)
Density 1.433±0.06 g/cm3(Predicted)
storage temp. 2-8°C
Appearance Colorless to light yellow Liquid
InChI InChI=1S/C9H9BrO2/c1-6-5-7(10)3-4-8(6)9(11)12-2/h3-5H,1-2H3
InChIKey CYEXEOXALMJXDI-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC=C(Br)C=C1C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
HS Code  2916399090

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M3630 Methyl 4-Bromo-2-methylbenzoate min. 98.0 % 99548-55-7 5G $75 2026-03-19 Buy
TCI Chemical M3630 Methyl 4-Bromo-2-methylbenzoate min. 98.0 % 99548-55-7 25G $225 2026-03-19 Buy
TRC M295845 Methyl4-Bromo-2-methylbenzoate 99548-55-7 1g $55 2021-12-16 Buy
Apolloscientific OR51873 Methyl4-bromo-2-methylbenzoate 99548-55-7 1g $66 2021-12-16 Buy
SynQuest Laboratories 2723-9-30 Methyl 4-bromo-2-methylbenzoate 99548-55-7 1g $72 2021-12-16 Buy
Product number Packaging Price Buy
M3630 5G $75 Buy
M3630 25G $225 Buy
M295845 1g $55 Buy
OR51873 1g $66 Buy
2723-9-30 1g $72 Buy

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Chemical Properties,Uses,Production

Chemical Properties

off-white powder

Uses

Methyl 4-Bromo-2-methylbenzoate can be used as an organic synthesis intermediate and a pharmaceutical intermediate.

Synthesis

4-Bromo-2-methylbenzoic acid

68837-59-2

(TRIMETHYLSILYL)DIAZOMETHANE

18107-18-1

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

99548-55-7

Step 1: To a mixed solution of 4-bromo-2-methylbenzoic acid (15.1 g, 0.070 mol) in tetrahydrofuran (180 mL) and methanol (45 mL) was slowly added dropwise (trimethylsilyl) diazomethane in 2.0 M hexane solution (42 mL, 0.084 mol) at 0 °C. The reaction mixture was gradually warmed to room temperature and stirred continuously for 1 hour. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure to afford methyl 4-bromo-2-methylbenzoate (16 g, 100% yield) as a yellow oil. The crude product could be used in the subsequent reaction without further purification. The product was characterized as follows: 1H NMR (400 MHz, CDCl3): δ 7.78 (d, 1H), 7.42 (s, 1H), 7.38 (d, 1H), 3.88 (s, 3H), 2.58 (s, 3H). Mass spectrum (EI): m/z 230 ([M+H]+, C9H9BrO2).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2005, vol. 15, # 4, p. 999 - 1004
[2] Patent: WO2009/55077, 2009, A1. Location in patent: Page/Page column 430
[3] Journal of Medicinal Chemistry, 2014, vol. 57, # 6, p. 2334 - 2356
[4] Patent: US2009/69370, 2009, A1. Location in patent: Page/Page column 17-18
[5] Patent: WO2009/158369, 2009, A1. Location in patent: Page/Page column 38; 39

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER synthesis

68837-59-2
74-88-4
99548-55-7
Synthesis of BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER from 4-Bromo-2-methylbenzoic acid and Iodomethane

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Preparation Products And Raw materials

Raw materials

Benzoyl chloride, 4-bromo-2-methyl- 4-Bromo-2-methylbenzonitrile 4-Bromo-2-methylbenzoic acid Methanol Dimethyl sulfate
Iodomethane (TRIMETHYLSILYL)DIAZOMETHANE

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Preparation Products

Methyl 4-hydroxy-7-phenoxyisoquinoline-3-carboxylate 5-Bromo-2-(bromomethyl)toluene, 4-Bromo-1-(bromomethyl)-2-methylbenzene 2,6-Piperidinedione, 3-[5-(aminomethyl)-1,3-dihydro-1-oxo-2H-isoindol-2-yl]- METHYL 4-BROMO-2-BROMOMETHYL-BENZOATE

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Suppliers

Global( 200)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20124 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29640 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Nanjing Dolon Biotechnology Co.,Ltd. 		18905173768 52513593@qq.com CHINA 2972 58
Accela ChemBio Inc. 		+1-858-6993322 info@accelachem.com United States 21193 58
Alchem Pharmtech,Inc. 		8485655694 sales@alchempharmtech.com United States 63687 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29795 58
Jinan Liheng Biotechnology Co., Ltd. 		15865262812 info@lihengpharm.com CHINA 938 58
Fuxin Pharmaceutical 		+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10000 58
Supplier Advantage
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
Changzhou Ansciep Chemical Co., Ltd. 		58
Nanjing Dolon Biotechnology Co.,Ltd. 		58
Accela ChemBio Inc. 		58
Alchem Pharmtech,Inc. 		58
career henan chemical co 		58
Jinan Liheng Biotechnology Co., Ltd. 		58
Fuxin Pharmaceutical 		58

View Lastest Price from BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
methyl 4-bromo-2-methylbenzoate pictures 2026-04-22 methyl 4-bromo-2-methylbenzoate
99548-55-7
 US $0.00 / kg 20kg 99% 20 tons Qingdao RENAS Polymer Material Co., Ltd.
BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER pictures 2025-09-25 BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER
99548-55-7
 US $5.00-0.10 / KG 1KG 98% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Methyl 4-bromo-2-methylbenzoate pictures 2022-01-15 Methyl 4-bromo-2-methylbenzoate
99548-55-7
 US $0.00 / KG 1KG 99.0% 100 tons Honest Joy Holdings Limited

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Spectrum

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER(99548-55-7)1HNMR

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Methyl 2-methyl-4-bromobenzoate 4-BroMo-2-Methyl-benzoic acid Methyl ester BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER 2- Methyl-4-broMo benzoic acidMethyl ester 4-BROMO-2-METHYL-,METHYL ESTER 99548-55-7